Youn Jaung Cho

Synthesis and structure of ansa-cyclopentadienyl pyrrolyl titanium complexes: [(η5-C5H4)CH2(2-C4H3N)]Ti(NMe2)2 and [1,3-{CH2(2-C4H3N)}2(η5-C5H3)]Ti(NMe2)

Abstract Reaction of ansa-cyclopentadienyl pyrrolyl ligand (C5H5)CH2(2-C4H3NH) (2) with Ti(NMe2)4 affords bis(dimethylamido)titanium complex [(η5-C5H4)CH2(2-C4H3N)]Ti(NMe2)2 (3) via amine elimination. A cyclopentadiene ligand with two pendant pyrrolyl arms, a mixture of 1,3- and 1,4-{CH2(2-C4H3NH)}2C5H4 (4), undergoes an analogous reaction with Ti(NMe2)4 to give [1,3-{CH2(2-C4H3N)}2(η5-C5H3)]Ti(NMe2) (5). Molecular structures of 3 and 5 have been determined by single crystal X-ray diffraction studies.