Goswin Heckrath

Landscape-scale modeling of carbon cycling under the impact of soil redistribution: The role of tillage erosion

Despite its global significance, soil-atmosphere carbon (C) exchange under the impact of soil redistribution remains an unquantified component of the global C budget. Here we use radionuclide and soil organic carbon (SOC) data for two agricultural fields in Europe to undertake a spatial analysis of sediment and SOC fate during erosion and deposition in agricultural uplands. C fluxes induced by soil redistribution are quantified by incorporating C dynamics in a spatially distributed model including both water- and tillage-induced soil redistribution (SPEROS-C). The SOC patterns predicted by SPEROS- C are in good agreement with field observations and show that in upland areas, tillage erosion and deposition exerts a large influence on SOC redistribution and soil profile evolution at a timescale of a few decades. The formation of new SOC at eroding sites and the burial of eroded SOC below plough depth provide an important mechanism for C sequestration on sloping arable land in the order of 3–10 g C m 2 yr 1 . Any attempt to manage agricultural land to maximize sequestration must fully account for erosion, burial and fate of eroded and buried SOC across the landscape and must also account for the correlation between tillage and erosion.

Tillage erosion and its effect on soil properties and crop yield in Denmark

The leaching characteristics of air pollution control (APC) residues collected in Shanghai, China, were compared by performing three compliance leaching tests. These were the standard Chinese method for determining the leaching toxicity of solid waste (GB 5086.1-1997), the USEPAs Toxicity Characteristic Leaching Procedure (TCLP), and the new European shake test (EN 12457-3). In particular, behaviors of raw samples and samples that had been subjected to natural aging were compared. Both the leaching tests and natural aging substantially affected the leaching results concerning the APC residue samples. Most importantly, EN and GB tests classified the raw APC residues as hazardous, but the residues passed the TCLP test as nonhazardous. After it had been naturally aged for 720 h, however, the aged sample was classified as hazardous by the TCLP and EN tests, but as nonhazardous by the GB test. Metals that are thought to have been immobilized by carbonation were released at pH 6.3. Model calculations based on the geochemical thermodynamic equilibrium model MINTEQA2 revealed that the formation of metal carbonates did not correspond to the noted change in the leaching behaviors in the three leaching tests. Rather, the partial neutralization of alkaline ash by dissolved CO2 changing the final pH of the leachate dominated the leaching characteristics. The leaching results showed a change in leachate pH.

International phosphorus workshop: diffuse phosphorus loss to surface water bodies--risk assessment, mitigation options, and ecological effects in river basins.

Agriculture is a major source of P to the aquatic environment in many countries. Although efforts have been made to improve the P utilization in agricultural production, which is reflected in modestly declining P surpluses in many countries, increasing agricultural P surpluses are still observed in some countries. The IPW5 Special Submission included in this issue addresses and discusses four key topics that emerged from the workshop: (i) managing agricultural P losses-effectiveness, uncertainties, and costs; (ii) P modeling at different scales; (iii) functioning of riparian buffers; (iv) ecological responses to P loadings and impacts of climate change. Each of these four topics interacts with each other as well as with the four tiers of the P Transfer Continuum (Source, Mobilization, Transport, and Ecological Effects). In this review paper we highlight the main outcomes of the workshop and the special collection of eight papers. Moreover, we identify the main gaps in our knowledge and future research directions on P, which are linked to important issues such as addressing scale effects, improved P models with the ability to quantify uncertainty, the linking of P losses with ecological effects, and climate change.

Colloid and Phosphorus Leaching From Undisturbed Soil Cores Sampled Along a Natural Clay Gradient

The presence of strongly sorbing compounds in groundwater and tile drains can be a result of colloid-facilitated transport. Colloid and phosphorus leaching from macropores in undisturbed soil cores sampled across a natural clay gradient at Aarup, Denmark, were studied. The aim of the study was to correlate easily measurable soil properties, such as clay content and water-dispersible colloids, to colloid and phosphorus leaching. The clay contents across the gradient ranged from 0.11 to 0.23 kg kg−1. Irrigating with artificial rainwater, all samples showed a high first flush of colloids and phosphorus followed by lower and stable colloid and phosphorus concentrations. The mass of particles leached at first flush was independent of clay content and was attributed to the instant release of particles associated with the macropore walls and released upon contact with flowing water. Below a clay content of ∼0.15 kg kg−1, the later leaching (after the first flush) of particles was independent of the clay content. Above this threshold, there was a positive relationship between the mass of leached particles after the first flush and the clay content. Particle release after the first flush was linearly correlated to the accumulated outflow and was described as a diffusion controlled process, using √(accumulated outflow). The mass of leached particles was positively correlated to the clay content as well as to water-dispersible colloids. Particulate phosphorus (P) was linearly correlated to concentration of leached particles and accounted for ∼70% of the total mass of leached P. Approximately 50% of particulate P was associated with the first flush. The P concentration on leached particles was negatively correlated to clay content (R2 = 0.89) and followed the same trend as the P concentration on soil clay and the so-called degree of P saturation (oxalate-extractable P on iron and aluminum minerals). Because higher colloidal P concentration was countered by a lower colloidal leaching, the total amount of leached P stayed remarkably constant along the natural clay gradient.

Biochar effects on soil aggregate properties under no-till maize.

Abstract Soil aggregates are useful indicators of soil structure and stability, and the impact on physical and mechanical aggregate properties is critical for the sustainable use of organic amendments in agricultural soil. In this work, we evaluated the short-term soil quality effects of applying biochar (0–10 kg m−2), in combination with swine manure (2.1 and 4.2 kg m−2), to a no-till maize (Zea mays L.) cropping system on a sandy loam soil in Denmark. Topsoil (0–20 cm) aggregates were analyzed for clay dispersibility, aggregate stability, tensile strength (TS), and specific rupture energy (SRE) using end-over-end shaking, a Yoder-type wet-sieving method, and an unconfined compression test in soil samples collected 7 and 19 months after final biochar application. The highest rates of biochar and swine manure application resulted in the highest aggregate stability and lowest clay dispersibility. Applying both amendments systematically increased TS and SRE for large aggregates (4–8 and 8–16 mm) but not for small aggregates (1–2 and 2–4 mm). Increased biochar application also decreased the friability index of soil aggregates. Based on X-ray visualization, it was found that aggregates containing larger amounts of biochar particles had higher TS and SRE probably because of bonding effects. Based on the improved soil aggregate properties, we suggest that biochar can be effective for increasing and sustaining overall soil quality, for example, related to minimizing the soil erosion potential.

Macropores and Macropore Transport: Relating Basic Soil Properties to Macropore Density and Soil Hydraulic Properties

Abstract Preferential transport of water through soil macropores is a governing process in the facilitated transport of strongly sorbing compounds. The aim of this study was to investigate the relationships between macropore density and the hydraulic conductivity of the soil and to test the sampling representativeness of soil columns for the measurement of saturated hydraulic conductivity. Macropore density was determined in three horizons in four typical Danish soil types (third year of pasture), and saturated hydraulic conductivity and near-saturated hydraulic conductivity were measured in the laboratory on undisturbed soil columns (6,280 cm3) in the same three horizons. A strong relationship between macropore density and the mean particle diameter was found in the B and C horizons. A poor relationship was found between macropore density and the hydraulic conductivity at a matric potential of −10 hPa, whereas a stronger relationship was found at saturation. Results of the test of the number of soil columns needed for a representative distribution of macropores for the measurement of saturated hydraulic conductivity indicated that approximately six soil columns were enough. Our work suggests that integrating knowledge of the abundance of macropores in relation to soil type and land use will increase the performance of pedotransfer functions in predicting saturated hydraulic conductivity.

Detection and Delineation of Localized Flooding from WorldView-2 Multispectral Data

Remote sensing technology serves as a powerful tool for analyzing geospatial characteristics of flood inundation events at various scales. However, the performance of remote sensing methods depends heavily on the flood characteristics and landscape settings. Difficulties might be encountered in mapping the extent of localized flooding with shallow water on riverine floodplain areas, where patches of herbaceous vegetation are interspersed with open water surfaces. To address the difficulties in mapping inundation on areas with complex water and vegetation compositions, a high spatial resolution dataset has to be used to reduce the problem of mixed pixels. The main objective of our study was to investigate the possibilities of using a single date WorldView-2 image of very high spatial resolution and supporting data to analyze spatial patterns of localized flooding on a riverine floodplain. We used a decision tree algorithm with various combinations of input variables including spectral bands of the WorldView-2 image, selected spectral indices dedicated to mapping water surfaces and vegetation, and topographic data. The overall accuracies of the twelve flood extent maps derived with the decision tree method and performed on both pixels and image objects ranged between 77% and 95%. The highest mapping overall accuracy was achieved with a method that utilized all available input data and the object-based image analysis. Our study demonstrates the possibility of using single date WorldView-2 data for analyzing flooding events at high spatial detail despite the absence of spectral bands from the short-waveform region that are frequently used in water related studies. Our study also highlights the importance of topographic data in inundation analyses. The greatest difficulties were met in mapping water surfaces under dense canopy herbaceous vegetation, due to limited water surface exposure and the dominance of vegetation reflectance.

Transport-distance specific SOC distribution: Does it skew erosion induced C fluxes?

The net effect of soil erosion by water, as a sink or source of atmospheric carbon dioxide (CO2), is determined by the spatial (re-)distribution and stability of eroded soil organic carbon (SOC), and the dynamic replacement of eroded C by the production of new photosynthate. The depositional position of eroded SOC is a function of the transport distances of soil fractions where the SOC is stored. In theory, the transport distances of soil fractions are related to their settling velocities under given flow conditions. Yet, very few field investigations have been conducted to examine the actual movement of eroded soil fractions along hillslopes, let alone the re-distribution pattern of SOC fractions. Eroding sandy soils and sediment were sampled after a series of rainfall events along a slope on a freshly seeded cropland in Jutland, Denmark. All the soil samples were fractionated into five settling classes using a settling tube apparatus. The spatial distribution of soil settling classes shows a coarsening effect immediately below the eroding slope, followed by a fining trend at the slope tail. These findings support the validity of the conceptual model proposed by Starr et al. (Land Degrad Dev 11:83–91, 2000) to predict SOC redistribution patterns along hillslopes. The δ13C values of soil fractions were more positive at the footslope than on the slope shoulder or at the slope tail, suggesting enhanced decomposition rate of fresh SOC input at the footslope during or after erosion-induced transport. Pronounced CO2 emission rates at the slope tail also suggest a higher potential for decomposition of the eroded SOC after deposition. Overall, our results illustrate that immediate deposition of fast settling soil fractions and the associated SOC at footslopes, and potential CO2 emissions during or immediately after transport, must be appropriately accounted for in attempts to quantify the role of soil erosion in terrestrial C sequestration. A SOC erodibility parameter based on actual settling velocity distribution of eroded fractions is needed to better calibrate soil erosion models.

Associations between soil texture, soil water characteristics and earthworm populations in grassland

Abstract The aim of the present study was to investigate the relationships between soil physical characteristics and earthworms in a regional-scale field study in Denmark. The earthworm populations along within-field gradients in soil texture were quantified at five field sites, representing dominant soil types of Denmark. Eleven earthworm species were found, but populations were mainly dominated by Aporrectodea tuberculata and A. longa. Despite considerable variation in soil parameters across the five study sites the results suggest that the biomass of anecic worms (or A. longa as a species) was not causally associated with the soil parameters studied. This indicates that there must be other causal factors associated with the abundance (and composition) of anecic worms that are not among the soil texture and structure parameters studied. On the other hand, soil texture (Coarse sand) was associated with the abundance of the dominant endogeic species, A. tuberculata, but not endogeic worms in general. It was hypothesized that anecic and endogeic earthworms might respond to local soil water characteristics rather than soil texture, but this hypothesis could not be confirmed with the present data.

Using Vis-NIR Spectroscopy for Monitoring Temporal Changes in Soil Organic Carbon

Abstract Monitoring the spatial and temporal changes in soil organic carbon (SOC) brought about by climate change and agricultural practices is challenging because existing SOC monitoring methods are very time and resource consuming. This study examined the use of visible near-infrared spectroscopy (Vis-NIR) as a speedy method to predict SOC and to monitor spatial and temporal changes in SOC compared with labor-intensive traditional laboratory (TL) measurements. For SOC prediction, topsoil (0–25 cm) and subsoil (25–50 cm) samples in the Danish soil spectral library for the years 1986 and 2009 were used. Empirical Bayesian Kriging was used to map SOC. The Vis-NIR predictions indicated that average topsoil and subsoil SOC had decreased slightly in Denmark from 1986 to 2009, and this was confirmed by TL measurements of SOC. In East Denmark, Vis-NIR predictions differed significantly from the measured SOC values. For subsoil samples, the ability of Vis-NIR to predict SOC levels varied. In West Jutland, Central Jutland, North Jutland, and Thy, Vis-NIR–predicted SOC levels did not differ from TL-measured levels, showing good predictive ability. For topsoil samples, the spatial pattern of change in TL-measured and predicted SOC was consistent during the 23-year study period, but there were significant discrepancies in the corresponding SOC change patterns for subsoil samples. To conclude, Vis-NIR is a promising method for monitoring spatial and temporal changes in SOC at the national scale, especially in the topsoil. Some difficulties can arise in low SOC subsoils, so more systematic work is needed to improve the method for practical applications.