Alain Fave

Absorption enhancement using photonic crystals for silicon thin film solar cells

We propose a design that increases significantly the absorption of a thin layer of absorbing material such as amorphous silicon. This is achieved by patterning a one-dimensional photonic crystal (1DPC) in this layer. Indeed, by coupling the incident light into slow Bloch modes of the 1DPC, we can control the photon lifetime and then, enhance the absorption integrated over the whole solar spectrum. Optimal parameters of the 1DPC maximize the integrated absorption in the wavelength range of interest, up to 45% in both S and P polarization states instead of 33% for the unpatterned, 100 nm thick amorphous silicon layer. Moreover, the absorption is tolerant with respect to fabrication errors, and remains relatively stable if the angle of incidence is changed.

Combined front and back diffraction gratings for broad band light trapping in thin film solar cell

In this paper, we present the integration of combined front and back 1D and 2D diffraction gratings with different periods, within thin film photovoltaic solar cells based on crystalline silicon layers. The grating structures have been designed considering both the need for incident light absorption enhancement and the technological feasibility. Long wavelength absorption is increased thanks to the long period (750 nm) back grating, while the incident light reflection is reduced by using a short period (250 nm) front grating. The simulated short circuit current in a solar cell combining a front and a back grating structures with a 1.2 µm thick c-Si layer, together with the back electrode and TCO layers, is increased up to 30.3 mA/cm2, compared to 18.4 mA/cm2 for a reference stack, as simulated using the AM1.5G solar spectrum intensity distribution from 300 nm to 1100 nm, and under normal incidence.

Absorbing one-dimensional planar photonic crystal for amorphous silicon solar cell

We report on the absorption of a 100nm thick hydrogenated amorphous silicon layer patterned as a planar photonic crystal (PPC), using laser holography and reactive ion etching. Compared to an unpatterned layer, electromagnetic simulation and optical measurements both show a 50% increase of the absorption over the 0.38-0.75micron spectral range, in the case of a one-dimensional PPC. Such absorbing photonic crystals, combined with transparent and conductive layers, may be at the basis of new photovoltaic solar cells.

Two-dimensional photonic crystal for absorption enhancement in hydrogenated amorphous silicon thin film solar cells

We propose a photovoltaic solar cell design based on a 100 nm thick absorbing layer made of hydrogenated amorphous silicon and patterned as a two-dimensional planar photonic crystal (PPC). After scanning the parameters of the PPC within the patterned cell, optical simulations performed on the best configuration obtained reveal that a relative increase in the integrated absorption inside the active layer of 28% can be expected between 300 and 720 nm compared to an equivalent but nonpatterned cell under normal incidence. Besides, this integrated absorption is found to be robust toward the angle of incidence. Incident light is efficiently coupled to leaky mode resonances of the PPC provided an appropriated tuning of its parameters. The effects of the reflectance of the back contact coupled to a conductive optical spacer on the absorption are also discussed.

Design, fabrication and optical characterization of photonic crystal assisted thin film monocrystalline-silicon solar cells.

In this paper, we present the integration of an absorbing photonic crystal within a monocrystalline silicon thin film photovoltaic stack fabricated without epitaxy. Finite difference time domain optical simulations are performed in order to design one- and two-dimensional photonic crystals to assist crystalline silicon solar cells. The simulations show that the 1D and 2D patterned solar cell stacks would have an increased integrated absorption in the crystalline silicon layer would increase of respectively 38% and 50%, when compared to a similar but unpatterned stack, in the whole wavelength range between 300 nm and 1100 nm. In order to fabricate such patterned stacks, we developed an effective set of processes based on laser holographic lithography, reactive ion etching and inductively coupled plasma etching. Optical measurements performed on the patterned stacks highlight the significant absorption increase achieved in the whole wavelength range of interest, as expected by simulation. Moreover, we show that with this design, the angle of incidence has almost no influence on the absorption for angles as high as around 60°.

Light harvesting by planar photonic crystals in solar cells: the case of amorphous silicon

In this paper, we discuss on light management in silicon thin film solar cells, using photonic crystals (PhC) structures. We particularly focus on photovoltaic devices including amorphous silicon absorbers patterned as 2D PhCs. Physical principles and design rules leading to the optimized configuration of the patterned cell are discussed by means of optical simulations performed on realistic thin film solar cell stacks. Theoretically, a maximum 40%rel increase of integrated absorption in the a-Si:H layer of the patterned cell is expected compared to the unpatterned case. Moreover, both simulation and optical characterization of the fabricated cells demonstrate the robustness of their optical properties with regards to the angle of incidence of the light and to the fabrication induced defects in the PhCs. Finally, the impact of the surface recombination due to the generation of new free surfaces with higher defect densities is addressed. We demonstrate that patterning still induces a substantial increase of the conversion efficiency, with a reasonable surface recombination velocity.

New method of parameters extraction from dark I-V curve

It is very necessary, for solar cells, to obtain a low series resistance and to be able to determine it with accuracy because it is an important parameter of fill factor and efficiency improvement. In the case of low series resistance, we have developed a new method of parameters extraction from only one dark I-V characteristic. We have also improved another technique (the integral) of series resistance extraction. We have compared these two methods to two other ones (the derivative and the Lee et al. method). Our method gives very good results. Moreover it is very simple to use and presents the advantage of being independent of the voltage step in contrary to the derivative and to the integral. We have then applied our technique to a whole solar cell I-V curve and the results are very good.

Micrometer-Thin Crystalline-Silicon Solar Cells Integrating Numerically Optimized 2-D Photonic Crystals

A 2-D photonic crystal was integrated experimentally into a thin-film crystalline-silicon solar cell of 1-μm thickness, after numerical optimization maximizing light absorption in the active material. The photonic crystal boosted the short-circuit current of the cell, but it also damaged its open-circuit voltage and fill factor, which led to an overall decrease in performances. Comparisons between modeled and actual optical behaviors of the cell, and between ideal and actual morphologies, show the global robustness of the nanostructure to experimental deviations, but its particular sensitivity to the conformality of the top coatings and the spread in pattern dimensions, which should not be neglected in the optical model. As for the electrical behavior, the measured internal quantum efficiency shows the strong parasitic absorptions from the transparent conductive oxide and from the back-reflector, as well as the negative impact of the nanopattern on surface passivation. Our exemplifying case, thus, illustrates and experimentally confirms two recommendations for future integration of surface nanostructures for light trapping purposes: 1) the necessity to optimize absorption not for the total stack but for the single active material, and 2) the necessity to avoid damage to the active material by pattern etching.

Photonic crystal assisted ultra-thin silicon photovoltaic solar cell

A new concept of ultra-thin film photovoltaic solar cell including a planar photonic crystal is proposed. The goal is to couple the incident light into broad resonances guided in the absorbing layer. To achieve this, a periodic lattice is patterned within the active layer, for example made of holes in amorphous silicon. By adjusting the pattern dimensions, the spectral position and quality factor of these resonances can be controlled so as to optimise the global absorption. Design details will be discussed in this communication.

Design and fabrication of photonic crystals in epitaxial free silicon for ultrathin solar cells

In this paper, we present the integration of an absorbing photonic crystal within a thin film photovoltaic solar cell. Optical simulations performed on a complete solar cell revealed that patterning the epitaxial crystalline silicon active layer as a 1D and 2D photonic crystal enabled to increase its integrated absorption by 37%abs and 68%abs between 300 nm and 1100 nm, compared to a similar but unpatterned stack. In order to fabricate such promising cells, a specific fabrication processes based on holographic lithography, inductively coupled plasma etching and reactive ion etching has been developed and implemented to obtain ultrathin patterned solar cells.