Agnieszka Gałuszka

Polynuclear aromatic hydrocarbons, phenols, and trace metals in selected soil profiles and plant bioindicators in the Holy Cross Mountains, South-Central Poland

This report presents the results of PAH, phenol, and selected trace element (Cd, Cu, Hg, Pb, S, and Zn) determinations on detailed soil profiles and associated plant bioindicators (including lichen Hypogymnia physodes, moss Hylocomium splendens, pine Pinus sylvetris) from the three most representative habitats in the Holy Cross Mts, south-central Poland. This study is only part of a larger ongoing environmental study that includes complex sulfur isotope and element determinations in three national parks in N, central and S parts of Poland. The highest concentrations of PAHs (1887 ppb) and numerous trace elements are found in the organic horizon-O and humic horizon-A of each soil type. Different plant species and their individual tissues reveal considerable variability in the concentration of PAHs, phenols and elements examined. Most of the H. physodes thalli also reveal higher concentrations of individual hydrocarbons and some elements (including S and Zn) than their host bark. The highest concentration levels of phenols (1217 ppb) are noted in the 1-year pine needles. Most of the PAHs and elements examined seem to be of anthropogenic origin. The only exception is the distribution pattern of elements in southwestern part of the study area, which is linked to the local bedrock geochemical anomaly. The results of this study indicate that the content of PAHs, Cd, Cu, Hg, Pb, S and Zn in the soils and plant bioindicators examined has not changed considerably since 1998.

The Characteristics, Occurrence, and Geochemical Behavior of Rare Earth Elements in the Environment: A Review

The increasing number of rare earth elements (REEs) studies in the past decade has been induced by their wider applications in industry, including electronics and high technology. This review presents the brief characteristics of REE, their occurrence in abiotic and biotic systems, and their possible detrimental effects on the environmental quality and human health. This also outlines the REE behavior in different geochemical interactions and the potential for tracing anthropogenic pollution sources.

Moving your laboratories to the field - Advantages and limitations of the use of field portable instruments in environmental sample analysis

The recent rapid progress in technology of field portable instruments has increased their applications in environmental sample analysis. These instruments offer a possibility of cost-effective, non-destructive, real-time, direct, on-site measurements of a wide range of both inorganic and organic analytes in gaseous, liquid and solid samples. Some of them do not require the use of reagents and do not produce any analytical waste. All these features contribute to the greenness of field portable techniques. Several stationary analytical instruments have their portable versions. The most popular ones include: gas chromatographs with different detectors (mass spectrometer (MS), flame ionization detector, photoionization detector), ultraviolet-visible and near-infrared spectrophotometers, X-ray fluorescence spectrometers, ion mobility spectrometers, electronic noses and electronic tongues. The use of portable instruments in environmental sample analysis gives a possibility of on-site screening and a subsequent selection of samples for routine laboratory analyses. They are also very useful in situations that require an emergency response and for process monitoring applications. However, quantification of results is still problematic in many cases. The other disadvantages include: higher detection limits and lower sensitivity than these obtained in laboratory conditions, a strong influence of environmental factors on the instrument performance and a high possibility of sample contamination in the field. This paper reviews recent applications of field portable instruments in environmental sample analysis and discusses their analytical capabilities.

Green Chemistry Metrics with Special Reference to Green Analytical Chemistry

The concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor, EATOS, and Eco-Scale are described. Both the well-established and recently developed green analytical chemistry metrics, including NEMI labeling and analytical Eco-scale, are presented. Additionally, this paper focuses on the possibility of the use of multivariate statistics in evaluation of environmental impact of analytical procedures. All the above metrics are compared and discussed in terms of their advantages and disadvantages. The current needs and future perspectives in green chemistry metrics are also discussed.

Stratigraphic and Earth System approaches to defining the Anthropocene

Stratigraphy provides insights into the evolution and dynamics of the Earth System over its long history. With recent developments in Earth System science, changes in Earth System dynamics can now be observed directly and projected into the near future. An integration of the two approaches provides powerful insights into the nature and significance of contemporary changes to Earth. From both perspectives, the Earth has been pushed out of the Holocene Epoch by human activities, with the mid-20th century a strong candidate for the start date of the Anthropocene, the proposed new epoch in Earth history. Here we explore two contrasting scenarios for the future of the Anthropocene, recognizing that the Earth System has already undergone a substantial transition away from the Holocene state. A rapid shift of societies toward the UN Sustainable Development Goals could stabilize the Earth System in a state with more intense interglacial conditions than in the late Quaternary climate regime and with little further biospheric change. In contrast, a continuation of the present Anthropocene trajectory of growing human pressures will likely lead to biotic impoverishment and a much warmer climate with a significant loss of polar ice.

Colonization of the Americas, ‘Little Ice Age’ climate, and bomb-produced carbon: Their role in defining the Anthropocene

A recently published analysis by Lewis and Maslin (Lewis SL and Maslin MA (2015) Defining the Anthropocene. Nature 519: 171–180) has identified two new potential horizons for the Holocene−Anthropocene boundary: 1610 (associated with European colonization of the Americas), or 1964 (the peak of the excess radiocarbon signal arising from atom bomb tests). We discuss both of these novel suggestions, and consider that there is insufficient stratigraphic basis for the former, whereas placing the latter at the peak of the signal rather than at its inception does not follow normal stratigraphical practice. Wherever the boundary is eventually placed, it should be optimized to reflect stratigraphical evidence with the least possible ambiguity.

Can nuclear weapons fallout mark the beginning of the Anthropocene Epoch

Many scientists are making the case that humanity is living in a new geological epoch, the Anthropocene, but there is no agreement yet as to when this epoch began. The start might be defined by a historical event, such as the beginning of the fossil-fueled Industrial Revolution or the first nuclear explosion in 1945. Standard stratigraphic practice, however, requires a more significant, globally widespread, and abrupt signature, and the fallout from nuclear weapons testing appears most suitable. The appearance of plutonium 239 (used in post-1945 above-ground nuclear weapons tests) makes a good marker: This isotope is rare in nature but a significant component of fallout. It has other features to recommend it as a stable marker in layers of sedimentary rock and soil, including: long half-life, low solubility, and high particle reactivity. It may be used in conjunction with other radioactive isotopes, such as americium 241 and carbon 14, to categorize distinct fallout signatures in sediments and ice caps. On a global scale, the first appearance of plutonium 239 in sedimentary sequences corresponds to the early 1950s. While plutonium is easily detectable over the entire Earth using modern measurement techniques, a site to define the Anthropocene (known as a “golden spike”) would ideally be located between 30 and 60 degrees north of the equator, where fallout is maximal, within undisturbed marine or lake environments.

The influence of chloride deicers on mineral nutrition and the health status of roadside trees in the city of Kielce, Poland

Application of chemical road deicers has a negative impact on roadside vegetation. Every year, the trees in cities suffer from direct and indirect effects of salt application for winter road maintenance. To elucidate this problem in the city of Kielce, the chemistry of snow, soil, tree bark, and leaf samples has been investigated together with an assessment of the health status of the trees. Twelve investigation sites were selected along the roads with different traffic intensity. Snow samples were collected twice during the winter and analyzed for pH, EC, Na + , Ca2 + , Mg2 + , and Cl − . In soil (collected from two depth intervals), tree bark, and leaf samples, the concentrations of B, Ca, Fe, K, Mg, Mn, N, Na, P, S, and Zn were determined. The contents of total organic carbon (TOC) in soils, as well as the pH of soil and tree bark samples were also measured. Negative symptoms revealed by roadside trees included the loss of assimilative apparatus and decreased vitality. The results of chemical analyses indicated that the snowmelt might be a substantial source of chloride ions and alkalizing substances that influenced higher pH of soils. The soil samples displayed elevated concentrations of S and Zn and lower than typical for soil contents of B, Mg, and TOC. The pH of alkaline soils favored greater bioavailability of B and reduced bioavailability of Na and Zn by the trees examined.

Assessing the Anthropocene with geochemical methods

Abstract Anthropogenic chemical contamination is one of the most evident signals of human influence on the environment. The large amounts of industrially produced pollutants that have been introduced, over decades, into air, soil and water have caused modifications to natural elemental cycling. Anthropogenic contamination usually leads to enrichment in many elements, particularly in industrial areas. Thus, certain elements and their isotopes can be used as geochemical tracers of anthropogenic impact. Some human-induced changes in the environment may be regarded as a secondary effect of pollution, such as acidification, which causes increased geochemical mobility of several trace elements in surficial deposits. Methods used by geochemists to assess the scale of anthropogenic influence on the environment include calculations of anthropogenic influence on the environment via enrichment and contamination factors, geoaccumulation index and pollution load index. The use of geochemical background levels for delineating between natural and anthropogenic pollution is important. A historical perspective of anthropogenic contamination, allied with isotopic and geochemical signatures in dated sediment cores, may be applied to help define the Anthropocene.

ELEMENT CONCENTRATIONS IN SOILS AND PLANT BIOINDICATORS IN SELECTED HABITATS OF THE HOLY CROSS MOUNTAINS, POLAND

The objectives of this investigation in the HolyCross Mountain region of Poland were (1) to determineconcentration ranges and (2) mobility of elements within fivedetailed soil profiles and their apparent impact on thechemistry of some plant bioindicators, i.e. lichen thalli ofthe species Hypogymnia physodes (L.) Nyl. and Scotspine (Pinus sylvestris L.) bark. The results ofelemental determinations performed on soils and vegetationfrom the Holy Cross Mts show that some concentrations ofelements are elevated primarily due to air pollution.However, since 1994 a steady decrease in the content of S andsome heavy metals has been recorded in all the mediaexamined. Concentrations of many elements in H.physodes thalli and P. sylvestris needles of the Holy Cross Mountains are generally similarto those in other areas of Europe.