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Textile Research Journal | 1985

Flame Retardation of Fe(III)-Poly(vinyl Alcohol) Films

Akio Kurose; Kazuko Miyagawa; Mutsuko Otsuki; Etsuko Masuda; Hirofusa Shirai; Fukashi Shimizu; Nobumasa Hojo

was completely hydrolyzed by alkali solution and purified by dialysis. Metal-PVA complexes were prepared in.,the same way as in our previous papers [2, 5]. Kn aqueous solution of Ti(III), Fe(III), and Zn(II) chloride was added to the PVA solution, and the pH of the mixed solution was adjusted to the desired value with KOH. The molar ratios of total metal ions (TM) to monomeric units of PV A(Tud, T,,~/T&dquo;,_


Textile Research Journal | 1985

Flame Retardation of Poly(vinyl Alcohol) and Poly(vinyl Chloride) Films Containing Dispersed Metal-Ethylenediamine Complexes

Akio Kurose; Kazuko Miyagawa; Mutsuko Otsuki; Etsuko Masuda; Hirofusa Shirai; Fukashi Shimizu; Nobumasa Hojo

Table I shows that there is not much marked difference in the decrease of cell length and in the increase of cell wall thickness at 1 minute and at 30 minutes of treatment time. Thus it appears that the swelling reaction, which causes the longitudinal shrinkage of the filaments and the increase in cell wall thickness and which is reported to be associated with crimp formation in jute [3, 5], is mostly complete at one minute of treatment time.


Polymer Journal | 1983

Kinetics of Ligand Exchange Reaction of Cu(II)–Poly(vinyl alcohol Complex with Ethylenedianune- N , N , N ′, N ′-tetraacetic Acid

Tsuneo Suzuki; Hirofusa Shirai; Fukashi Shimizu; Nobumasa Hojo


Textile Research Journal | 1984

Thermal stabilities of Ni(II) partially phosphorylated polyvinyl alcohol complexes

Akio Kurose; Hirofusa Shirai; Fukashi Shimizu; Nobumasa Hojo


Sen-i Gakkaishi | 1980

ADSORPTIVE RATE OF METAL CATIONS ON SILK FIBROIN FIBER

Fukashi Shimizu; Ikuzo Sakaguchi


Sen-i Gakkaishi | 1976

AFTER CHROMING OF SILK WITH POTASSIUM BICHROMATE

Fukashi Shimizu; Kyohei Jyoko; Ikuzo Sakaguchi


Sen-i Gakkaishi | 1976

ADSORPTION BEHAVIOR OF Cu(II) ON SILK FIBROIN FIBERS

Fukashi Shimizu; Kyohei Jyoko; Ikuzo Sakaguchi; Toshiro Iijima


Sen-i Gakkaishi | 1979

ADSORPTION BEHAVIOR OF Ni (II), Co (II) AND Mn (II) ON SILK FIBROIN FIBER

Fukashi Shimizu; Ikuzo Sakaguchi


Sen-i Gakkaishi | 1976

ADSORPTION OF CHROMIUM (VI) ON SILK FIBROIN FIBER

Fukashi Shimizu; Kyohei Jyoko; Ikuzo Sakaguchi


Sen-i Gakkaishi | 1970

ADSORPTION BEHAVIOR OF COPPER (II) IONS BY SILK YARNS ON CUPRIC SALT TREATMENTS, WITH REFERENCE TO ITS INHIBITORY EFFECT ON PHOTODEGRADATION

Fukashi Shimizu; Gensaku Aida

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