H. W. Herrmann

Carbonaceous aerosol over the Indian Ocean: OC/EC fractions and selected specifications from size‐segregated onboard samples

[1]xa0Concentrations and mass fractions of organic carbon, elemental carbon, and numerous organic species have been determined for submicrometer and supermicrometer particles in the Indian Ocean on the cruise of the R/V Ron Brown during INDOEX in February/March 1999. The total carbon (TC) concentration was low for air masses originating from the southern hemisphere of the Indian Ocean, where only small amounts of organic carbon (OC) could be detected in supermicrometer (sea salt) particles. The OC concentration was typically more than one order of magnitude higher in the northern Indian Ocean, where continental air masses were encountered, both for submicrometer and supermicrometer particles. Elemental carbon (EC) was mostly found in submicrometer particles, increasing up to more than two orders of magnitude in the northern part compared to the southern part of the Indian Ocean. The mass fraction of carbonaceous material was in the range of 6–15% and 2–12% for submicrometer and supermicrometer particles, respectively, with the higher values for more polluted air masses. A high degree of mixing with light scattering material is the main reason for high-absorption coefficients. The absorption efficiency is higher for lower mass fractions of EC. Various short-chain dicarboxylic and hydroxylated dicarboxylic acids have been determined. Dicarboxylic acids were mostly found in supermicrometer particles, whereas hydroxylated dicarboxylic acids showed up mainly in submicrometer particles. Alkanes and polycyclic aromatic hydrocarbons have been found in small amounts, leading to the conclusion that an important part of the organic material is of secondary origin. This is confirmed by the good correlation of the sum of carboxylic acids with OC, nitrate with a less pronounced correlation with sulfate. However, low OC/EC ratios indicate the existence of primary OC.

Anomalous yield reduction in direct-drive deuterium/tritium implosions due to H3e additiona)

Glass capsules were imploded in direct drive on the OMEGA laser [Boehly et al., Opt. Commun. 133, 495 (1997)] to look for anomalous degradation in deuterium/tritium (DT) yield and changes in reaction history with H3e addition. Such anomalies have previously been reported for D/H3e plasmas but had not yet been investigated for DT/H3e. Anomalies such as these provide fertile ground for furthering our physics understanding of inertial confinement fusion implosions and capsule performance. Anomalous degradation in the compression component of yield was observed, consistent with the “factor of 2” degradation previously reported by Massachusetts Institute of Technology (MIT) at a 50% H3e atom fraction in D2 using plastic capsules [Rygg, Phys. Plasmas 13, 052702 (2006)]. However, clean calculations (i.e., no fuel-shell mixing) predict the shock component of yield quite well, contrary to the result reported by MIT but consistent with Los Alamos National Laboratory results in D2/H3e [Wilson et al., J. Phys.: Conf....

D-T gamma-to-neutron branching ratio determined from inertial confinement fusion plasmasa)

A new deuterium-tritium (D-T) fusion gamma-to-neutron branching ratio [3H(d,γ)5He/3H(d,n)4He] value of (4.2u2009±u20092.0)u2009×u200910−5 was recently reported by this group [Y. Kim et al. Phys. Rev. C (submitted)]. This measurement, conducted at the OMEGA laser facility located at the University of Rochester, was made for the first time using inertial confinement fusion (ICF) plasmas. Neutron-induced backgrounds are significantly reduced in these experiments as compared to traditional beam-target accelerator-based experiments due to the short pulse nature of ICF implosions and the use of gas Cherenkov γ-ray detectors with fast temporal responses and inherent energy thresholds. It is expected that this ICF-based measurement will help resolve the large and long-standing inconsistencies in previously reported accelerator-based values, which vary by a factor of approximately 30. The reported value at ICF conditions was determined by averaging the results of two methods: (1) a direct measurement of ICF D-T γ-ray and neutron ...

Measurement of areal density in the ablators of inertial-confinement-fusion capsules via detection of ablator (n, n′γ) gamma-ray emission

We report the first gamma-ray-based measurements of the areal density of ablators in inertial-confinement-fusion capsule implosions. The measurements, made at the OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)], used observations of gamma rays arising from inelastic scattering of 14.1-MeV deuterium-tritium (DT) neutrons on 12C nuclei in the compressed plastic ablators. The emission of 12C(n,n′γ) gamma rays from the capsules is detected using the Gamma Reaction History instrument [H. W. Herrmann et al., J. Phys.: Conf. Ser. 244, 032047 (2010)] operating at OMEGA. From the ratio of a capsules 12C(n,n′γ) emission to the emission from the same processes in an in situ reference graphite “puck” of known mass and geometry [N. M. Hoffman et al., in IFSA 2011 proceedings (submitted)], we determine the time-averaged areal density of 12C in the capsules compressed ablator. Measured values of total ablator areal density for thirteen imploded capsules, in the range 23u2009±u200910 to 58u2009±u200914u2009mg/cm2, are comp...

Multi-shot analysis of the gamma reaction history diagnostic.

The gamma reaction history diagnostic at the National Ignition Facility has the capability to determine a number of important performance metrics for cryogenic deuterium-tritium implosions: the fusion burn width, bang time and yield, as well as the areal density of the compressed ablator. Extracting those values from the measured γ rays of an implosion, requires accounting for a γ-ray background in addition to the impulse response function of the instrument. To address these complications, we have constructed a model of the γ-ray signal, and are developing a simultaneous multi-shot fitting routine to constrain its parameter space.

Ultra-high speed photomultiplier tubes with nanosecond gating for fusion diagnostics

Fusion diagnostics can involve the measurement of ultra-fast optical pulses, often in close temporal proximity. We present a solution for the diagnostics of gamma reaction history and neutron time of flight by using microchannel plate based photomultiplier tubes (PMTs). The time response of the PMTs can be as fast as 100 ps FWHM and with a gain of up to 10(7). To observe small events in close temporal proximity to much larger signals such as the down-scattered fraction, the response of MCP-PMTs can be gated with an on∕off ratio of up to 10(13) in just 2 ns.

Gamma Reaction History ablator areal density constraints upon correlated diagnostic modeling of National Ignition Facility implosion experiments

The inelastic neutron scattering induced γ-ray signal from 12C in an Inertial Confinement Fusion capsule is demonstrated to be an effective and general diagnostic for shell ablator areal density. Experimental acquisition of the time-integrated signal at 4.4u2009MeV using threshold detection from four gas Cerenkov cells provides a direct measurement of the 12C areal density near stagnation. Application of a three-dimensional isobaric static model of data acquired in a recent high neutron yield National Ignition Facility experimental campaign reveals two general trends: smaller remaining ablator mass at stagnation and higher shell density with increasing laser drive.

Characterizing chemical transformation of organophosphorus compounds by 13C and 2H stable isotope analysis

Continuous and excessive use of organophosphorus compounds (OPs) has led to environmental contaminations which raise public concerns. This study investigates the isotope fractionation patterns of OPs in the aquatic environment dependence upon hydrolysis, photolysis and radical oxidation processes. The hydrolysis of parathion (EP) and methyl parathion (MP) resulted in significant carbon fractionation at lower pH (pH2-7, εC=-6.9~-6.0‰ for EP, -10.5~-9.9‰ for MP) but no detectable carbon fractionation at higher pH (pH12). Hydrogen fractionation was not observed during any of the hydrolysis experiments. These results indicate that compound specific isotope analysis (CSIA) allows distinction of two different pH-dependent pathways of hydrolysis. Carbon and hydrogen isotope fractionation were determined during UV/H2O2 photolysis of EP and tris(2-chloroethyl) phosphate (TCEP). The constant δ2H values determined during the OH radical reaction of EP suggested that the rate-limiting step proceeded through oxidative attack by OH radical on the PS bond. The significant H isotope enrichment suggested that OH radical oxidation of TCEP was caused by an H-abstraction during the UV/H2O2 processes (εH=-56±3‰). Fenton reaction was conducted to validate the H isotope enrichment of TCEP associated with radical oxidation, which yielded εH of -34±5‰. Transformation products of OPs during photodegradation were identified using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS). This study highlights that the carbon and hydrogen fractionation patterns have the potential to elucidate the transformation of OPs in the environment.

Using inertial fusion implosions to measure the T+He3 fusion cross section at nucleosynthesis-relevant energies

Light nuclei were created during big-bang nucleosynthesis (BBN). Standard BBN theory, using rates inferred from accelerator-beam data, cannot explain high levels of ^{6}Li in low-metallicity stars. Using high-energy-density plasmas we measure the T(^{3}He,γ)^{6}Li reaction rate, a candidate for anomalously high ^{6}Li production; we find that the rate is too low to explain the observations, and different than values used in common BBN models. This is the first data directly relevant to BBN, and also the first use of laboratory plasmas, at comparable conditions to astrophysical systems, to address a problem in nuclear astrophysics.

Direct Probing of Criegee Intermediates from Gas-Phase Ozonolysis Using Chemical Ionization Mass Spectrometry

Criegee intermediates (CIs), mainly formed from gas-phase ozonolysis of alkenes, are considered as atmospheric oxidants besides OH and NO3 radicals as well as ozone. Direct CI measurement techniques are inevitably needed for reliable assessment of CIs role in atmospheric processes. We found that CIs from ozonolysis reactions can be directly probed by means of chemical ionization mass spectrometry with a detection limit of about 104-105 molecules cm-3. Results from quantum chemical calculations support the experimental findings. The simplest CI, CH2OO, is detectable as an adduct with protonated ethers, preferably with protonated tetrahydrofuran. Kinetic measurements yielded k(CH2OO + SO2) = (3.3 ± 0.9) × 10-11 and k(CH2OO + acetic acid) = (1.25 ± 0.30) × 10-10 cm3 molecule-1 s-1 at 295 ± 2 K, in very good agreement with recent measurements using diiodomethane photolysis for CH2OO generation. CIs from the ozonolysis of cyclohexene, acting as surrogate for cyclic terpenes, are followed as protonated species (CI)H+ using protonated amines as reagent ions. Kinetic investigations indicate a different reactivity of cyclohexene-derived CIs compared with that of simple CIs, such as CH2OO. It is supposed that the aldehyde group significantly influences the CI reactivity of the cyclohexene-derived CIs. The direct CI detection method presented here should allow study of the formation and reactivity of a wide range of different CIs formed from atmospheric ozonolysis reactions.