Rita Traversi

One-to-one coupling of glacial climate variability in Greenland and Antarctica.

Precise knowledge of the phase relationship between climate changes in the two hemispheres is a key for understanding the Earth’s climate dynamics. For the last glacial period, ice core studies have revealed strong coupling of the largest millennial-scale warm events in Antarctica with the longest Dansgaard–Oeschger events in Greenland through the Atlantic meridional overturning circulation. It has been unclear, however, whether the shorter Dansgaard–Oeschger events have counterparts in the shorter and less prominent Antarctic temperature variations, and whether these events are linked by the same mechanism. Here we present a glacial climate record derived from an ice core from Dronning Maud Land, Antarctica, which represents South Atlantic climate at a resolution comparable with the Greenland ice core records. After methane synchronization with an ice core from North Greenland, the oxygen isotope record from the Dronning Maud Land ice core shows a one-to-one coupling between all Antarctic warm events and Greenland Dansgaard–Oeschger events by the bipolar seesaw6. The amplitude of the Antarctic warm events is found to be linearly dependent on the duration of the concurrent stadial in the North, suggesting that they all result from a similar reduction in the meridional overturning circulation.

Spatial and temporal variability of snow accumulation in East Antarctica from traverse data

Recent snow accumulation rate is a key quantity for ice-core and mass-balance studies. Several accumulation measurement methods (stake farm, fin core, snow-radar profiling, surface morphology, remote sensing) were used, compared and integrated at eight sites along a transect from Terra Nova Bay to Dome C, East Antarctica, to provide information about the spatial and temporal variability of snow accumulation. Thirty-nine cores were dated by identifying tritium/b marker levels (1965-66) and non-sea-salt (nss) SO4 2- spikes of the Tambora (Indonesia) volcanic event (1816) in order to provide information on temporal variability. Cores were linked by snow radar and global positioning system surveys to provide detailed information on spatial variability in snow accumulation. Stake-farm and ice-core accumulation rates are observed to differ significantly, but isochrones (snow radar) correlate well with ice-core derived accumulation. The accumulation/ablation pattern from stake measurements suggests that the annual local noise (metre scale) in snow accumulation can approach 2 years of ablation and more than four times the average annual accumulation, with no accumulation or ablation for a 5 year period in up to 40% of cases. The spatial variability of snow accumulation at the kilometre scale is one order of magnitude higher than temporal variability at the multi-decadal/secular scale. Stake measurements and firn cores at Dome C confirm an approximate 30% increase in accumulation over the last two centuries, with respect to the average over the last 5000 years.

Atmosphere–snow interaction by a comparison between aerosol and uppermost snow-layers composition at Dome C, East Antarctica

Abstract The study of aerosol composition and air–snow exchange processes is relevant to the reconstruction of past atmosphere composition from ice cores. For this purpose, aerosol samples, superficial snow layers and firn samples from snow pits were collected at Dome Concordia station, East Antarctica, during the 2000/01 summer field season. The aerosol was collected in a ‘coarse’ and a ‘fine’ fraction, roughly separated from each other by a stacked filter system (5.0 and 0.4 μm). Atomic Force Microscopy (AFM) direct measurements on the fine fraction showed that 72% of surface size distribution ranges from 1.0 x 105 to 1.2 x 106 nm2. Assuming a spherical model, the volume size distribution of particles smaller than 5.0 μm shows a mode in the radius range 0.2–0.6 μm. Ion chromatographic (IC) measurements of selected chemical components allowed calculation of the ionic balance of the two size fractions. The fine fraction is dominant, representing 86% of the total ionic budget, and it is characterized by high content of sulphate and acidity. Principal component analysis (PCA) identified sea-spray and biogenic aerosol sources and showed some particulars of the transport and depositional processes of some chemical components (Ca2+, MSA, nssSO4 2–). Comparative analysis of aerosol, surface hoar and superficial snow showed differences in chemical composition: nitrate and chloride exhibit very high concentrations in the uppermost snow layers and in the surface hoar, and low values in the aerosol. This evidence demonstrates that nitrate and chloride are mainly in gas phase at Dome C and they can be caught on the snow and hoar surface through dry deposition and adsorption processes.

Chemical and isotopic snow variability along the 1998 ITASE traverse from Terra Nova Bay to Dome C (East-Antarctica)

Abstract In the framework of the PNRA–ITASE (Programma Nazionale di Ricerche in Antartide–International Trans-Antarctic Scientific Expedition) project, during the field season 1998/99, surface snow (1m cores and pits) and shallow firn cores (10–50m) were collected along a traverse from Terra Nova Bay (northern Victoria Land) to Dome C (East Antarctic ice sheet). Results of chemical, tritium and stable-isotope composition are presented here for the 1 m cores, some snow pits and the first 2 mof some shallow firn cores. the δ18O values show a regular trend with altitude, and the regression line between δ18O and surface temperature is δ18O = 0.99T (˚C) – 0.67. Primary aerosol components such as Na+, Cl–, Ca2+,Mg2+ and K+ show high concentrations decreasing with increasing altitude in the first 250–350km from the coast. At greater distances, concentrations of these species remain more constant. NO3 – concentration shows an irregular profile with a progressive decreasing trend as altitude increases. Non-sea-salt (nss) SO4 2– concentration decreases up to about 250 km from the coast, increases 250–770 km from the coast and remains relatively constant in the most remote stations. Methanesulphonate (MSA) concentration shows high variability. the MSA/nssSO4 2– ratio exhibits a decreasing trend 250–550km from the coast. With increasing distance, the ratio shows moderate oscillations. nssCl– concentration shows a progressive increase as distance from the coast increases, in agreement with the increasing influence of HCl on the Cl– budget of the inland Antarctic atmosphere. Post-depositional re-emissions of Cl– and NO3 – were found at stations characterized at the surface by long-term accumulation hiatus (wind crusts). the chemical-species distribution is consistent with the presence in the studied area of local and long-range transport processes, post-depositional effects and snow-accumulation variations observed along the traverse.

Snow accumulation rates in northern Victoria Land, Antarctica, by firn-core analysis

A multiparametric (chemical, isotopic and physical) study on three shallow firn cores sampled in northernVictoria Land was carried out to obtain glaciological information and climatic data in this Antarctic region. Sampling areas were accurately prospected to identify sites, located at different altitudes and distances from the sea, where the snow accumulation was not influenced by katabatic wind redistribution or summer melting. Stratigraphic, isotopic (δ 18 O) and chemical (H 2 O 2 , MSA and nssSO 4 2- ) profiles were mutually examined for dating purposes and to determine the mean snow-accumulation rates at three different stations. Annual accumulation rates of 85-420 kg m -2 a -1 were determined in the period 1971-92. An inverse pattern between accumulation rate and altitude was shown by the progression of the mean annual rates of 160, 203 and 260 kg m 2 a -1 , respectively, in the highest, medium and lowest stations. The mean accumulation value of all northern Victoria Land data available, 170 kg m 2 a -1 , represents a decrease of up to 35% with respect to the estimated value most widely used until now. Our accumulation value is very close to that required for a zero net surface mass balance according to ice discharge. A linear relationship with a gradient of 0.81 ‰ °C has been found between mean δ 18 O values and mean annual surface temperature for different ice cores drilled in northern Victoria Land.

Sea-spray deposition in Antarctic coastal and plateau areas from ITASE traverses

Abstract Sea-salt markers (Na+, Mg2+ and Cl–) were analyzed in recent snow collected at more than 600 sites located in coastal and central areas of East Antarctica (northern Victoria Land–Dome C–Wilkes Land), in order to understand the effect of site remoteness, transport efficiency and depositional and post-depositional processes on the spatial distribution of the primary marine aerosol. Firn-core, snow-pit and 1m integrated superficial snow samples were collected in the framework of the International Trans-Antarctic Scientific Expeditions (ITASE) project during recent Italian Antarctic Campaigns (1992–2002). The sampling sites were mainly distributed along coast–inland traverses (northern Victoria Land– Dome C) and an east–west transect following the 2100m contour line (Wilkes Land). At each site, the snow ionic composition was determined. Here, we discuss the distribution of sea-spray components (Na+, Mg2+ and Cl–) as a function of distance from the sea, altitude and accumulation rate, in order to discover the pulling-down rate, possible fractionating phenomena and alternative sources moving inland from coastal areas. Sea-spray depositional fluxes decrease as a function of distance from the sea and altitude. A two-order-of-magnitude decrease occurs in the first 200km from the sea, corresponding to about 2000ma.s.l. Correlations of Mg2+ and Cl– with Na+ and trends of Mg2+/Na+ and Cl–/Na+ ratios showed that chloride has other sources than sea spray (HCl) and is affected by post-depositional processes. Accumulation rate higher than 80 kgm–2 a–1 preserves the chloride record in the snow. Sea-spray atmospheric scavenging is dominated by wet deposition in coastal and inland sites.

SPATIAL AND TEMPORAL DISTRIBUTION OF ENVIRONMENTAL MARKERS FROM COASTAL TO PLATEAU AREAS IN ANTARCTICA BY FIRN CORE CHEMICAL ANALYSIS

The chemical analysis of shallow firn cores sampled in coastal and plateau areas in Northern Victoria Land and along a transect from Talos Dome to Dome C (East Antarctica, Pacific Ocean sector) allowed a global view of spatial and temporal changes in chemical composition of snow depositions over the last 100 years. Variations in concentration of primary (sea spray) and secondary (biogenic emission, atmospheric inputs) source markers were observed and discussed as a function of distance from the sea and altitude. In the stations characterized by relatively high snow accumulation rates, the sub-sampling resolution was sufficient to obtain a stratigraphic dating by using the periodical variations of seasonal markers. In these stations, a subdivision in “summer” and “winter” samples was carried out in order to study the seasonal changes of the contributions of the measured compounds to the snow composition as elevation and distance from the sea increase. Some evidence of post-depositional effects which are able to change the original deposition of chloride and nitrate, was observed at stations with low accumulation rates. The reliability of the depth/concentration profile of these substances for reconstructing past deposition was also discussed.

Chemical and isotopic snow variability in East Antarctica along the 2001/02 ITASE traverse

Abstract As part of the International Trans-Antarctic Scientific Expedition (ITASE) project, a traverse was carried out from November 2001 to January 2002 through Terre Adélie, George V Land, Oates Land and northern Victoria Land, for a total length of about 1875 km. The research goal is to determine the latitudinal and longitudinal variability of physical, chemical and isotopic parameters along three transects: one west–east transect (WE), following the 2150m contour line (about 400 km inland of the Adélie, George V and Oates coasts), and two north–south transects (inland Terre Adélie and Oates Coast–Talos Dome–Victoria Land). The intersection between the WE and Oates Coast–Victoria Land transects is in the Talos Dome area. Along the traverse, eight 2 m deep snow pits were dug and sampled with a 2.5 cm depth resolution. For spatial variability, 1 m deep integrated samples were collected every 5 km (363 sampling sites). In the snow-pit stratigraphy, pronounced annual cycles, with summer maxima, were observed for nssSO4 2–, MSA, NO3 – and H2O2. The seasonality of these chemical trace species was used in combination with stable-isotope stratigraphy to derive reliable and temporally representative snow-accumulation rates. The study of chemical, isotopic and accumulation-rate variability allowed the identification of a distribution pattern which is controlled not only by altitude and distance from the sea, but also by the complex circulation of air masses in the study area. In particular, although the Talos Dome area is almost equidistant from the Southern Ocean and the Ross Sea, local atmospheric circulation is such that the area is strongly affected only by the Ross Sea. Moreover, we observed a decrease in concentration of aerosol components in the central portion of the WE transect and in the southern portion of the Talos Dome transect; this decrease was linked to the higher stability of atmospheric pressure due to the channelling of katabatic winds.

Biomass burning contributions estimated by synergistic coupling of daily and hourly aerosol composition records

Biomass burning (BB) is a significant source of particulate matter (PM) in many parts of the world. Whereas numerous studies demonstrate the relevance of BB emissions in central and northern Europe, the quantification of this source has been assessed only in few cities in southern European countries. In this work, the application of Positive Matrix Factorisation (PMF) allowed a clear identification and quantification of an unexpected very high biomass burning contribution in Tuscany (central Italy), in the most polluted site of the PATOS project. In this urban background site, BB accounted for 37% of the mass of PM10 (particulate matter with aerodynamic diameter<10 μm) as annual average, and more than 50% during winter, being the main cause of all the PM10 limit exceedances. Due to the chemical complexity of BB emissions, an accurate assessment of this source contribution is not always easily achievable using just a single tracer. The present work takes advantage of the combination of a long-term daily data-set, characterized by an extended chemical speciation, with a short-term high time resolution (1-hour) and size-segregated data-set, obtained by PIXE analyses of streaker samples. The hourly time pattern of the BB source, characterised by a periodic behaviour with peaks starting at about 6 p.m. and lasting all the evening-night, and its strong seasonality, with higher values in the winter period, clearly confirmed the hypothesis of a domestic heating source (also excluding important contributions from wildfires and agricultural wastes burning).

High-resolution fast ion chromatography (FIC) measurements of chloride, nitrate and sulphate along the EPICA Dome C ice core

Abstract Fast ion chromatographic (FIC) analysis of the first European Project for Ice Coring in Antarctica (EPICA) Dome C ice core (788m deep) was used to obtain high-resolution profiles for Cl–, NO3 – and SO4 2–, spanning the last 45000 years. About 19 000 determinations for each component, with an average resolution of 4.0 cm, were performed in the field on continuously melted firn- and ice-core sections. the measured core covers the Holocene, the glacial/interglacial transition and about one-third of the last ice age. In the glacial period, mean concentrations of 93.8, 24.4 and 178.4 mg L–1 were calculated for Cl–, NO3 – and SO4 2–, respectively. the mean levels significantly increase in the Last Glacial Maximum (LGM), when these compounds reach values of 149.6, 53.9 and 219.3 mg L–1. During the glacial/interglacial transition, the mean concentrations quickly decrease reaching the typical Holocene values of 19.1, 12.9 and 93.3 mg L–1, for Cl–, NO3 – and SO4 2–, respectively. All species settle on Holocene-like values about 4000 years before the beginning of the warm period (from the isotopic curve) showing a low (chloride) and no (nitrate and sulphate) sensitivity to Antarctic Cold Reversal climatic change. the sulphate decrease is consistent with the dilution factor due to the higher accumulation rate in the interglacial conditions (about 2.5), suggesting no significant change in source intensity or transport efficiency occurred for this component. on the contrary, the Holocene values for chloride and nitrate, being much lower than those measured in the LGM, suggest a source-intensity and transport-efficiency enhancement during the LGM and/or a more effective fixing of HCl and HNO3 in the snow layers through the neutralizing effect of the higher atmospheric dust load.