Arvind Thiruvengadam

Criteria pollutant and greenhouse gas emissions from CNG transit buses equipped with three-way catalysts compared to lean-burn engines and oxidation catalyst technologies

Engine and exhaust control technologies applied to compressed natural gas (CNG) transit buses have advanced from lean-burn, to lean-burn with oxidation catalyst (OxC), to stoichiometric combustion with three-way catalyst (TWC). With this technology advancement, regulated gaseous and particulate matter emissions have been significantly reduced. Two CNG transit buses equipped with stoichiometric combustion engines and TWCs were tested on a chassis dynamometer, and their emissions were measured. Emissions from the stoichiometric engines with TWCs were then compared to the emissions from lean-burn CNG transit buses tested in previous studies. Stoichiometric combustion with TWC was effective in reducing emissions of oxides of nitrogen (NOX), particulate matter (PM), and nonmethane hydrocarbon (NMHC) by 87% to 98% depending on pollutants and test cycles, compared to lean combustion. The high removal efficiencies exceeded the emission reduction required from the certification standards, especially for NOX and PM. While the certification standards require 95% and 90% reductions for NOX and PM, respectively, from the engine model years 1998–2003 to the engine model year 2007, the measured NOX and PM emissions show 96% and 95% reductions, respectively, from the lean-burn engines to the stoichiometric engines with TWC over the transient Urban Dynamometer Driving Schedule (UDDS) cycle. One drawback of stoichiometric combustion with TWC is that this technology produces higher carbon monoxide (CO) emissions than lean combustion. In regard to controlling CO emissions, lean combustion with OxC is more effective than stoichiometric combustion. Stoichiometric combustion with TWC produced higher greenhouse gas (GHG) emissions including carbon dioxide (CO2) and methane (CH4) than lean combustion during the UDDS cycle, but lower GHG emissions during the steady-state cruise cycle. Implications: Stoichiometric combustion with three-way catalyst is currently the best emission control technology available for compressed natural gas (CNG) transit buses to meet the stringent U.S. Environmental Protection Agency (EPA) 2010 heavy-duty engine NOX emissions standard. For existing lean-burn CNG transit buses in the fleet, oxidation catalyst would be the most effective retrofit technology for the control of NMHC and CO emissions.

Influence of Real-World Engine Load Conditions on Nanoparticle Emissions from a DPF and SCR Equipped Heavy-Duty Diesel Engine

The experiments aimed at investigating the effect of real-world engine load conditions on nanoparticle emissions from a Diesel Particulate Filter and Selective Catalytic Reduction after-treatment system (DPF-SCR) equipped heavy-duty diesel engine. The results showed the emission of nucleation mode particles in the size range of 6-15 nm at conditions with high exhaust temperatures. A direct result of higher exhaust temperatures (over 380 °C) contributing to higher concentration of nucleation mode nanoparticles is presented in this study. The action of an SCR catalyst with urea injection was found to increase the particle number count by over an order of magnitude in comparison to DPF out particle concentrations. Engine operations resulting in exhaust temperatures below 380 °C did not contribute to significant nucleation mode nanoparticle concentrations. The study further suggests the fact that SCR-equipped engines operating within the Not-To-Exceed (NTE) zone over a critical exhaust temperature and under favorable ambient dilution conditions could contribute to high nanoparticle concentrations to the environment. Also, some of the high temperature modes resulted in DPF out accumulation mode (between 50 and 200 nm) particle concentrations an order of magnitude greater than typical background PM concentrations. This leads to the conclusion that sustained NTE operation could trigger high temperature passive regeneration which in turn would result in lower filtration efficiencies of the DPF that further contributes to the increased solid fraction of the PM number count.

Characterization of Particulate Matter Emissions from a Current Technology Natural Gas Engine

Experiments were conducted to characterize the particulate matter (PM)-size distribution, number concentration, and chemical composition emitted from transit buses powered by a USEPA 2010 compliant, stoichiometric heavy-duty natural gas engine equipped with a three-way catalyst (TWC). Results of the particle-size distribution showed a predominant nucleation mode centered close to 10 nm. PM mass in the size range of 6.04 to 25.5 nm correlated strongly with mass of lubrication-oil-derived elemental species detected in the gravimetric PM sample. Results from oil analysis indicated an elemental composition that was similar to that detected in the PM samples. The source of elemental species in the oil sample can be attributed to additives and engine wear. Chemical speciation of particulate matter (PM) showed that lubrication-oil-based additives and wear metals were a major fraction of the PM mass emitted from the buses. The results of the study indicate the possible existence of nanoparticles below 25 nm formed as a result of lubrication oil passage through the combustion chamber. Furthermore, the results of oxidative stress (OS) analysis on the PM samples indicated strong correlations with both the PM mass calculated in the nanoparticle-size bin and the mass of elemental species that can be linked to lubrication oil as the source.

Emission Rates of Regulated Pollutants from Current Technology Heavy-Duty Diesel and Natural Gas Goods Movement Vehicles

Chassis dynamometer emissions testing of 11 heavy-duty goods movement vehicles, including diesel, natural gas, and dual-fuel technology, compliant with US-EPA 2010 emissions standard were conducted. Results of the study show that three-way catalyst (TWC) equipped stoichiometric natural gas vehicles emit 96% lower NOx emissions as compared to selective catalytic reduction (SCR) equipped diesel vehicles. Characteristics of drayage truck vocation, represented by the near-dock and local drayage driving cycles, were linked to high NOx emissions from diesel vehicles equipped with a SCR. Exhaust gas temperatures below 250 °C, for more than 95% duration of the local and near-dock driving cycles, resulted in minimal SCR activity. The low percentage of activity SCR over the local and near-dock cycles contributed to a brake-specific NOx emissions that were 5-7 times higher than in-use certification limit. The study also illustrated the differences between emissions rate measured from chassis dynamometer testing and prediction from the EMFAC model. The results of the study emphasize the need for model inputs relative to SCR performance as a function of driving cycle and engine operation characteristics.

Unregulated, Greenhouse Gas and Ammonia Emissions from Current Technology Heavy-Duty Vehicles.

ABSTRACT The study presents the measurement of carbonyl, BTEX (benzene, toluene, ethyl benzene, and xylene), ammonia, elemental/organic carbon (EC/OC), and greenhouse gas emissions from modern heavy-duty diesel and natural gas vehicles. Vehicles from different vocations that included goods movement, refuse trucks, and transit buses were tested on driving cycles representative of their duty cycle. The natural gas vehicle technologies included the stoichiometric engine platform equipped with a three-way catalyst and a diesel-like dual-fuel high-pressure direct-injection technology equipped with a diesel particulate filter (DPF) and a selective catalytic reduction (SCR). The diesel vehicles were equipped with a DPF and SCR. Results of the study show that the BTEX emissions were below detection limits for both diesel and natural gas vehicles, while carbonyl emissions were observed during cold start and low-temperature operations of the natural gas vehicles. Ammonia emissions of about 1 g/mile were observed from the stoichiometric natural gas vehicles equipped with TWC over all the driving cycles. The tailpipe GWP of the stoichiometric natural gas goods movement application was 7% lower than DPF and SCR equipped diesel. In the case of a refuse truck application the stoichiometric natural gas engine exhibited 22% lower GWP than a diesel vehicle. Tailpipe methane emissions contribute to less than 6% of the total GHG emissions. Implications: Modern heavy-duty diesel and natural gas engines are equipped with multiple after-treatment systems and complex control strategies aimed at meeting both the performance standards for the end user and meeting stringent U.S. Environmental Protection Agency (EPA) emissions regulation. Compared to older technology diesel and natural gas engines, modern engines and after-treatment technology have reduced unregulated emissions to levels close to detection limits. However, brief periods of inefficiencies related to low exhaust thermal energy have been shown to increase both carbonyl and nitrous oxide emissions.

Comparison of Regulated and Unregulated Exhaust Emissions From a Fleet of Multi-Fuel Solid Resource Collection Vehicles

The refuse truck segment of the heavy duty diesel vehicle population has been identified as the most fuel inefficient sector. This is predominantly due to the stop and go driving pattern associated with these trucks. Constantly evolving emissions norms are forcing large truck fleet operators to explore the economic viability of alternative fueled vehicles to combat the increasing operating costs in terms of retrofit requirements of heavy-duty diesel vehicles. The objective of this study was to determine the emissions benefits and the economic viability of introducing liquefied natural gas (LNG), and LNG-Ultra-low sulfur diesel (ULSD) dual-fueled vehicles into the solid resource collection vehicle fleet (SRCV) in the city of Los Angeles. The 12 vehicles tested in this study were part of a multi-fuel refuse truck fleet. It should be noted that these vehicles are not representative of the state-of-the-art advanced technology engines that power the present day fleets. Vehicles were exercised over the AQMD refuse truck cycle and a newly developed compaction cycle on a heavy-duty chassis dynamometer. Regulated emissions together with a whole spectrum of unregulated speciation including the analysis of 1,3 butadiene with an on-site gas chromatograph was performed. Results showed that PM distance-specific mass emissions from LNG-fueled vehicles were on an average 82% lower than diesel trucks equipped with a DPF. Chemical speciation of exhaust from different fueled trucks indicated a characteristic emissions profile specific to the fuel used in these vehicles. While emissions from LNG vehicles were characterized by carbonyls, and other lower chain hydrocarbon compounds, emissions from diesel vehicles were dominated by polyaromatic hydrocarbons (PAH) and higher chain hydrocarbons.Copyright

Total Particle Number Emissions from Modern Diesel, Natural Gas, and Hybrid Heavy-Duty Vehicles During On-Road Operation

Particle emissions from heavy-duty vehicles (HDVs) have significant environmental and public health impacts. This study measured total particle number emission factors (PNEFs) from six newly certified HDVs powered by diesel and compressed natural gas totaling over 6800 miles of on-road operation in California. Distance-, fuel- and work-based PNEFs were calculated for each vehicle. Distance-based PNEFs of vehicles equipped with original equipment manufacturer (OEM) diesel particulate filters (DPFs) in this study have decreased by 355-3200 times compared to a previous retrofit DPF dynamometer study. Fuel-based PNEFs were consistent with previous studies measuring plume exhaust in the ambient air. Meanwhile, on-road PNEF shows route and technology dependence. For vehicles with OEM DPFs and Selective Catalytic Reduction Systems, PNEFs under highway driving (i.e., 3.34 × 1012 to 2.29 × 1013 particles/mile) were larger than those measured on urban and drayage routes (i.e., 5.06 × 1011 to 1.31 × 1013 particles/mile). This is likely because a significant amount of nucleation mode volatile particles were formed when the DPF outlet temperature reached a critical value, usually over 310 °C, which was commonly achieved when vehicle speed sustained over 45 mph. A model year 2013 diesel HDV produced approximately 10 times higher PNEFs during DPF active regeneration events than nonactive regeneration.

Development of an Ammonia Reduction Aftertreatment Systems for Stoichiometric Natural Gas Engines

Development of an Ammonia Reduction After-treatment Systems for Stoichiometric Natural Gas Engines

Correction to Characterization of Particulate Matter Emissions from a Current Technology Natural Gas Engine

the figure showed a high mass fraction of lubrication oil derived elements and metals. Figure 4 of this erratum shows the corrected mass fraction of PM after the calculation error was addressed. The corrections of the error results in the conclusion that the mass fraction of lubrication oil derived elements and metals are less than 10% of total mass of PM. The comparison of distance-specific emissions of lubricationoil-derived elements from this study with previous SCRequipped diesel work presented by Hu et al. is discussed in Line 2, second column of page 8239 of the original manuscript. The original manuscript suggested that the distance-specific emissions of lubrication-oil-derived elements are an order of magnitude higher from TWC-equipped natural gas vehicles compared to DPF-SCR-equipped diesel over the UDDS driving cycle. As a result of the correction to the calculation, the results now conclude that the distance-specific emissions of lubrication-oil-derived elements from TWC-equipped natural gas engines are up to 2 times higher than the retrofit DPF-SCR equipped diesel engines. The overall conclusions of the study remain unchanged after the correction of the error. The original manuscript suggests the possibility of lubrication oil-derived elements from TWCequipped natural gas engines to contribute more toward particle number count in the 10 nm size range. The manuscript also suggests that renucleation of inorganic lubrication oil additives, passing through the combustion chamber of the engine to be the primary contributor to particle number count in this size range.

Evaluation of Drayage Truck Chassis Dynamometer Test Cycles and Emissions Measurement

In 2006, the ports of Long Beach and Los Angeles adopted the final San Pedro Bay Ports Clean Air Action Plan (CAAP), initiating a broad range of programs intended to improve the air quality of the port and rail yard communities in the South Coast Air Basin. As a result, the Technology Advancement Program (TAP) was formed to identify, evaluate, verify and accelerate the commercial availability of new emissions reduction technologies for emissions sources associated with port operations, [1]. Container drayage truck fleets, an essential part of the port operations, were identified as the second largest source of NOx and the fourth largest source of diesel PM emissions in the ports’ respective 2010 emissions inventories [2, 3]. In response, TAP began to characterize drayage truck operations in order to provide drayage truck equipment manufacturers with a more complete understanding of typical drayage duty cycles, which is necessary to develop emissions reduction technologies targeted at the drayage market.As part of the broader TAP program, the Ports jointly commissioned TIAX LLC to develop a series of drayage truck chassis dynamometer test-cycles. These cycles were based on the cargo transport distance, using vehicle operational data collected on a second-by-second basis from numerous Class 8 truck trips over a period of two weeks, while performing various modes of typical drayage-related activities. Distinct modes of operation were identified; these modes include creep, low-speed transient, high-speed transient and high-speed cruise. After the modes were identified, they were assembled in order to represent typical drayage operation, namely, near-dock operation, local operation and regional operation, based on cargo transport distances [4].The drayage duty-cycles, thus developed, were evaluated on a chassis dynamometer at West Virginia University (WVU) using a class 8 tractor powered by a Mack MP8-445C, 13 liter 445 hp, and Model Year (MY) 2011 engine. The test vehicle is equipped with a state-of-the-art emissions control system meeting 2010 emissions regulations for on-road applications. Although drayage trucks in the San Pedro Bay Ports do not have to comply with the 2010 heavy-duty emissions standards until 2023, more than 1,000 trucks already meet that standard and are equipped with diesel particulate filter (DPF) and selective catalytic reduction (SCR) technology as used in the test vehicle. An overview of the cycle evaluation work, along with comparative results of emissions between integrated drayage operations, wherein drayage cycles are run as a series of shorter tests called drayage activities, and single continuous drayage operation cycles will be presented herein. Results show that emissions from integrated drayage operations are significantly higher than those measured over single continuous drayage operation, approximately 14% to 28% for distance-specific NOx emissions. Furthermore, a similar trend was also observed in PM emissions, but was difficult to draw a definite conclusion since PM emissions were highly variable and near detection limits in the presence of DPF. Therefore, unrepresentative grouping of cycle activity could lead to over-estimation of emissions inventory for a fleet of drayage vehicles powered by 2010 compliant on-road engines.Copyright