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Proceedings of the National Academy of Sciences of the United States of America | 2013

Measurements of methane emissions at natural gas production sites in the United States

David T. Allen; Vincent M. Torres; James Thomas; David W. Sullivan; Matthew T. Harrison; Al Hendler; Scott C. Herndon; Charles E. Kolb; Matthew P. Fraser; A. Daniel Hill; Brian K. Lamb; Jennifer Lynne Miskimins; Robert F. Sawyer; John H. Seinfeld

Significance This work reports direct measurements of methane emissions at 190 onshore natural gas sites in the United States. The measurements indicate that well completion emissions are lower than previously estimated; the data also show emissions from pneumatic controllers and equipment leaks are higher than Environmental Protection Agency (EPA) national emission projections. Estimates of total emissions are similar to the most recent EPA national inventory of methane emissions from natural gas production. These measurements will help inform policymakers, researchers, and industry, providing information about some of the sources of methane emissions from the production of natural gas, and will better inform and advance national and international scientific and policy discussions with respect to natural gas development and use. Engineering estimates of methane emissions from natural gas production have led to varied projections of national emissions. This work reports direct measurements of methane emissions at 190 onshore natural gas sites in the United States (150 production sites, 27 well completion flowbacks, 9 well unloadings, and 4 workovers). For well completion flowbacks, which clear fractured wells of liquid to allow gas production, methane emissions ranged from 0.01 Mg to 17 Mg (mean = 1.7 Mg; 95% confidence bounds of 0.67–3.3 Mg), compared with an average of 81 Mg per event in the 2011 EPA national emission inventory from April 2013. Emission factors for pneumatic pumps and controllers as well as equipment leaks were both comparable to and higher than estimates in the national inventory. Overall, if emission factors from this work for completion flowbacks, equipment leaks, and pneumatic pumps and controllers are assumed to be representative of national populations and are used to estimate national emissions, total annual emissions from these source categories are calculated to be 957 Gg of methane (with sampling and measurement uncertainties estimated at ±200 Gg). The estimate for comparable source categories in the EPA national inventory is ∼1,200 Gg. Additional measurements of unloadings and workovers are needed to produce national emission estimates for these source categories. The 957 Gg in emissions for completion flowbacks, pneumatics, and equipment leaks, coupled with EPA national inventory estimates for other categories, leads to an estimated 2,300 Gg of methane emissions from natural gas production (0.42% of gross gas production).


Environmental Science & Technology | 2015

Methane Emissions from Process Equipment at Natural Gas Production Sites in the United States: Pneumatic Controllers

David T. Allen; Adam P. Pacsi; David W. Sullivan; Daniel Zavala-Araiza; Matthew Harrison; Kindal Keen; Matthew P. Fraser; A. Daniel Hill; Robert F. Sawyer; John H. Seinfeld

Emissions from 377 gas actuated (pneumatic) controllers were measured at natural gas production sites and a small number of oil production sites, throughout the United States. A small subset of the devices (19%), with whole gas emission rates in excess of 6 standard cubic feet per hour (scf/h), accounted for 95% of emissions. More than half of the controllers recorded emissions of 0.001 scf/h or less during 15 min of measurement. Pneumatic controllers in level control applications on separators and in compressor applications had higher emission rates than controllers in other types of applications. Regional differences in emissions were observed, with the lowest emissions measured in the Rocky Mountains and the highest emissions in the Gulf Coast. Average methane emissions per controller reported in this work are 17% higher than the average emissions per controller in the 2012 EPA greenhouse gas national emission inventory (2012 GHG NEI, released in 2014); the average of 2.7 controllers per well observed in this work is higher than the 1.0 controllers per well reported in the 2012 GHG NEI.


Environmental Science & Technology | 2015

Methane Emissions from Process Equipment at Natural Gas Production Sites in the United States: Liquid Unloadings

David T. Allen; David W. Sullivan; Daniel Zavala-Araiza; Adam P. Pacsi; Matthew Harrison; Kindal Keen; Matthew P. Fraser; A. Daniel Hill; Brian K. Lamb; Robert F. Sawyer; John H. Seinfeld

Methane emissions from liquid unloadings were measured at 107 wells in natural gas production regions throughout the United States. Liquid unloadings clear wells of accumulated liquids to increase production, employing a variety of liquid lifting mechanisms. In this work, wells with and without plunger lifts were sampled. Most wells without plunger lifts unload less than 10 times per year with emissions averaging 21,000-35,000 scf methane (0.4-0.7 Mg) per event (95% confidence limits of 10,000-50,000 scf/event). For wells with plunger lifts, emissions averaged 1000-10,000 scf methane (0.02-0.2 Mg) per event (95% confidence limits of 500-12,000 scf/event). Some wells with plunger lifts are automatically triggered and unload thousands of times per year and these wells account for the majority of the emissions from all wells with liquid unloadings. If the data collected in this work are assumed to be representative of national populations, the data suggest that the central estimate of emissions from unloadings (270 Gg/yr, 95% confidence range of 190-400 Gg) are within a few percent of the emissions estimated in the EPA 2012 Greenhouse Gas National Emission Inventory (released in 2014), with emissions dominated by wells with high frequencies of unloadings.


Volume 6: Polar and Arctic Sciences and Technology; Offshore Geotechnics; Petroleum Technology Symposium | 2013

Propped Fracture Conductivity in Shales

Junjing Zhang; Anton Kamenov; Ding Zhu; A. Daniel Hill

The successful development of the major shale gas plays in North America hinges upon the creation of complicated fracture networks by pumping low viscosity fracturing fluid with low proppant concentrations at high flow rate. Direct laboratory measurement of hydraulic fracture conductivity created in the networks is needed for reliable well performance analysis and fracture design optimization.A series of experiments were conducted under realistic hydraulic fracturing conditions to measure the conductivity using a modified API conductivity cell. Natural fractures were preserved and fracture infill was kept for initial conductivity measurement. Fractures were also induced along the natural bedding planes to obtain fracture surface asperities. Proppants of various sizes were placed between rough fracture surfaces at realistic concentrations. The two sides of the rough fractures were either aligned or displaced with a 0.1 inch offset.Results show that the hydraulic fracture conductivity of shale samples with rough surfaces can be accurately measured in a laboratory with appropriate experimental procedures and good control on experimental errors. The unpropped offset fracture can create conductivity as much as poorly cemented natural fracture, while the conductivity of unpropped matched fracture is minor. The presence of proppants can elevate the fracture conductivity by 2 to 3 orders of magnitude. Propped fracture conductivity increases with larger proppant size and higher proppant concentration. This study also indicates that within 20 hours propped fracture conductivity can be reduced by as much as 24% as shown in the longer term fracture conductivity measurements.Copyright


Spe Production & Operations | 2016

Water-Induced Damage to Propped-Fracture Conductivity in Shale Formations

Junjing Zhang; Ding Zhu; A. Daniel Hill


Spe Journal | 2017

Theoretical and Experimental Study on Optimal Injection Rates in Carbonate Acidizing

Kai Dong; Ding Zhu; A. Daniel Hill


Journal of Petroleum Science and Engineering | 2015

A new theoretical method to calculate shale fracture conductivity based on the population balance equation

Junjing Zhang; Ding Zhu; A. Daniel Hill


Journal of Petroleum Science and Engineering | 2018

The role of temperature on optimal conditions in dolomite acidizing: An experimental study and its applications

Kai Dong; Ding Zhu; A. Daniel Hill


Journal of Petroleum Technology | 2013

Deja vu All Over Again

A. Daniel Hill; Stephen A. Holditch


Journal of Petroleum Science and Engineering | 2018

Mechanism of wormholing and its optimal conditions: A fundamental explanation

Kai Dong; Ding Zhu; A. Daniel Hill

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David T. Allen

University of Texas at Austin

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David W. Sullivan

University of Texas at Austin

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John H. Seinfeld

California Institute of Technology

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Brian K. Lamb

Washington State University

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Adam P. Pacsi

University of Texas at Austin

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