Anna Gioncada

Petrology of volcanic products younger than 42 ka on the Lipari-Vulcano complex (Aeolian Islands, Italy): an example of volcanism controlled by tectonics

Abstract Over the last 42 ka, volcanic activity at Lipari Island (Aeolian Arc, Italy) produced lava domes, flows and pyroclastic deposits with rhyolitic composition, showing in many cases evidence of magma mixing such as latitic enclaves and banding. In this same period, on nearby Vulcano Island, similar rhyolitic lava domes, pyroclastic products and lava flows, ranging in composition from shoshonite to rhyolite, were erupted. As a whole, the post-42 ka products of Lipari and Vulcano show geochemical variations with time, which are well correlated between the two islands and may correspond to a modification of the primary magmas. The rhyolitic products are similar to each other in their major elements composition, but differ in their trace element abundances (e.g. La ranging from 40 to 78 ppm for SiO2 close to 75 wt%). Their isotopic composition is variable, too. The 87Sr/86Sr (0.704723–0.705992) and 143Nd/144Nd (0.512575–0.512526) ranges partially overlap those of the more mafic products (latites), having 87Sr/86Sr from 0.7044 to 0.7047 and 143Nd/144Nd from 0.512672 to 0.512615. 206Pb/204Pb is 19.390–19.450 in latites and 19.350–19.380 in rhyolites. Crystal fractionation and crustal assimilation processes of andesitic to latitic melts, showing an increasing content in incompatible elements in time, may explain the genesis of the different rhyolitic magmas. The rocks of the local crustal basement assimilated may correspond to lithotypes present in the Calabrian Arc. Mixing and mingling processes between latitic and rhyolitic magmas that are not genetically related occur during most of the eruptions. The alignment of vents related to the volcanic activity of the last 40 ka corresponds to the NNW–SSE Tindari–Letojanni strike-slip fault and to the correlated N–S extensional fault system. The mafic magmas erupted along these different directions display evidence of an evolution at different PH2O conditions. This suggests that the Tindari–Letojanni fault played a relevant role in the ascent, storage and diversification of magmas during the recent volcanic activity.

The deep structure of the Eolian arc (Filicudi-Panarea-Vulcano sector) in light of gravity, magnetic and volcanological data

Abstract The magnetic and gravimetric methods of investigation have been applied to the central sector of the Eolian arc, combined with geovolcanological data, for the purpose of defining the structural framework in which the volcanism developed. The processing of the magnetic and gravimetric data involved 3D modeling of the volcanic bodies and the application of a “depth separation filter”, in order to subtract from the measured field the effect caused by the subaerial and submarine volcanic edifices and by all surface inhomogeneities. Magnetic and gravimetric 2.5D modeling on selected profiles has also been done, in a joint interpretation of the magnetic and gravimetric data, constrained by volcanological knowledge. The interpretation of the final maps and profiles has demonstrated the existence of extensional tectonics, resulting in the development of horst and graben. Volcanism occurs in the graben areas. In particular, the Salina-Lipari-Vulcano magmatic axis has developed in a very deep articulated graben of lithospheric importance and completely filled by volcanic deposits and intrusive bodies. The origin of this structure and of the associated igneous activity is suggested to be related to trans-tensional tectonics along a Plio-Pleistocene regional strike-slip fault system.

Assessment of a shallow magmatic system: the 1888–90 eruption, Vulcano Island, Italy

The magmatic system feeding the last eruption of the volcano La Fossa, Vulcano Island, Italy was studied. The petrogenetic mechanisms controlling the differentiation of erupted rocks were investigated through petrography, mineral chemistry, major, trace and rare earth element and Sr, Nd and Pb isotopic geochemistry. In addition, melt inclusion and fluid inclusion data were collected on both juvenile material and xenolithic partially melted metamorphic clasts to quantify the P-T conditions of the magma chamber feeding the eruption. A regular and continuous chemical zoning has been highlighted: rhyolites are the first erupted products, followed by trachytes and latites, whereas rhyolitic compositions were also found in the upper part of the sequence. The chemical and isotopic composition of the rhyolites indicates that they originated by fractional crystallization from latitic magmas plus the assimilation of crustal material; the trachytes represent hybrid magmas resulting from the mixing of latites and rhyolites, contaminated in the shallow magmatic system. The erupted products, primarily compositionally zoned from latites to rhyolites, are heterogeneous due to syn-eruptive mingling. The occurrence of magmacrust interaction processes, evidenced by isotopic variations (87Sr/86Sr=0.70474±3 to 0.70511±3; 143Nd/144Nd=0.512550±6 to 0.512614±8; 206Pb/204Pb=19.318–19.489; 207Pb/204Pb=15.642–15.782; 208Pb/204Pb=39.175–39.613), is confirmed by the presence of partially melted metamorphic xenoliths, with 87Sr/86Sr=0.71633±6 to 0.72505±2 and 143Nd/144Nd=0.51229±7, in rhyolites and trachytes. AFC calculations indicate a few percentage contribution of crustal material to the differentiating magmas. Thermometric measurements on melt inclusions indicate that the crystallization temperatures of the latites and trachytes were in the range of 1050–1100° C, whereas the temperature of the rhyolites appears to have been around 1000°C at the time of the eruption. Compositional data on melt inclusions reveal that the magmas involved in the eruption contained about 1–1.5 wt.% dissolved H2O in pre-eruptive conditions. Secondary fluid inclusions found in metamorphic xenoliths give low equilibration pressure data (30–60 MPa), giving the location of the higher portions of the chamber at around 1500–2000 m of depth.

Rare-earth element (REE) behaviour in the alteration facies of the active magmatic-hydrothermal system of Vulcano (Aeolian Islands, Italy)

Abstract This work reports a study on the rare-earth element (REE) behaviour in the high-sulfidation-type superficial alteration and in the phyllic and propylitic alteration in the subsurface of the island of Vulcano. The results of this study demonstrate notable differences in the REE behaviour in the different alteration facies. In silicic alteration, all REE are equally strongly depleted; in advanced argillic alteration, LREE are quite immobile whereas HREE are strongly depleted; in intermediate argillic, phyllic and propylitic alteration, REE patterns are almost unchanged compared with their fresh rock equivalents. These features indicate that the behaviour of REE in hydrothermal alteration facies at La Fossa is mainly controlled by pH, availability of complexing ions in the fluid (mainly SO42− and, in the silicic facies, F−) and the presence of secondary minerals able to host REE in their structures. The origin of the acid fluids is related to the hypogenic introduction of prevalently magmatic acid gases produced by the degassing of the shallow magmatic system of La Fossa volcano. In the active high-temperature fumarolic field of La Fossa, REE behaviour illustrates the transition from a dry vapor system, corresponding to the high-temperature fumaroles, to a wet condensing system in the surrounding area. The results of this research, carried out on an active high-sulfidation system, provide a useful tool for the study of high-sulfidation epithermal ore deposits and particularly help to understand the alteration processes during the main stage of hypogene wall rock alteration.

Distribution of fossil marine vertebrates in Cerro Colorado, the type locality of the giant raptorial sperm whale Livyatan melvillei (Miocene, Pisco Formation, Peru)

Hundreds of fossil marine vertebrates cropping out at Cerro Colorado (Pisco Basin, Peru) are identified and reported on a 1:6500 scale geological map and in a joined stratigraphic section. All the fossils are from the lower strata of the Pisco Formation, dated in this area to the late middle or early late Miocene. They are particularly concentrated (88%) in the stratigraphic interval from 40 to 75 m above the unconformity with the underlying Chilcatay Formation. The impressive fossil assemblage includes more than 300 specimens preserved as bone elements belonging mostly to cetaceans (81%), represented by mysticetes (cetotheriids and balaenopteroids) and odontocetes (kentriodontid-like delphinidans, pontoporiids, ziphiids, and physeteroids, including the giant raptorial sperm whale Livyatan melvillei). Seals, crocodiles, sea turtles, seabirds, bony fish, and sharks are also reported. Isolated large teeth of Carcharocles and Cosmopolitodus are common throughout the investigated stratigraphical interval, whereas other shark teeth, mostly of carcharinids, are concentrated in one sandy interval. This work represents a first detailed census of the extraordinary paleontological heritage of the Pisco Basin and the basis for future taphonomic, paleoecological, and systematic studies, as well as a much needed conservation effort for this extremely rich paleontological site.

Miocene magmatism and tectonics of the easternmost sector of the Calama–Olacapato–El Toro fault system in Central Andes at ~24°S: Insights into the evolution of the Eastern Cordillera

The Miocene Las Burras–Almagro–El Toro magmatic complex lies ~300 km to the east of the Central Andes volcanic arc, in the easternmost sector of the transverse Calama–Olacapato–El Toro fault zone. The magmatic rocks of the Las Burras–Almagro–El Toro complex comprise a monzogabbro to monzogranite laccolith like intrusion and basaltic andesite to dacite volcanic rocks that include seven lithostratigraphic members. New Rb-Sr dates indicate that the intrusive rocks are ca. 14 Ma, and K-Ar dates suggest emplacement ages of ca. 12.8–6.4 Ma for the volcanic rocks. The emplacement of the intrusion was controlled by N-S–striking strike-slip faults in a context of oblique convergence; the volcanism, which occurred along WNW-ESE– and N-S–striking extensional faults, relates to the Calama–Olacapato–El Toro fault zone. Two magmatic phases were recognized. Intrusive and volcanic rocks of the older magmatic phase (ca. 14–13 Ma) are characterized by Ba/Nb (7–14), La/Ta (11–18), and isotopic ratios ( 87 Sr/ 86 Sr: 0.704339–0.705281, 143 Nd/ 144 Nd: 0.512713–0.512598), which are intraplate characteristics. The source of the older magmas was isotopically depleted lithospheric mantle rich in K, Rb, and Th. Energy constrained–assimilation and fractional crystallization (EC-AFC) modeling indicates that fractional crystallization and crustal assimilation moderately modified magma composition during its residence in the crust. The products of the younger magmatic phase (ca. 11–6 Ma) have higher Ba/Nb (24–42) and La/Ta (24–30) and 87 Sr/ 86 Sr (0.706738–0.708729) and lower 143 Nd/ 144 Nd (0.512433–0.512360). The results of EC-AFC modeling exclude a significant role for the upper crust in the generation of the most primitive magmas of this phase. Their compositions can be explained by (1) contamination of the primary magmas having originated in a depleted mantle with a mafic crust, or (2) the contribution of isotopically enriched mantle zones. Shallow differentiation and moderate contamination by continental crust can explain the composition of the intermediate and evolved products of the younger phase. The variation of the magma source characteristics at 11 Ma is discussed in the frame of the complex geo-dynamical setting in this region.

Stratigraphic framework of the late Miocene to Pliocene Pisco Formation at Cerro Colorado (Ica Desert, Peru)

This paper describes a ∼200 m-thick section of the Pisco Formation exposed at Cerro Colorado, an important fossiliferous site in the Ica desert. In order to properly place the fauna in its correct relative position, this study establishes the stratigraphic framework within which the different fossil-bearing intervals of this site can be compared and may prove invaluable in future high-resolution studies on the faunal change. Most of the Pisco Formation deposits exposed at Cerro Colorado consist of gently dipping fine-grained sandstones, diatomaceous siltstones and diatomites with minor ash layers and dolomites deposited within nearshore and offshore settings. To facilitate detailed stratigraphic correlations within the Pisco strata for a 30 km2 area, eight marker beds have been defined and large-scale (1:10,000 scale) geological mapping conducted to determine fault positions, styles and offsets. The geological map shows that there are two important angular unconformities in the study area. The first one is the interformational basal unconformity of the Pisco Formation against folded, faulted, and planated Oligo-Miocene rocks of the Chilcatay Formation. The second is a low-angle intraformational erosional discontinuity of up to 4° angular discordance that allows the subdivision of the Pisco stratigraphy exposed in the study area into two informal allomembers. Dating of the exposed succession by diatom biostratigraphy suggests that the age of the lower allomember is late Miocene, whereas the upper allomember is late Miocene or younger.

Hydric dilatation of ignimbritic stones used in the church of Santa Maria di Otti(Oschiri, northern Sardinia, Italy)

In the historical buildings of eastern Logudoro (northern Sardinia), as well as in large areas of western Sardinia, ignimbritic rocks are widely used for ashlars and architectural elements as architraves, pedestals, shafts and capitals of columns. The decay processes affecting these rocks cause a progressive disintegration of the stone ashlars, with loss of material by exfoliation and flaking that determine a progressive retraction of the external profile of the facade with obliteration of the decorative elements. New data on the linear dilatation due to water absorption of these volcanic rocks are presented in this study in order to contribute to the evaluation of the impact of hydric dilatation in the stone degradation. The relationships among linear hydric dilatation of ignimbritic samples and petrographic and mineralogical characteristics as well as physical properties (texture, welding degree, porosity) indicate that three lithotypes with different behaviour in the water absorption can be distinguished in the ignimbrite rocks used as building stones in the church of Santa Maria di Otti (Oschiri, northern Sardinia, Italy). Although the linear hydric dilatation of the ignimbrites is moderate to low, we suggest that hydric dilatation may be an additional factor in enhancing the decay of the stones of the Santa Maria di Otti church.

Fossil marine vertebrates of Cerro Los Quesos: Distribution of cetaceans, seals, crocodiles, seabirds, sharks, and bony fish in a late Miocene locality of the Pisco Basin, Peru

ABSTRACT One-hundred and ninety-two fossil marine vertebrate specimens, preserved as bone elements cropping out at Cerro Los Quesos (Pisco Basin, Peru), are identified and reported on a 1:4,000 scale geological map and in the corresponding stratigraphic section. All the fossils originate from the Pisco Formation, which is dated in this area to the late Miocene (from 7.55 Ma to ≥6.71 Ma, based on 40Ar/39Ar analyses of three volcanic ash layers along the section). Specimens are particularly concentrated near the top of the two main hills, where the geologically youngest portion of the examined section crops out. The impressive fossil assemblage includes cetaceans (91.6%), represented by mysticetes (balaenopteroids and cetotheriids) and odontocetes (phocoenids, physeteroids, and ziphiids, including the holotype of Nazcacetus urbinai). Seals, a crocodile, a seabird, bony fish, and sharks are also reported. Isolated large teeth of Carcharocles and Cosmopolitodus are common and, in several instances, associated to mysticete skeletons. Together with a similar work recently published for the other late Miocene locality of Cerro Colorado, this work represents a case study for the detailed inventory of the extraordinary paleontological heritage of the Pisco Basin. As such, it constitutes the basis for future taphonomic, paleoecological, and systematic studies, as well as for a much-needed conservation effort.

Stratigraphic framework of the late Miocene Pisco Formation at Cerro Los Quesos (Ica Desert, Peru)

The enormous concentration of marine vertebrates documented within the Pisco Formation is unique for Peru and South America and places this unit among the prime fossil Lagerstätten for Miocene to Pliocene marine mammals worldwide. In order to provide a robust stratigraphic framework for the fossil-bearing locality of Cerro Los Quesos, this study presents a 1:10,000 scale geological map covering an area of about 21 km2, a detailed measured section spanning 290 m of strata, and a refined chronostratigraphy for the studied succession well constrained by diatom biostratigraphy and high-resolution 40Ar/39Ar isotopic dating of three interbedded ash layers. Within the apparently monotonous, diatomite-dominated sedimentary section, the Pisco Formation has been subdivided into six local members, with stratigraphic control over the different outcrops facilitated by the establishment of a detailed marker bed stratigraphy based on 15 readily distinguishable sediment layers of different nature.