Roberto Rana

Recycled-PET fibre based panels for building thermal insulation: Environmental impact and improvement potential assessment for a greener production

A screening of Life Cycle Assessment for the evaluation of the damage arising from the production of 1 kg of recycled Polyethylene Terephthalate (RPET) fibre-based panel for building heat insulation was carried out according to the ISO 14040:2006 and 14044:2006. All data used were collected on site based on observations during site visits, review of documents and interviews with technical personnel and management. These data were processed by using SimaPro 7.3.3, accessing the Ecoinvent v.2.2 database and using the Impact 2002+ method. The study showed damage to be equal to 0.000299 points mostly due to the: 1) PET thermo-bonding fibre supply from China by means of a freight-equipped intercontinental aircraft; 2) production of bottle-grade granulate PET; 3) medium voltage electricity consumption during the manufacturing of RPET fibre panel. It was also highlighted that there were environmental benefits due to recycling through mainly avoiding significant emissions and reduced resource consumption. An improvement assessment was carried out to find solutions aimed at reducing the damage coming from the most impacting phases. Furthermore, the environmental impacts due to the production of the analysed RPET fibre-based panel were compared to other materials with the same insulating function, such as polystyrene foam, rock wool and cork slab. Finally, the environmental benefits of the recycling of PET bottles for flake production were highlighted compared to other treatment scenarios such as landfill and municipal incineration.

Foamy polystyrene trays for fresh-meat packaging: Life-cycle inventory data collection and environmental impact assessment

Food packaging systems are designed to perform series of functions mainly aimed at containing and protecting foods during their shelf-lives. However, to perform those functions a package causes environmental impacts that affect food supply chains and that come from its life-cycle phases. Therefore, package design should be done based upon not only the issues of cost, food shelf-life and safety, as well as practicality, but also of environmental sustainability. For this purpose, Life Cycle Assessment (LCA) can be applied in the packaging field with the aim of highlighting environmental hotspots and improvement potentials, thus enabling more eco-friendly products. In this context, an LCA of foamy polystyrene (PS) trays used for fresh meat packaging was performed here. The study highlighted that the highest environmental impacts come from PS-granule production and electricity consumption. In this regard, the authors underscored that there are no margins for improvement in the production of the granules and in the transport of the material inputs involved as well as of the trays to users. On the contrary, changing the energy source into a renewable one (by installing, for instance, a wind power plant) would enable a 14% damage reduction. In this way, the authors documented that alternative ways can be found for global environmental improvement of the system analysed and so for enhanced environmental sustainability of food packaging systems.

The European Policy for the Sustainability of Urban Areas and the “Covenant of Mayors” Initiative: A Case Study

The “Covenant of Mayors” (CoM) is an initiative of the DG for Energy of the European Commission. It was started in 2008, with the aim of reducing Greenhouse Gases (GHGs) by 20 % by 2020 through the implementation of adequate actions taken in agreement between the European Commission and the municipalities (so called signatories), which intend to adhere. The actions are identified and listed in the “Sustainable Energy Action Plan (SEAP),” which each signatory must produce within one year from adhesion and submit to the European organisms for formal approval and consequent accession to financial tools to implement them. A total of 36 (out of 61) municipalities of the province of Foggia subscribed to the above-mentioned agreement in 2010 and, 1 year later, submitted their SEAPs to the validation of the experts of the Joint Research Centre-Institute of Energy (JRC-IE) of the European Commission. All the submitted SEAPs were formally approved in July 2012. This chapter reports on the methodology the authors used for the elaboration of the SEAPs and the achieved results.

Greenhouse gas emissions of an agro-biogas energy system: Estimation under the Renewable Energy Directive.

Agro-biogas from energy crops and by-products is a renewable energy carrier that can potentially contribute to climate change mitigation. In this context, application of the methodology defined by the Renewable Energy Directive 2009/28/EC (RED) was performed in order to estimate the 100-year Global Warming Potential (GWP100) associated with an agro-biogas supply chain (SC) in Southern Italy. Doing so enabled calculation of Greenhouse Gas (GHG) emission saving in order to verify if it is at least equal to 35% compared to the fossil fuel reference system, as specified by the RED. For the assessment, an attributional Life Cycle Assessment (LCA) approach (International Organization for Standardization (ISO), 2006a,b) was integrated with the RED methodology applied following the guidelines reported in COM(2010)11 and updated by SWD(2014)259 and Report EUR 27215 EN (2015). Moreover, primary data were collected with secondary data extrapolated from the Ecoinvent database system. Results showed that the GWP100 associated with electricity production through the biogas plant investigated was equal to 111.58gCO2eqMJe(-1) and so a 40.01% GHG-emission saving was recorded compared to the RED reference. The highest contribution comes from biomass production and, in particular, from crop cultivation due to production of ammonium nitrate in the overall amount used for crop cultivation. Based upon the findings of the study, the GHG saving calculated slightly exceeds the related minimum proposed by the RED: therefore, improvements are needed anyway. In particular, the authors documented that through replacement of ammonium nitrate with urea the GHG-emission saving would increase to almost 68%, thus largely satisfying the RED limit. In addition, the study highlighted that conservation practices, such as NT, can significantly enable reduction of the GHG-emissions coming from agricultural activities. Therefore, those practices should be increasingly adopted for cultivation of energy crops, because the latter significantly contribute to biogas production yield enhancement.

Characterization of dried and freeze-dried sea fennel ( Crithmum maritimum L. ) samples with headspace gas-chromatography/mass spectrometry and evaluation of an electronic nose discrimination potential

Processed samples (air-dried @ 40 and @ 60 °C and freeze-dried) of sea fennel (Crithmum maritimum L.), an autochthonous spice with interesting market potential, were analyzed by headspace gas-chromatography/mass spectrometry and classification capabilities of an electronic nose in discriminating between samples with stepwise forward statistics were evaluated as well. Freeze-drying process was the most preservative in terms of limiting darkening without compromising appearance of the final product, providing weight loss of about 85% and water activity below the limit for mold growth issues. Headspace analysis of samples highlighted the presence of 35 volatiles grouped as terpene hydrocarbons, oxygenated terpenes, sesquiterpen hydrocarbons, phenyl propanoids, not-terpenic aldehydes and not-terpenic ketones. Correlations emerged between selected sensors and some detected volatile organic compounds. Stepwise linear discriminant analysis and simple K-nearest neighbors obtained a 100% overall correct classification rate in cross-validation of the electronic nose in classifying samples, whereas stepwise quadratic discriminant analysis and Naive-Bayes gave 93.3%. The sea fennel could be a new interesting spice to launch in the food market and the electronic nose showed the potential to be used in monitoring the industrial process aimed at extending its shelf-life.