Yuansheng Du

Pyrite framboids interpreted as microbial colonies within the Permian Zoophycos spreiten from southeastern Australia

Two types of pyrite framboids (PF, probably sulphate-reducing bacteria) have been found within the Zoophycos spreiten, hosted in the Guadalupian (Middle Permian) glaciomarine greywacke of the Westley Park Sandstone Member within the Broughton Formation from the southern Sydney Basin of southeastern Australia. They are composed of non-sheathed (PF1) and sheathed (PF2) sub-micron balls, respectively. Chemically, the sub-micron balls consist of iron, sulphur, carbon and oxygen. Both PF1 and PF2 occur in rhythmic alternation within the thick, light-grey and thin, dark-grey minor lamellae of Zoophycos spreiten. The framboids from the minor lamellae are highly abundant and occur in an orderly arrangement of equal density and in a good state of preservation. Within Zoophycos spreiten no homogeneous filling, fecal pellets, or any sign of re-exploitation of the minor lamellae have been recognized. No similar framboids have been observed outside Zoophycos spreiten. Therefore, the framboids are interpreted as the pyritized remains of microbial colonies within Zoophycos spreiten. The trace Zoophycos would be a multifunctional garden that may have been carefully constructed by the Zoophycos maker, where different microbial colonies were orderly and carefully planted and cultured within different minor lamellae. Further, it is proposed that the Zoophycos maker had a symbiotic relationship with microbial colonies on the mutual basis of food supply and redox conditions. The fact that the overlying spreiten cut the underlying ones indicates that the Zoophycos from the study area is of an upward construction. The rhythmic alternation of both the thick, light-grey and thin, dark-grey minor lamellae within Zoophycos spreiten may be suggestive of a gardening manner of the Zoophycos maker responding to the warm and cold changes, food supply in pulses and variations of sedimentation rate for planting and culturing microbial colonies under the conditions of a glaciomarine environment at the high latitudes.

Terminal suturing of Gondwana along the southern margin of South China Craton: Evidence from detrital zircon U‐Pb ages and Hf isotopes in Cambrian and Ordovician strata, Hainan Island

Hainan Island, located near the southern end of mainland South China, consists of the Qiongzhong Block to the north and the Sanya Block to the south. In the Cambrian, these blocks were separated by an intervening ocean. U-Pb ages and Hf isotope compositions of detrital zircons from the Cambrian succession in the Sanya Block suggest that the unit contains detritus derived from late Paleoproterozoic and Mesoproterozoic units along the western margin of the West Australia Craton (e.g., Northampton Complex) or the Albany-Fraser-Wilkes orogen, which separates the West Australia and Mawson cratons. Thus, in the Cambrian the Sanya Block was not part of the South China Craton but rather part of the West Australian Craton and its environs. In contrast, overlying Late Ordovician strata display evidence for input of detritus from the Qiongzhong Block, which constituted part of the southeastern convergent plate margin of the South China Craton in the early Paleozoic. The evolving provenance record of the Cambrian and Ordovician strata suggests that the juxtaposition of South China and West Australian cratons occurred during the early to mid-Ordovician. The event was linked with the northern continuation of Kuungan Orogeny, with South China providing a record of final assembly of Gondwana.

A sedimentary archive of tectonic switching from Emeishan Plume to Indosinian orogenic sources in SW China

Upper Permian to Middle Triassic sedimentary rocks in the Youjiang Basin, SW China, record a change from a within-plate mafic-dominated source to the NW, to a mixed source involving magmatic arc and recycled orogenic detritus that lay to the west and east. Upper Permian and some Lower Triassic sedimentary rocks are characterized by relatively high contents of TiO2 and Nb, and low ratios of Al2O3/TiO2 and Th/Nb. Detrital zircons yield U–Pb ages of c. 260 Ma and have geochemical affinities to those crystallized from the within-plate type magmas. These features, combined with extensive basaltic lithic fragments and plagioclase grains in the sandstones, imply a sedimentary source dominated by the Emeishan Large Igneous Province exposed to the NW of the basin. The Early and Middle Triassic marked a significant change in sediment provenance, with rocks displaying geochemical affinity to upper continental crust. U–Pb ages and trace elements of detrital zircons from this material show input from multiple sedimentary sources including the subduction–collision rocks related to the Indosinian Orogeny to the west of the basin and the recycled Precambrian–early Palaeozoic sedimentary and granitic rocks in the South China hinterland to the east of the basin. The Early Triassic change in the nature of the source supplying detritus to the Youjiang Basin, together with regional sedimentary and tectonothermal events, suggests a tectonic transition from the Emeishan Plume to the Indosinian Orogeny in SW China. Regional stratigraphic correlation and provenance data suggest that the Emeishan basalts provided a large sediment influx for the riverine–littoral–marine systems in the Late Permian. This basaltic particulate and dissolved input may have contributed significant unradiogenic Sr to the Late Permian seawater. Supplementary material: Details of sample preparation, analytical procedure and results, and additional figures are available at www.geolsoc.org.uk/SUP18698.

Intraplate orogenesis in response to Gondwana assembly: Kwangsian Orogeny, South China

In intraplate orogens tectonothermal activity occurs at a site removed from a plate margin and is considered to result from localization of far-field plate-boundary stresses through a combination of pre-existing structural features and modification of lithospheric properties through fluid alteration, enhanced heat flow and potential thermal blanketing effects. The mid-Paleozoic Kwangsian Orogeny (460–400 Ma) in the South China Craton is geodynamically associated with the far-field response to convergence along the northern margin of east Gondwana. Deformation is focused adjacent to the site of both early Neoproterozoic suturing of the Yangtze and Cathaysia blocks and mid-Neoproterozoic rifting within the craton. Furthermore, this region is one of high crustal heat flow and of widespread fluid release and localized crustal melting during orogenesis. In the late Neoproterozoic-Cambrian, the South China Craton constituted part of the lithosphere of greater India and was separated from Australia by the Kuunga Ocean. The closure of the Kuunga Ocean during Cambrian-Ordovician time, resulting in final assembly of Gondwana, permitted the stresses sourced from the Terra Australis accretionary orogen in East Gondwana to propagate inboard across the supercontinent. These stresses localized along the site of the Neoproterozoic Nanhua Rift Basin of South China resulting in basin inversion and development of the intraplate Kwangsian Orogeny.

From Subduction to Collision in the Northern Tibetan Plateau: Evidence from the Early Silurian Clastic Rocks, Northwestern China

The Qilian Orogen records early Paleozoic collisional suturing of the Qaidam Block and the Central Qilian Block to the North China Craton. The composition and U-Pb age of detrital zircons and the composition of Cr-spinels from the Early Silurian Lujiaogou and Angzanggou formations in the northern part of orogen indicate derivation from evolving oceanic and continental source terranes. Heavy-mineral chemistry indicates the incorporation of suprasubduction zone–type ophiolitic detritus in addition to continent-derived material. Integrating these chemical and age data with regional data on the duration of subduction-related magmatic activity, syn- and postcollisional granitic rocks, and high-pressure metamorphic rocks constrains the transformation from oceanic subduction to continental collision to 450–440 Ma. The collision resulted in a flood of detritus into the northern part of the orogen from the Central Qilian Block, which masked input from the intervening magmatic arc, implying rapid exposure of the block.

Depositional chemistry of chert during late Paleozoic from western Guangxi and its implication for the tectonic evolution of the Youjiang Basin

Continual deep-water sediments from the late Early Devonian to the Late Permian extended in wide areas of western Guangxi. We analyzed the major, trace, and rare earth elements of the Upper Paleozoic cherts in Badu, western Guangxi. High non-terrigenous SiO2 contents (Sinon-ter/Sibulk(%)> 80%) and pure chert components (> 70%) indicate a large extent of silicification in the Upper Paleozoic cherts, except for the Upper Devonian-Lower Carboniferous Luzhai Formation cherts, which have lower non-terrigenous SiO2 contents (avg. 71.8%) and pure chert components (40%–70%). The Al/(Al+Fe+Mn) ratios and Feter/Febulk(%) values of samples from the lowest horizon of the Pingen Formation are 0.05–0.26, 13.1%–14.5%, respectively, indicating hydrothermal origins. All other samples show high Al/(Al+Fe+Mn) ratios (0.39–0.81) and high Feter/Febulk(%) values (23.1%–186.8%), indicating non-hydrothermal origins. The Pingen Formation and Liujiang Formation cherts show slightly-moderately negative Ce anomalies (0.71±0.07, 0.81±0.08, respectively) and higher Y/Ho ratios (33.49±1.27, 36.10±2.05, respectively) than PAAS. This suggests that these cherts were deposited in the open marine basin, rather than in the intracontinental rift basin as previously assumed. The Luzhai Formation cherts may be deposited near the seamount or seafloor plateaus with no negative Ce anomalies (1.09±0.07) and no significant Y-Ho fractionation (Y/Ho=28.60±1.25). The Nandan Formation and Sidazhai Formation cherts were deposited in the open-ocean basin with moderately negative Ce anomalies (0.67±0.08, 0.73±0.11, respectively) and high Y/Ho ratios (36.01±1.00, 32.00±2.25, respectively). On the basis of our studies about cherts, we conclude that the Youjiang Basin originated as part of the Paleo-Tethys that controlled the depositional environments of cherts during late Paleozoic. The rift of the Youjiang Basin had occurred at least since the Early-Middle Devonian. The basin had a trend of evolving into an open-ocean basin during the Early-Middle Permian.

Soft-sediment deformation structures interpreted as seismite from the Middle Permian of the southern Sydney Basin, southeastern Australia

The Middle Permian Wandrawandian Siltstone of the southern Sydney Basin is well exposed along the coastline from Lagoon Head in the south to North Head in the north near Ulladulla in southern New South Wales. The unit is dominated by fossiliferous siltstone and mudstone, with abundant dropstones and minor pebbly sandstone interbeds, and contains an interval of well-preserved and extensive soft-sediment deformation structures. These deformation structures occur mainly in the middle part of the cliff sections and are bounded above and below by undeformed sedimentary units of similar lithology. A wide range of soft-sediment deformation structures have been observed, including cracks, sandstone and sandy mudstone dykes, a possible sand volcano, networks of relatively small and closely connected fissure-like structures, metre-scale complex-type slump folds, flexural stratification, concave-up depressional structures, small-scale normal faults (with displacements usually <1 m), shear planes, and breccias (pseudonodules). The slumps and associated deformations are here collectively interpreted as representing a seismite deposit attributable to penecontemporaneous deformation of soft, hydroplastic sediment layers following a liquefaction triggered by seismic shocks. The timing of the inferred earthquake events appears to correspond to the onset of a major basin-wide tectonism during the Middle Permian.

Reconstructing Early Permian tropical climates from chemical weathering indices

This study was financially supported by the National Natural Science Foundation of China (grants 41302083, 41572078), the National Basic Research Program of China (grant 2011CB808800), and the Fundamental Research Funds for the Central Universities (grant CUGL140402), China University of Geosciences (Wuhan). P.A. Cawood acknowledges support from NERC grant NE/J021822/1.

Geochemical significance of the Paleogene soda-deposits bearing strata in Biyang Depression, Henan Province

The Biyang Depression, lying in the eastern Nanxiang Basin, has a dustpan-shape with faults developed to the southwest and southeast. The Paleogene Hetaoyuan Formation in this depression hosts one of the oldest soda-deposits, the Anpeng deposit. These sodium carbonate-bearing strata consist of lutites, muddy dolomites, and bedded soda-deposits, which are dominated by nahcolite with little trona, mirabilite, and halite. In the top Unit 3 and lower Unit 2 of Hetaoyuan Formation where the sodium carbonates are concentrated, dolomitic shale, muddy carbonate, and sodium carbonate can be separated based on their distinct Al2O3, TiO2, Na2O, MgO+CaO, and LOI (loss on ignition) contents. By using Na2O/(MgO+CaO) ratio as an indicator for the relative concentration of Na carbonates to Mg-Ca carbonates, the muddy dolomites can be classified into two groups. One group with Na2O/(MgO+CaO)<0.6 exhibits a positive correlation between this ratio and Al2O3+TiO2 content, an proxy for terrigenous clastic input and the other group with Na2O/(MgO+CaO)>0.6 presents a negative correlation. As the clastic proportion decreases, the former indicates that it tends to form pure Mg-Ca carbonates reflecting evaporation less than or equal to replenishment for the lake water in a relative humid climate, and the latter reveals a trend to form sodium carbonates with lake water’s evaporation more than replenishment in a relatively dry climate. From muddy dolomite to sodium carbonate samples, with Na2O/(MgO+CaO) ratio increasing, the Al normalized Zr, Ti, La, K, Rb, and Ba tend to be enriched and the post-Archean Average Shale (PAAS) normalized positive Eu anomaly becomes more obvious. Integrated with the high B contents and the report of searlesite in the bedded sodium carbonates and the regional extensional tectonic regime, the above geochemical characteristics were interpreted to signify hydrothermal contribution to forming these soda-deposits through the deep fault systems of basin margins.

Aulacogen Formation in Response to Opening the Ailaoshan Ocean: Origin of the Qin-Fang Trough, South China

The Qin-Fang Trough, South China, trends northeast-southwest, orthogonal to the adjoining southern margin of the craton. The Devonian strata within the trough are unconformable on late Neoproterozoic units of the Yunkai Massif, indicating that strata within the trough are autochthonous. U-Pb ages and Hf isotope compositions of detrital zircons from the Silurian to Devonian succession are consistent with derivation from the massif. In comparisons of our data with those from equivalent units in the Ailaoshan Belt and Hainan Island, detrital zircons from the Silurian strata show similar age distributions and Hf isotope compositions, indicating that the three areas shared a common source and were adjacent to each other during the Silurian. In contrast, the age distributions of detrital zircons preserved in Devonian strata in the Qin-Fang area are different from those of equivalent units in the Ailaoshan Belt. This, along with the absence of Devonian strata on Hainan Island, suggests that the Qin-Fang area had separated from the Ailaoshan Belt by the Devonian. This change is linked to opening of the Ailaoshan Ocean, which was synchronous with expansion of the Qin-Fang Trough and the adjoining Youjiang Basin into epicontinental basins during the Devonian and Carboniferous. Combining these findings with temporal and spatial correlations, we conclude that the Qin-Fang Trough originated as an aulacogen: a “failed” rift of a three-armed rift system, with the other two rift arms evolving into the Ailaoshan Ocean during the opening of Paleo-Tethys. The Ailaoshan Ocean was an Atlantic-type oceanic basin with rifting commencing in the Early Silurian.