Baicheng Yao

Graphene-coated microfiber Bragg grating for high-sensitivity gas sensing

A graphene coated microfiber Bragg grating (GMFBG) for gas sensing is reported in this Letter. Taking advantage of the surface field enhancement and gas absorption of a GMFBG, we demonstrate an ultrasensitive approach to detect the concentration of chemical gas. The obtained sensitivities are 0.2 and 0.5 ppm for NH3 and xylene gas, respectively, which are tens of times higher than that of a GMFBG without graphene for tiny gas concentration change detection. Experimental results indicate that the GMFBG-based NH3 gas sensor has fast response due to its highly compact structure. Such a miniature fiber-optic element may find applications in high sensitivity gas sensing and trace analysis.

Four-Wave Mixing in a Microfiber Attached Onto a Graphene Film

We demonstrate effective four-wave mixing in a 2- μm microfiber attached onto a graphene film by using two continuous-wave pump lasers at wavelengths near 1550 nm. With a contact length of 10 mm between the microfiber and the graphene film and input powers of 600 and 100 mW for the two pumps, we achieve a conversion efficiency that varies from -28 to -34 dB as the wavelength difference between the two pump lasers varies from 0.5 to 4.5 nm. Graphene-attached microfibers could find applications as miniaturized nonlinear devices in optical signal processing.

Graphene enhanced evanescent field in microfiber multimode interferometer for highly sensitive gas sensing

Graphene based new physics phenomena are leading to a variety of stimulating graphene-based photonic devices. In this study, the enhancement of surface evanescent field by graphene cylindrical cladding is observed, for the first time, by using a graphene-coated microfiber multi-mode interferometer (GMMI). It is found theoretically and experimentally that the light transmitting in the fiber core is efficiently dragged by the graphene, hence significantly enhancing the evanescent fields, and subsequently improving the sensitivity of the hybrid waveguide. The experimental results for gas sensing verified the theoretical prediction, and ultra-high sensitivities of ~0.1 ppm for NH(3) gas detection and ~0.2 ppm for H(2)O vapor detection are achieved, which could be used for trace analysis. The enhancement of surface evanescent field induced by graphene may pave a new way for developing novel graphene-based all-fiber devices with compactness, low cost, and temperature immunity.

Hybrid Graphene-Microfiber Waveguide for Chemical Gas Sensing

Graphene has been attracting great interest as the basis of novel photonic devices and sensors due to its many unique optical and electric properties that are quite different from conventional film materials. In this paper, we propose and demonstrate a novel hybrid graphene-microfiber waveguide structure and its application to chemical gas sensing for the first time to our knowledge. As the complex refractive index of the extremely thin graphene film (<;1 nm) can be easily modified by chemical gas molecules distributing on its surface, the transverse electric mode surface wave intensity is sensitive to gas concentration. Such an intensity modulation induced by gas molecules can be detected via the coupling of evanescent field between the graphene waveguide and the microfiber. A sensitivity of 0.31 dB/100 ppm and good reversibility are observed experimentally for acetone vapor gas sensing. It is believed that this hybrid waveguide structure could open a new window to realize a variety of graphene-based photonic sensors, for potential applications in the fields of biology, medicine, and chemistry.

Demonstration of complex refractive index of graphene waveguide by microfiber-based Mach–Zehnder interferometer

The complex refractive index (CRI) of graphene waveguide (GW) is of great importance for modeling and developing graphene-based photonic or optoelectronic devices. In this paper, the CRI of the GW is investigated theoretically and experimentally, it is found that the CRI of the GW will modulate the intensity and phase of transmitting light. The phase alterations are obtained spectrally by a Microfiber-based Mach-Zehnder interferometer (MMZI), experimental results demonstrate that the CRIs of the GW vary from 2.91-i13.92 to 3.81-i14.64 for transmitting wavelengths ranging from 1510 to 1590 nm. This method cannot only be used to determine the CRI of the GW optically and provide one of the fundamental parameters for designing graphene-based optic devices for communication and sensing applications, but also is adoptable in graphene-based transformation optics for determination of the CRI of the GW at other wavelengths.

Graphene oxide deposited microfiber knot resonator for gas sensing

Graphene and its derivative graphene oxide (GO) have been the focus of attention in the field of chemical and biological sensing. In this paper, we report a fiber-optic sensor for chemical gas sensing by using graphene oxide coated microfiber knot resonator (GMKR). The refractive index of GO was changed when the gas molecules were adsorbed to the surface of GO, and the gas concentration varying induced refractive index change can be detected by measuring the interference fringes shift of the GMKR. The experimental results show the sensitivities of ~0.35pm/ppm for NH3 and ~0.17pm/ppm for CO detection, due to the different adsorption energy and charge transfer ability between the gas molecules and GO. Experimental results show GO is a promising candidate for gas sensing and can be combined with various fiber-optic devices due to the easy transfer process.

Graphene based widely-tunable and singly-polarized pulse generation with random fiber lasers

Pulse generation often requires a stabilized cavity and its corresponding mode structure for initial phase-locking. Contrastingly, modeless cavity-free random lasers provide new possibilities for high quantum efficiency lasing that could potentially be widely tunable spectrally and temporally. Pulse generation in random lasers, however, has remained elusive since the discovery of modeless gain lasing. Here we report coherent pulse generation with modeless random lasers based on the unique polarization selectivity and broadband saturable absorption of monolayer graphene. Simultaneous temporal compression of cavity-free pulses are observed with such a polarization modulation, along with a broadly-tunable pulsewidth across two orders of magnitude down to 900 ps, a broadly-tunable repetition rate across three orders of magnitude up to 3 MHz, and a singly-polarized pulse train at 41 dB extinction ratio, about an order of magnitude larger than conventional pulsed fiber lasers. Moreover, our graphene-based pulse formation also demonstrates robust pulse-to-pulse stability and wide-wavelength operation due to the cavity-less feature. Such a graphene-based architecture not only provides a tunable pulsed random laser for fiber-optic sensing, speckle-free imaging, and laser-material processing, but also a new way for the non-random CW fiber lasers to generate widely tunable and singly-polarized pulses.

Generation of cascaded four-wave-mixing with graphene-coated microfiber

A graphene-coated microfiber (GCM)-based hybrid waveguide structure formed by wrapping monolayer graphene around a microfiber with length of several millimeters is pumped by a nanosecond laser at ∼1550  nm, and multi-order cascaded four-wave-mixing (FWM) is effectively generated. By optimizing both the detuning and the pump power, such a GCM device with high nonlinearity and compact size would have potential for a wide range of FWM applications, such as phase-sensitive amplification, multi-wavelength filter, all-optical regeneration and frequency conversion, and so on.

Graphene-based D-shaped fiber multicore mode interferometer for chemical gas sensing

In this Letter, a graphene-coated D-shaped fiber (GDF) chemical gas sensor is proposed and demonstrated. Taking advantage of both the graphene-induced evanescent field enhancement and the in-fiber multimode interferometer, the GDF shows very high sensitivity for polar gas molecule adsorptions. An extinction ratio of up to 28 dB within the free spectrum range of ~30  nm in the transmission spectrum is achieved. The maximum sensitivities for NH₃ and H₂O gas detections are ~0.04 and ~0.1  ppm, respectively. A hybrid sensing scheme with such compactness, high sensitivity, and online monitoring capabilities may pave the way for others to explore a series of graphene-based lab-on-fiber devices for biochemical sensing.

Graphene-Based D-Shaped Polymer FBG for Highly Sensitive Erythrocyte Detection

Graphene-based silica fiber-optic sensors, with high sensitivity, fast response, and low cost, have shown great promise for gas sensing applications. In this letter, by covering a monolayer of p-doped graphene on a D-shaped microstructured polymer fiber Bragg grating (FBG), we propose and demonstrate a novel biochemical probe sensor, the graphene-based D-shaped polymer FBG (GDPFBG). Due to the graphene-based surface evanescent field enhancement, this sensor shows high sensitivity to detect surrounding biochemical parameters. By monitoring the Bragg peak locations of the GDPFBG online, human erythrocyte (red blood cell) solutions with different cellular concentrations ranging from 0 to 104 ppm were detected precisely, with the maximum resolution of sub-ppm. Such a sensor is structurally compact, is clinically acceptable, and provides good recoverability, offering a state-of-the-art polymer-fiber-based sensing platform for highly sensitive in situ and in vivo cell detection applications.