Z.A. Zainal

Experimental investigation of a downdraft biomass gasifier

An experimental investigation of a downdraft biomass gasifier is carried out using furniture wood and wood chips. The effect of equivalence ratio on the gas composition, calorific value and the gas production rate is presented. The calorific value of the producer gas increases with equivalence ratio initially, attains a peak and then decreases with the increase in equivalence ratio. The gas flow rate per unit weight of the fuel increases linearly with equivalence ratio. It is also observed that complete conversion of carbon to gaseous fuel has not taken place even for the optimum equivalence ratio.

Analysis of biomass-residue-based cogeneration system in palm oil mills

Abstract Palm oil mills in Malaysia operate on cogeneration system using biomass residue as fuel in the boiler. The boiler produces high pressure and temperature steam which expands in a backpressure steam turbine and produces enough electric power for the internal needs of the mill. The exhaust steam from the turbine goes to an accumulator which distributes the steam to various processes in the mill. The study were made on seven palm oil mills in the Perak state in Malaysia. The primary objectives of the study are to determine boiler and turbine efficiencies, energy utilization factor, oil extraction rate and heat/power ratio for various palm oil mills working under similar conditions and adopting same processes. The palm oil industry is one of those rare industries where very little attempt is made to save energy. The energy balance in a typical palm oil mill is far from optimum and there is considerable scope for improvement. Bench-marking is necessary for the components in the mill. Energy-use bench-marking can give an overview of energy performance of the mills. The calculations were done to get net gain in power when back pressure turbine is replaced by a condensing turbine. It was found that the boiler and turbine have low thermal efficiencies compared to conventional ones used in power plants due to non-homogeneity and non-uniform quality of the fuel. The extraction rate was around 0.188. The use of condensing turbine increase the power output by 60% and the utilization factor was found to be 65% for the cogeneration system.

Gasification of palm empty fruit bunch in a bubbling fluidized bed: A performance and agglomeration study

Gasification of palm empty fruit bunch (EFB) was investigated in a pilot-scale air-blown fluidized bed. The effect of bed temperature (650-1050 °C) on gasification performance was studied. To explore the potential of EFB, the gasification results were compared to that of sawdust. Results showed that maximum heating values (HHV) of 5.37 and 5.88 (MJ/Nm3), dry gas yield of 2.04 and 2.0 (Nm3/kg), carbon conversion of 93% and 85 % and cold gas efficiency of 72% and 71 % were obtained for EFB and sawdust at the temperature of 1050 °C and ER of 0.25. However, it was realized that agglomeration was the major issue in EFB gasification at high temperatures. To prevent the bed agglomeration, EFB gasification was performed at temperature of 770±20 °C while the ER was varied from 0.17 to 0.32. Maximum HHV of 4.53 was obtained at ER of 0.21 where no agglomeration was observed.

CO2 gasification reactivity of biomass char: catalytic influence of alkali, alkaline earth and transition metal salts.

This study investigates the influence of alkali (Na, K), alkaline earth (Ca, Mg) and transition (Fe) metal nitrates on CO2 gasification reactivity of pistachio nut shell (PNS) char. The preliminary gasification experiments were performed in thermogravimetric analyzer (TGA) and the results showed considerable improvement in carbon conversion; Na-char>Ca-char>Fe-char>K-char>Mg-char>raw char. Based on TGA studies, NaNO3 (with loadings of 3-7 wt%) was selected as the superior catalyst for further gasification studies in bench-scale reactor; the highest reactivity was devoted to 5 wt% Na loaded char. The data acquired for gasification rate of catalyzed char were fitted with several kinetic models, among which, random pore model was adopted as the best model. Based on obtained gasification rate constant and using the Arrhenius plot, activation energy of 5 wt% Na loaded char was calculated as 151.46 kJ/mol which was 53 kJ/mol lower than that of un-catalyzed char.

Microwave-enhanced CO2 gasification of oil palm shell char

CO2 gasification of oil palm shell (OPS) char to produce CO through the Boudouard reaction (C + CO2 ↔ 2CO) was investigated under microwave irradiation. A microwave heating system was developed to carry out the CO2 gasification in a packed bed of OPS char. The influence of char particle size, temperature and gas flow rate on CO2 conversion and CO evolution was considered. It was attempted to improve the reactivity of OPS char in gasification reaction through incorporation of Fe catalyst into the char skeleton. Very promising results were achieved in our experiments, where a CO2 conversion of 99% could be maintained during 60 min microwave-induced gasification of iron-catalyzed char. When similar gasification experiments were performed in conventional electric furnace, the superior performance of microwave over thermal driven reaction was elucidated. The activation energies of 36.0, 74.2 and 247.2 kJ/mol were obtained for catalytic and non-catalytic microwave and thermal heating, respectively.

Co-gasification of tire and biomass for enhancement of tire-char reactivity in CO2 gasification process

In this investigation, palm empty fruit bunch (EFB) and almond shell (AS) were implemented as two natural catalysts rich in alkali metals, especially potassium, to enhance the reactivity of tire-char through co-gasification process. Co-gasification experiments were conducted at several blending ratios using isothermal Thermogravimetric analysis (TGA) under CO2. The pronounced effect of inherent alkali content of biomass-chars on promoting the reactivity of tire-char was proven when acid-treated biomass-chars did not exert any catalytic effect on improving the reactivity of tire-char in co-gasification experiments. In kinetic studies of the co-gasified samples in chemically-controlled regime, modified random pore model (M-RPM) was adopted to describe the reactive behavior of the tire-char/biomass-char blends. By virtue of the catalytic effect of biomass, the activation energy for tire-char gasification was lowered from 250 kJ/mol in pure form 203 to 187 kJ/mol for AS-char and EFB-char co-gasified samples, respectively.

Optimization of thermal resistance of stacked micro‐channel using genetic algorithms

Purpose – To determine the optimal dimensions for a stacked micro‐channel using the genetic algorithms (GAs) under different flow constraints.Design/methodology/approach – GA is used as an optimization tool for optimizing the thermal resistance of a stacked micro‐channel under different flow constraints obtained by using the one dimensional (1D) and two dimensional (2D) finite element methods (FEM) and by thermal resistance network model as well (proposed by earlier researcher). The 2D FEM is used to study the effect of two dimensional heat conduction in the micro‐channel material. Some parametric studies are carried out to determine the resulting performance of the stacked micro‐channel. Different number of layers of the stacked micro‐channel is also investigated to study its effect on the minimum thermal resistance.Findings – The results obtained from the 1D FEM analysis compare well with those obtained from the thermal resistance network model. However, the 2D FEM analysis results in lower thermal resi...

Ash of palm empty fruit bunch as a natural catalyst for promoting the CO2 gasification reactivity of biomass char

Palm empty fruit bunch ash (EFB-ash) was used as a natural catalyst, rich in potassium to enhance the CO2 gasification reactivity of palm shell char (PS-char). Various EFB-ash loadings (ranging from 0 to 12.5wt.%) were implemented to improve the reactivity of PS-char during CO2 gasification studies using thermogravimetric analysis. The achieved results explored that the highest gasification reactivity was devoted to 10% EFB-ash loaded char. The SEM-EDS and XRD analyses further confirmed the successful loading of EFB-ash on PS-char which contributed to promoting the gasification reactivity of char. Random pore model was applied to determine the kinetic parameters in catalytic gasification of char at various temperatures of 800-900°C. The dependence of char reaction rate on gasification temperature resulted in a straight line in Arrhenius-type plot, from which the activation energy of 158.75kJ/mol was obtained for the catalytic char gasification.

Thermocatalytic treatment of biomass tar model compounds via radio frequency.

A new effective RF tar thermocatalytic treatment process with low energy intensive has been proposed to remove tar from biomass gasification. Toluene and naphthalene as biomass tar model compounds were removed via both thermal and catalytic treatment over a wide temperature range from 850 °C to 1200 °C and 450 °C to 900 °C, respectively at residence time of 0-0.7 s. Thermal characteristics of the new technique are also described in this paper. This study clearly clarified that toluene was much easier to be removed than naphthalene. Soot was found as the final product of thermal treatment of the tar model and completely removed during catalytic treatment. Radical reactions generated by RF non-thermal effect improve the tar removal. The study showed that Y-zeolite has better catalytic activity compared to dolomite on toluene and naphthalene removal due to its acidic nature and large surface area, even at lower reaction temperature of about 550 °C.

Study on kinetic model of microwave thermocatalytic treatment of biomass tar model compound.

Kinetic model parameters for toluene conversion under microwave thermocatalytic treatment were evaluated. The kinetic rate constants were determined using integral method based on experimental data and coupled with Arrhenius equation for obtaining the activation energies and pre-exponential factors. The model provides a good agreement with the experimental data. The kinetic model was also validated with standard error of 3% on average. The extrapolation of the model showed a reasonable trend to predict toluene conversion and product yield both in thermal and catalytic treatments. Under microwave irradiation, activation energy of toluene conversion was lower in the range of 3-27 kJ mol(-1) compared to those of conventional heating reported in the literatures. The overall reaction rate was six times higher compared to conventional heating. As a whole, the kinetic model works better for tar model removal in the absence of gas reforming within a level of reliability demonstrated in this study.