Carlo Ingrao

Recycled-PET fibre based panels for building thermal insulation: Environmental impact and improvement potential assessment for a greener production

A screening of Life Cycle Assessment for the evaluation of the damage arising from the production of 1 kg of recycled Polyethylene Terephthalate (RPET) fibre-based panel for building heat insulation was carried out according to the ISO 14040:2006 and 14044:2006. All data used were collected on site based on observations during site visits, review of documents and interviews with technical personnel and management. These data were processed by using SimaPro 7.3.3, accessing the Ecoinvent v.2.2 database and using the Impact 2002+ method. The study showed damage to be equal to 0.000299 points mostly due to the: 1) PET thermo-bonding fibre supply from China by means of a freight-equipped intercontinental aircraft; 2) production of bottle-grade granulate PET; 3) medium voltage electricity consumption during the manufacturing of RPET fibre panel. It was also highlighted that there were environmental benefits due to recycling through mainly avoiding significant emissions and reduced resource consumption. An improvement assessment was carried out to find solutions aimed at reducing the damage coming from the most impacting phases. Furthermore, the environmental impacts due to the production of the analysed RPET fibre-based panel were compared to other materials with the same insulating function, such as polystyrene foam, rock wool and cork slab. Finally, the environmental benefits of the recycling of PET bottles for flake production were highlighted compared to other treatment scenarios such as landfill and municipal incineration.

Foamy polystyrene trays for fresh-meat packaging: Life-cycle inventory data collection and environmental impact assessment

Food packaging systems are designed to perform series of functions mainly aimed at containing and protecting foods during their shelf-lives. However, to perform those functions a package causes environmental impacts that affect food supply chains and that come from its life-cycle phases. Therefore, package design should be done based upon not only the issues of cost, food shelf-life and safety, as well as practicality, but also of environmental sustainability. For this purpose, Life Cycle Assessment (LCA) can be applied in the packaging field with the aim of highlighting environmental hotspots and improvement potentials, thus enabling more eco-friendly products. In this context, an LCA of foamy polystyrene (PS) trays used for fresh meat packaging was performed here. The study highlighted that the highest environmental impacts come from PS-granule production and electricity consumption. In this regard, the authors underscored that there are no margins for improvement in the production of the granules and in the transport of the material inputs involved as well as of the trays to users. On the contrary, changing the energy source into a renewable one (by installing, for instance, a wind power plant) would enable a 14% damage reduction. In this way, the authors documented that alternative ways can be found for global environmental improvement of the system analysed and so for enhanced environmental sustainability of food packaging systems.

Greenhouse gas emissions of an agro-biogas energy system: Estimation under the Renewable Energy Directive.

Agro-biogas from energy crops and by-products is a renewable energy carrier that can potentially contribute to climate change mitigation. In this context, application of the methodology defined by the Renewable Energy Directive 2009/28/EC (RED) was performed in order to estimate the 100-year Global Warming Potential (GWP100) associated with an agro-biogas supply chain (SC) in Southern Italy. Doing so enabled calculation of Greenhouse Gas (GHG) emission saving in order to verify if it is at least equal to 35% compared to the fossil fuel reference system, as specified by the RED. For the assessment, an attributional Life Cycle Assessment (LCA) approach (International Organization for Standardization (ISO), 2006a,b) was integrated with the RED methodology applied following the guidelines reported in COM(2010)11 and updated by SWD(2014)259 and Report EUR 27215 EN (2015). Moreover, primary data were collected with secondary data extrapolated from the Ecoinvent database system. Results showed that the GWP100 associated with electricity production through the biogas plant investigated was equal to 111.58gCO2eqMJe(-1) and so a 40.01% GHG-emission saving was recorded compared to the RED reference. The highest contribution comes from biomass production and, in particular, from crop cultivation due to production of ammonium nitrate in the overall amount used for crop cultivation. Based upon the findings of the study, the GHG saving calculated slightly exceeds the related minimum proposed by the RED: therefore, improvements are needed anyway. In particular, the authors documented that through replacement of ammonium nitrate with urea the GHG-emission saving would increase to almost 68%, thus largely satisfying the RED limit. In addition, the study highlighted that conservation practices, such as NT, can significantly enable reduction of the GHG-emissions coming from agricultural activities. Therefore, those practices should be increasingly adopted for cultivation of energy crops, because the latter significantly contribute to biogas production yield enhancement.

Life cycle assessment of CRT lead recovery process

In recent years, the high rate of technological obsolescence and subsequent replacement of ICT devices has led to a significant increase in waste from electrical and electronic equipment (WEEE) and oriented institutional stakeholders to promote recycling and material recovery to prevent the dispersion of hazardous substances into the environment and wastage of valuable resources. For cathode ray tube (CRT) WEEE, the standard treatment of end-of-life CRTs generates leaded glass which is usually landfill-disposed after inertisation. An experimental treatment was designed and applied to a pilot plant to obtain valuable secondary raw materials (SRMs). The industrialisation phase of the treatment requires assessing its sustainability according to the life cycle assessment approach. The paper analyses this treatment and from the significant results suggests it is environmentally sustainable.

Barrier Properties of Poly(Propylene Cyclohexanedicarboxylate) Random Eco-Friendly Copolyesters

Random copolymers of poly(propylene 1,4-cyclohexanedicarboxylate) containing different amounts of neopentyl glycol sub-unit were investigated from the gas barrier point of view at the standard temperature of analysis (23 °C) with respect to the three main gases used in food packaging field: N2, O2, and CO2. The effect of temperature was also evaluated, considering two temperatures close to the Tg sample (8 and 15 °C) and two above Tg (30 and 38 °C). Barrier performances were checked after food contact simulants and in different relative humidity (RH) environments obtained with two saturated saline solutions (Standard Atmosphere, 23 °C, 85% of RH, with saturated KCl solution; Tropical Climate, 38 °C, 90% RH, with saturated KNO3 solution). The results obtained were compared to those of untreated film, which was used as a reference. The relationships between the gas transmission rate, the diffusion coefficients, the solubility, and the copolymer composition were established. The results highlighted a correlation between barrier performance and copolymer composition and the applied treatment. In particular, copolymerization did not cause a worsening of the barrier properties, whereas the different treatments differently influenced the gas barrier behavior, depending on the chemical polymer structure. After treatment, Fourier transform infrared analysis confirmed the chemical stability of these copolymers. Films were transparent, with a light yellowish color, slightly more intense after all treatments.

The Use of Polylactic Acid in Food Packaging

Polylactide polymers have gained a great attention in the last decade to replace the conventional synthetic polymers and as a growing alternative packaging material for demanding food market.

Environmental Life Cycle Assessment of marine sediment decontamination by citric acid enhanced-microwave heating

The potential ability of microwave heating (MWH) for the remediation of marine sediments affected by severe hydrocarbon (HC) contamination was investigated. Decontamination effectiveness and environmental sustainability through a comparative Life Cycle Assessment (LCA) were addressed. Main results revealed that the application of a 650-W MWH treatment resulted in a rapid (15min) HC removal. A citric acid (CA) dose of 0.1M led to enhanced-HC removals of 76.9, 96.5 and 99.7% after 5, 10 and 15min of MW irradiation, respectively. The increase in CA dose to 0.2M resulted in a shorter successful remediation time of 10min. The exponential kinetic model adopted showed a good correlation with the experimental data with R2 values in the 0.913-0.987 range. The nature of the MW treatment was shown to differently influence the HC fraction concentration after the irradiation process. Achieved HC removals in such a short remediation time are hardly possible by other clean-up techniques, making the studied treatment a potential excellent choice. Removal mechanisms, which allowed the enhanced-MWH to operate as a highly effective multi-step technique (pure thermal desorption+chemical washing), undoubtedly represent a key factor in the whole remediation process. The LCA highlighted that the MW technology is the most environmentally sustainable alternative for sediment decontamination applications, with a total damage, which was 75.74% lower than that associated with the EK (0.0503pt).

Bio-based and recycled-waste materials in buildings: A study of energy performance of hemp-lime concrete and recycled-polyethylene terephthalate façades for office facilities in France and Italy

Global environmental issues are arising over the developed and developing world. Improving energy efficiency and reducing Green Gases emissions become the key issues in all the economic sectors and, in particular, the building sector that is one of the most energy-consuming. It is, therefore, important to find alternative building materials with low-environmental impact contributing to global sustainability. In that context, this study reports on the performance of sustainable materials produced from natural resources as hemp-concrete or from recycled-waste nonbiodegradable materials including recycled polyethylene terephthalate. Three façades employing three different materials (hemp-concrete, hemp-concrete with brick and recycled polyethylene terephthalate) were investigated in three cities in France (Nancy and Carpentras) and Italy (Perugia) with different climate. The energy performance of each façade was assessed in terms of cooling and heating demands, electrical consumption for a constant flow rate ventilation mode, considering different orientations. The study also shows the effect of window size (10%, 25%, and 40%) on the annual energy consumption.

Quality- and sustainability-related issues associated with biopolymers for food packaging applications

Biopolymers are increasingly gaining attention largely in response to the growing concerns about the sustainability of conventional polymers and the environmental pollution caused by plastic packaging waste treatment. In this regard, this chapter was designed to discuss, briefly but exhaustively, about the quality- and sustainability-related issues of biopolymers, thereby exploring their feasibility of usage for food packaging purposes. In particular, the attention was focused on poly(lactic acid) (PLA) as it is currently acknowledged to be one of the most versatile and widespread biopolymers: a review of its technical and environmental issues was performed.

Life cycle assessment applied to the sector of microelectronic devices

This work is about the application of LCA to the ends of the environmental assessment of pure-silicon wafers production. The input-data quantification is realized studying two microelectronic devices and presenting schematically tables and graphs, to be easily interpreted. This will allow help the reader to individuate, clearly and immediately, the materials flows and the relationships among the different steps of the production process. The material flows, in terms of raw materials use and energy consumption, were studied using the data provided by a firm involved in the microelectronic device production field. The two devices environmental analysis was developed considering potential effects such as Acidification, Eutrophication, Ozone reduction, Global warming, Ozone photochemical formation, Human Toxicity.