Zulkiflle Leman

Sugar palm (Arenga pinnata): Its fibres, polymers and composites

Sugar palm (Arenga pinnata) is a multipurpose palm species from which a variety of foods and beverages, timber commodities, biofibres, biopolymers and biocomposites can be produced. Recently, it is being used as a source of renewable energy in the form of bio-ethanol via fermentation process of the sugar palm sap. Although numerous products can be produced from sugar palm, three products that are most prominent are palm sugar, fruits and fibres. This paper focuses mainly on the significance of fibres as they are highly durable, resistant to sea water and because they are available naturally in the form of woven fibre they are easy to process. Besides the recent advances in the research of sugar palm fibres and their composites, this paper also addresses the development of new biodegradable polymer derived from sugar palm starch, and presents reviews on fibre surface treatment, product development, and challenges and efforts on properties enhancement of sugar palm fibre composites.

The Effect of Environmental Treatments on Fiber Surface Properties and Tensile Strength of Sugar Palm Fiber-Reinforced Epoxy Composites

Fiber glass has been used widely in manufacturing industries, especially marine industries, because of low cost and high strength. However, glass fiber can cause acute irritation to the skin, eyes, and upper respiratory tract. This study looked at the possibility of substituting glass fiber with natural fiber in composite materials. The surface properties of sugar palm fiber (Arenga pinnata) were modified using seawater and freshwater as treatment substances. This led to biological, chemical, and water degradation of the sugar palm fiber. Morphological and structural changes in the fibers were investigated using a scanning electron microscope (SEM). A series of tensile tests based on ASTM D638-99 was carried out on epoxy composites with 15% sugar palm fiber by volume. It was found that seawater and freshwater treatments improved the surface properties of the sugar palm fiber and thus resulted in better adhesion quality as compared to untreated fiber. An improvement in tensile strength also supported this finding. Treatment with seawater for 30 days proved to be the best, with 67.26% increase in tensile strength.

Mechanical properties of kenaf bast and core fibre reinforced unsaturated polyester composites

Kenaf fibre has high potential to be used for composite reinforcement in biocomposite material. It is made up of an inner woody core and an outer fibrous bark surrounding the core. The aim of this study was to compare the mechanical properties of short kenaf bast and core fibre reinforced unsaturated polyester composites with varying fibre weight fraction i.e. 0%, 5%, 10%, 20%, 30% and 40%. The compression moulding technique was used to prepare the composite specimens for tensile, flexural and impact tests in accordance to the ASTM D5083, ASTM D790 and ASTM D256 respectively. The overall results showed that the composites reinforced with kenaf bast fibre had higher mechanical properties than kenaf core fibre composites. The results also showed that the optimum fibre content for achieving highest tensile strength for both bast and core fibre composites was 20%wt. It was also observed that the elongation at break for both composites decreased as the fibre content increased. For the flexural strength, the optimum fibre content for both composites was 10%wt while for impact strength, it was at 10%wt and 5%wt for bast and core fibre composites respectively.

Mechanical properties and fabrication of small boat using woven glass/sugar palm fibres reinforced unsaturated polyester hybrid composite

In recent years, sugar palm fibre has been found to have great potential to be used as fibre reinforcement in polymer matrix composites. This research investigates the mechanical properties of woven glass/sugar palm fibres reinforced unsaturated polyester hybrid composite. The composite specimens made of different layer of fibres such as strand mat, natural and hand woven of sugar palm fibres. The composites were fabricated using a compression moulding technique. The tensile and impact test was carried out in accordance to ASTM 5083 and ASTM D256 standard. The fibre glass boat is a familiar material used in boat industry. A lot of research on fabrication process such as lay-up, vacuum infusion mould and resin transfer mould has been conducted. Hybrid material of sugar palm fibre and fibre glass was used in fabricating the boat. This research investigates the method selection for fabrication of small boat application of natural fibre composites. The composite specimens made of different layer of fibres; woven glass fibre, strand mat, natural and hand woven of woven sugar palm fibres were prepared. The small boat were fabricated using a compression moulding and lay up technique. The results of the experiment showed that the tensile strength, tensile modulus, elongation at break value and impact strength were higher than the natural woven sugar palm fibre. The best method for fabricating the small boat was compression moulding technique. As a general conclusion, the usage of glass fibre had improved the tensile properties sugar palm fibre composites and compression moulding technique is suitable to be used in making a small boat application of natural fibre composites.

Mechanical performance of woven kenaf-Kevlar hybrid composites

Hybrid composites offer a combination of advantages of constituent components to produce a material with determined properties. In the present work, woven hybrid composite was prepared by hand lay-up method in laminate configuration. Kevlar/kenaf hybrid composites were fabricated with total fibre content of 30% and the ratio of Kevlar/kenaf varies in weight fraction of 78/22, 60/40, 50/50, 26/74, and 32/68, respectively. The Kevlar/epoxy and kenaf/epoxy were also prepared for comparison. The mechanical properties of hybrid, kenaf/epoxy, and Kevlar/epoxy composites were tested. Morphological properties of tensile fracture surface of hybrid composites were studied by scanning electron microscopy. Results have established that the mechanical properties of kenaf-Kevlar hybrid composites are a function of fibre content. The hybrid composites with Kevlar/kenaf (78/22) ratio exhibited better mechanical properties compared to other hybrid composites. This result indicates the potential of Kevlar-kenaf hybrid composite for impact applications.

Physicochemical and thermal properties of lignocellulosic fiber from sugar palm fibers: effect of treatment

Sugar palm fiber (SPF) is one of the prospective fibers used to reinforce polymer composites. The aim of this study is to evaluate the physicochemical, thermal, and morphological properties of SPF after alkali and sea water treatments. The chemical constituents group and thermal stability of the SPF were determined using scanning electronic microscopy (SEM) along with energy dispersive X-ray spectroscopy and thermogravimetric analysis (TGA). Fourier transform infrared spectroscopy was carried out to detect the presence of functional groups in untreated and treated SPF. The SEM images after both treatments showed that the external surface of the fiber became clean as a result. However, the sea water treatment affected the fiber properties physically, while the alkali treatment affected it both physically and chemically by dissolving the hemicellulose in the fiber. The TGA results showed that untreated fiber is significantly more stable than treated fiber. In conclusion, the results show that the fiber surface treatment significantly affected the characterization of the fiber.

Reviewing the Literature of Inventory Models under Trade Credit Contact

In the classical inventory models, it was assumed that the buyer pays for the purchased items as they are received from the seller. In practice, however, the seller allows the buyer to settle the account with a delay period. Such a contract has attracted the attention of many researchers and practitioners in recent years. Thus, this paper addresses the researches with delay in payment and presents pertinent information about developments and extensions of such models to provide an up-to-date review of the studies conducted since 1973 and assist in developing the future researches.

A review on the characterisation of natural fibres and their composites after alkali treatment and water absorption

ABSTRACT Natural fibre-reinforced polymer matrix composites are gaining increased attention among the researchers due to their low density, biodegradability, abundance, good mechanical properties, etc. Significant amount of research works can be found on the material characterisation of natural fibres like hemp, flax, sisal, kenaf, coir and jute and their composites based on the polymer matrices. Natural fibres are hydrophilic in nature and exhibit poor interfacial adhesion between fibre and matrix. Modification of the fibre surface by chemical methods, such as alkalisation, benzoylation and acetylation, has been used by researchers to improve the above-mentioned shortcomings. This review paper focuses on the effect of alkali treatment on the material properties of various natural fibres and their composites along with their water absorption behaviour.

Modeling for Green Supply Chain Evaluation

Green supply chain management (GSCM) has become a practical approach to develop environmental performance. Under strict regulations and stakeholder pressures, enterprises need to enhance and improve GSCM practices, which are influenced by both traditional and green factors. This study developed a causal evaluation model to guide selection of qualified suppliers by prioritizing various criteria and mapping causal relationships to find effective criteria to improve green supply chain. The aim of the case study was to model and examine the influential and important main GSCM practices, namely, green logistics, organizational performance, green organizational activities, environmental protection, and green supplier evaluation. In the case study, decision-making trial and evaluation laboratory technique is applied to test the developed model. The result of the case study shows only “green supplier evaluation” and “green organizational activities” criteria of the model are in the cause group and the other criteria are in the effect group.

Effects of Impregnation Pressure on Physical and Tensile Properties of Impregnated Sugar Palm (Arenga pinnata) Fibres

The aim of this study is to investigate the effect of impregnation pressure on physical and tensile properties of sugar palm (Arenga pinnata) fibres. The fibre was impregnated with phenol formaldehyde (PF) and unsaturated polyester (UP) with different impregnation pressures (1000, 900, 800, 700, 600 and 500 mmHg) at constant impregnation time of 5 min. Significant improvement in physical properties was observed due to reduction of moisture content (MC) and water absorption (WA) after being impregnated from 1000 to 500 mmHg while PF-impregnated fibre was showing more superior. Improvement in mechanical properties was also observed after being impregnated where much better tensile properties and toughness were found at UP-impregnated fibres while PF-impregnated fibres were found to be very much lower in toughness. This study concluded that in order to obtain a high toughness and better physical properties of sugar palm fibre, the fibre should be impregnated with UP resin with impregnation pressure of 600 mmHg.