Claudio Scarchilli

Insights on nitrate sources at Dome C (East Antarctic Plateau) from multi-year aerosol and snow records

Here we present the first multi-year record of nitrate in the atmospheric aerosol (2005–2008) and surface snow (2006–08) from central Antarctica. PM10 and size-segregated aerosol, together with superficial snow, have been collected all year-round at high resolution (daily for all the snow samples and for most of aerosol samples) at Dome C since the 2004/05 field season and analysed for main and trace ionic markers. The suitability of the sampling location in terms of possible contamination from the base is shown in detail. In spite of the relevance of nitrate in Antarctic atmosphere, both for better understanding the chemistry of N cycle in the plateau boundary layer and for improving the interpretation of long-term nitrate records from deep ice core records, nitrate sources in Antarctica are not well constrained yet, neither in extent nor in timing. A recurring seasonal pattern was pointed out in both aerosol and snow records, showing summer maxima and winter minima, although aerosol maxima lead the snow ones of 1–2 months, possibly due to a higher acidity in the atmosphere in mid-summer, favouring the repartition of nitrate as nitric acid and thus its uptake by the surface snow layers. On the basis of a meteorological analysis of one major nitrate event, of data related to PSC I extent and of irradiance values, we propose that the high nitrate summer levels in aerosol and snow are likely due to a synergy of enhanced source of nitrate and/or its precursors (such as the stratospheric inputs), higher solar irradiance and higher oxidation rates in this season. Moreover, we show here a further evidence of the substantial contribution of HNO3/NOx re-emission from the snowpack, already shown in previous works, and which can explain a significant fraction of atmospheric nitrate, maintaining the same seasonal pattern in the snow. As concerning snow specifically, the presented data suggest that nitrate is likely to be controlled mainly by atmospheric processes, not on the daily timescale but rather on the seasonal one.

Holocene sea ice variability driven by wind and polynya efficiency in the Ross Sea

The causes of the recent increase in Antarctic sea ice extent, characterised by large regional contrasts and decadal variations, remain unclear. In the Ross Sea, where such a sea ice increase is reported, 50% of the sea ice is produced within wind-sustained latent-heat polynyas. Combining information from marine diatom records and sea salt sodium and water isotope ice core records, we here document contrasting patterns in sea ice variations between coastal and open sea areas in Western Ross Sea over the current interglacial period. Since about 3600 years before present, an increase in the efficiency of regional latent-heat polynyas resulted in more coastal sea ice, while sea ice extent decreased overall. These past changes coincide with remarkable optima or minima in the abundances of penguins, silverfish and seal remains, confirming the high sensitivity of marine ecosystems to environmental and especially coastal sea ice conditions.Strong regional heterogeneity prevents thorough understanding of the recent increase in Antarctic sea ice. Here, analysis of marine and ice cores in the Western Ross Sea shows that late Holocene contrasting sea ice patterns between open and coastal areas are related to katabatic winds and polynya efficiency.

Multi-year record of atmospheric and snow surface nitrate in the central Antarctic plateau

Continuous all year-round samplings of atmospheric aerosol and surface snow at high (daily to 4-day) resolution were carried out at Dome C since 2004-05 to 2013 and nitrate records are here presented. Basing on a larger statistical data set than previous studies, results confirm that nitrate seasonal pattern is characterized by maxima during austral summer for both aerosol and surface snow, occurring in-phase with solar UV irradiance. This temporal pattern is likely due to a combination of nitrate sources and post-depositional processes whose intensity usually enhances during the summer. Moreover, it should be noted that a case study of the synoptic conditions, which took place during a major nitrate event, showed the occurrence of a stratosphere-troposphere exchange. The sampling of both matrices at the same time with high resolution allowed the detection of a an about one-month long recurring lag of summer maxima in snow with respect to aerosol. This result can be explained by deposition and post-deposition processes occurring at the atmosphere-snow interface, such as a net uptake of gaseous nitric acid and a replenishment of the uppermost surface layers driven by a larger temperature gradient in summer. This hypothesis was preliminarily tested by a comparison with surface layers temperature data in the 2012-13 period. The analysis of the relationship between the nitrate concentration in the gas phase and total nitrate obtained at Dome C (2012-13) showed the major role of gaseous HNO3 to the total nitrate budget suggesting the need to further investigate the gas-to-particle conversion processes.

Sea salt sodium record from Talos Dome (East Antarctica) as a potential proxy of the Antarctic past sea ice extent

Antarctic sea ice has shown an increasing trend in recent decades, but with strong regional differences from one sector to another of the Southern Ocean. The Ross Sea and the Indian sectors have seen an increase in sea ice during the satellite era (1979 onwards). Here we present a record of ssNa+ flux in the Talos Dome region during a 25-year period spanning from 1979 to 2003, showing that this marker could be used as a potential proxy for reconstructing the sea ice extent in the Ross Sea and Western Pacific Ocean at least for recent decades. After finding a positive relationship between the maxima in sea ice extent for a 25-year period, we used this relationship in the TALDICE record in order to reconstruct the sea ice conditions over the 20th century. Our tentative reconstruction highlighted a decline in the sea ice extent (SIE) starting in the 1950s and pointed out a higher variability of SIE starting from the 1960s and that the largest sea ice extents of the last century occurred during the 1990s.

Evaluation of the CloudSat surface snowfall product overAntarctica using ground-based precipitation radars

Before addressing the comments of the reviewer, it must be noted that during the revision process there was detected that a small part of erroneous MRR data at the PE station was included in the analysis. This erroneous data was recorded during the 2015-2016 austral winter season and was caused by interference from other instruments. It was removed from the sample lowering the period of concurrent data availability of the MRR and CloudSat from 928 to 851 days for the PE station (Fig. 2 in the main paper). This mainly affects Fig. 6 in the main paper where a clear lowering of both the MRR and CloudSat total precipitation amount is observed. However, as the total snowfall amount for both the MRR and CloudSat lowered with an equal amount, results and conclusions are not affected significantly.

Feedback mechanisms between snow and atmospheric mercury: Results and observations from field campaigns on the Antarctic plateau

The Antarctic Plateau snowpack is an important environment for the mercury geochemical cycle. We have extensively characterized and compared the changes in surface snow and atmospheric mercury concentrations that occur at Dome C. Three summer sampling campaigns were conducted between 2013 and 2016. The three campaigns had different meteorological conditions that significantly affected mercury deposition processes and its abundance in surface snow. In the absence of snow deposition events, the surface mercury concentration remained stable with narrow oscillations, while an increase in precipitation results in a higher mercury variability. The Hg concentrations detected confirm that snowfall can act as a mercury atmospheric scavenger. A high temporal resolution sampling experiment showed that surface concentration changes are connected with the diurnal solar radiation cycle. Mercury in surface snow is highly dynamic and it could decrease by up to 90% within 4/6 h. A negative relationship between surface snow mercury and atmospheric concentrations has been detected suggesting a mutual dynamic exchange between these two environments. Mercury concentrations were also compared with the Br concentrations in surface and deeper snow, results suggest that Br could have an active role in Hg deposition, particularly when air masses are from coastal areas. This research presents new information on the presence of Hg in surface and deeper snow layers, improving our understanding of atmospheric Hg deposition to the snow surface and the possible role of re-emission on the atmospheric Hg concentration.