Zhang Lan

Uranium extraction from simulated salt lake water by an amidoxime-based UHMWPE fiber

A batch of amidoxime (AO)-based ultra-high molecular weight polyethylene (UHMWPE- g -(PAO-co-PAA)) fiber was prepared by a 7u2005L graft polymerization reaction kettle. The chemical structure and morphology were evaluated by means of Fourier transform infrared spectrometry and scanning electron microscope, respectively. The uranium adsorption behaviors of the UHMWPE- g -(PAO-co-PAA) fiber were studied by batch adsorption in simulated salt lake water. Effect of the total dissolved solids (TDS) and initial concentration of uranium on the adsorption behaviors of the fiber was investigated. It was found that after 28u2005d adsorption in the simulated DagzeCo salt lake water, UHMWPE- g -(PAO-co-PAA) fiber with an AO density of 6.0u2005mmolu2005g−1 exhibited a uranium adsorption capacity of 8.29u2005mgu2005g−1. The adsorption capacity decreased with the increment of TDS. In the simulated salt lake water in which TDS was 10 times as the sea water, the adsorption capacity of uranium was 6.63u2005mgu2005g−1. The adsorption capacity increased with the increment of initial concentration of uranium in solution. The uranium adsorption capacity was 4.54u2005mgu2005g−1 in a solution with initial concentration of 187u2005µgu2005L−1 uranium, while the value increased to 17.48u2005mgu2005g−1 with 1639u2005µgu2005L−1 uranium simulated salt lake water solution. This study should shed light on improvement of uranium extraction from salt lake water and further application in uranium recovery from natural resources.