Evie L. Papadopoulou

Self-Cleaning Organic/Inorganic Photo-Sensors

We present the fabrication of a multifunctional, hybrid organic-inorganic micropatterned device, which is capable to act as a stable photosensor and, at the same time, displaying inherent superhydrophobic self-cleaning wetting characteristics. In this framework several arrays of epoxy photoresist square micropillars have been fabricated on n-doped crystalline silicon substrates and subsequently coated with a poly(3-hexylthiophene-2,5-diyl) (P3HT) layer, giving rise to an array of organic/inorganic p-n junctions. Their photoconductivity has been measured under a solar light simulator at different illumination intensities. The current-voltage (I-V) curves show high rectifying characteristics, which are found to be directly correlated with the illumination intensity. The photoresponse occurs in extremely short times (within few tens of milliseconds range). The influence of the interpillar distance on the I-V characteristics of the sensors is also discussed. Moreover, the static and dynamic wetting properties of these organic/inorganic photosensors can be easily tuned by changing the pattern geometry. Measured static water contact angles range from 125° to 164°, as the distance between the pillars is increased from 14 to 120 μm while the contact angle hysteresis decreases from 36° down to 2°.

Nylon 6,6/graphene nanoplatelet composite films obtained from a new solvent

Solution processing of aliphatic polyamides (nylon) is quite challenging due to the fact that only a few solvents, such as formic acid and cresol, dissolve nylon. In general, polyamide 6,6 (nylon 6,6) is dissolved in formic acid to produce porous membranes or electrospun fibers. Herein, we propose for the first time a mixture of trifluoroacetic acid (TFA) and acetone that dissolves nylon 6,6, resulting in crystalline and non-porous films. Furthermore the same mixture of solvents was proved to be an excellent co-solvent for graphene nanoplatelets that were homogeneously dispersed in the solutions to produce reinforced nylon 6,6 polymer composites. The dispersion of the nanoplates in the polymer solution was found to be very stable over time. The mechanical and electrical properties of the developed composites were studied as a function of filler content. The Youngs modulus of the nylon 6,6 films increases more than two times upon the addition of the nanoplates. Furthermore, the flexible composites exhibit semiconducting behavior, with their electrical conductivity reaching 10−2 S cm−1 for 20 wt% graphene nanoplatelet concentration.

Zwitterionic Nanofibers of Super-Glue for Transparent and Biocompatible Multi-Purpose Coatings

Here we show that macrozwitterions of poly(ethyl 2-cyanoacrylate), commonly called Super Glue, can easily assemble into long and well defined fibers by electrospinning. The resulting fibrous networks are thermally treated on glass in order to create transparent coatings whose superficial morphology recalls the organization of the initial electrospun mats. These textured coatings are characterized by low liquid adhesion and anti-staining performance. Furthermore, the low friction coefficient and excellent scratch resistance make them attractive as solid lubricants. The inherent texture of the coatings positively affects their biocompatibility. In fact, they are able to promote the proliferation and differentiation of myoblast stem cells. Optically-transparent and biocompatible coatings that simultaneously possess characteristics of low water contact angle hysteresis, low friction and mechanical robustness can find application in a wide range of technological sectors, from the construction and automotive industries to electronic and biomedical devices.

An Efficient Pure Polyimide Ammonia Sensor

Pyromellitic dianhydride–4,4-oxydianiline (PMDA–ODA), broadly known as Kapton, is investigated for detection and quantification of ammonia (NH3) vapors from ammonia solutions of different molarities. The PMDA–ODA films are made by solution casting on microscope glass slides and cured at 200 °C. Ammonia sensing is performed by measuring the changes in the electric current intensity under ambient conditions of temperature and humidity. The sensor exhibits fast response to ammonia vapors, for aqueous ammonia solutions with molarity as low as 3.5 mM. The adsorption processes of ammonia to the polyimide surface after exposure to ammonia vapors are investigated by FTIR and XPS, revealing that ammonia results in the disruption of imide linkages and the simultaneous creation of amides I and II. Control experiments performed on commercial Kapton adhesive tape show negligible sensitivity of the commercial product to ammonia vapors from different ammonia solution molarities. A device is also presented, demonstrating the real-time detection of ammonia vapors.

Investigation of the electro-spinnability of alginate solutions containing gold precursor HAuCl4.

Alginate nanofibers with an average diameter of 75nm have been prepared by the electrospinning process. In addition, the spinnability of the solutions in the presence of the gold precursor HAuCl4 was investigated. At low concentrations of HAuCl4 well-formed nanofibers were produced, whereas as its concentration increases the nanofibrous mats present an increased number of bead-like defects. Herein, the in situ preparation of gold nanoparticles (Au NPs) is discussed since sodium alginate (SA) acts as the reducing agent and a mechanism is proposed in order to explain the bead-effect as well as the surface morphology of the alginate fibers decorated with Au NPs.