F. H. Su

Synthesis and photoluminescence properties of vertically aligned ZnO nanorod-nanowall junction arrays on a ZnO-coated silicon substrate

Arrays of vertically well-aligned ZnO nanorod–nanowall junctions have been synthesized on an undoped ZnO-coated silicon substrate by a carbothermal reduction and vapour phase transport method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) show that the nanostructures are well-oriented with the c-axis perpendicular to the substrate. The room temperature photoluminescence (PL) spectrum of the as-prepared ZnO nanostructure reveals a dominant near-band-edge (NBE) emission peak and a weak deep level (DL) emission, which demonstrates its good optical properties. Temperature-dependent PL spectra show that both the intensity of NBE and DL emissions increased with decreasing temperature. The NBE emission at 3.27 eV is identified to originate from the radiative free exciton recombination. The possible growth mechanism of ZnO nanorod–nanowall junctions is also proposed.

Photoluminescence from self-assembled long-wavelength InAs/GaAs quantum dots under pressure

The photoluminescence from self-assembled long-wavelength InAs/GaAs quantum dots was investigated at 15 K under hydrostatic pressure up to 9 GPa. Photoemission from both the ground and the first excited states in large InAs dots was observed. The pressure coefficients of the two emissions were 69 and 72 meV/GPa, respectively. A nonlinear elasticity theory was used to interpret the significantly small pressure coefficients of the large dots. The sequential quenching of the ground and the excited state emissions with increasing pressure suggests that the excited state emissions originate from the optical transitions between the first excited electron states and the first excited hole states.

Temperature and pressure behavior of the emission bands from Mn-, Cu-, and Eu-doped ZnS nanocrystals

The temperature and pressure dependence of the photoluminescence from ZnS:Mn2+, ZnS:Cu2+, and ZnS:Eu2+ nanocrystals were investigated in the temperature range from 10 to 300 K and under hydrostatic pressure up to 6 GPa at room temperature. The orange emission (590 nm) from the 4T1-6A1 transition of Mn2+ ions, the green emission (518 nm) from the 4f65d1-4f7 transition of Eu2+ ions and the blue emission (460 nm) related to the transition from the conduction band of ZnS to the t2 level of Cu2+ ions were observed in the Mn-, Eu-, and Cu-doped samples, respectively. It was found that all of these emission bands decrease in intensity with increasing temperature. Among them the intensity of the Mn-orange emission dropped faster. The activation energies were estimated to be 58, 16, and 42 meV for the Mn-orange, Eu-green, and Cu-blue emissions, respectively. A negative pressure coefficient of −26 meV/GPa was obtained for the Mn-orange emission, which agrees with the value calculated from the crystal field theory. ...

Temperature behaviour of the orange and blue emissions in ZnS: Mn nanoparticles

The temperature dependences of the orange and blue emissions in 10, 4.5, and 3 nm ZnS:Mn nanoparticles were investigated. The orange emission is from the T-4(1)-(6)A(1) transition of Mn2+ ions and the blue emission is related to the donor-acceptor recombination in the ZnS host. With increasing temperature, the blue emission has a red-shift. On the other hand, the peak energy of the orange emission is only weakly dependent on temperature. The luminescence intensity of the orange emission decreases rapidly from 110 to 300 K for the 10 nm sample but increases obviously for the 3 nm sample, whereas the emission intensity is nearly, independent of temperature for the 4.5 nm sample. A thermally activated carrier-transfer model has been proposed to explain the observed abnormal temperature behaviour of the orange emission in ZnS:Mn nanoparticles.

Group delay of electromagnetic pulses through multilayer dielectric mirrors combined with gravitational wave

Group delay of electromagnetic pulses through multilayer dielectric mirrors (MDM) combined with gravitational wave (GW) is investigated. Unlike in traditional quantum tunneling, the group delay of a transmitted wave packet irradiated by a GW increases linearly with MDM length. This peculiar tunneling effect can be attributed to electromagnetic wave leakage in a time-dependent photonic bandgap caused by the GW. In particular, we find that the group delay of the tunneling photons is sensitive to GW. Our study provides insight into the nature of the quantum tunnelling as well as a novel process by which to detect the GW.