İzzet Şener

Azocalixarenes. 1: synthesis, characterization and investigation of the absorption spectra of substituted azocalix[4]arenes

Abstract A series of novel azocalix[4]arene dyes (1–12) were prepared by linking o-, m-, p-chloroaniline, o-, m-, p-nitroaniline, o-, m-, p-toluidine, m-, p-anisidine and aniline to calix[4]arene through a diazo-coupling reaction. These compounds were characterized by UV-vis, FT-IR and 1H-NMR spectroscopic techniques and elemental analysis. The effect of varying pH and solvent upon the absorption ability of azocalixarenes substituted with electron-donating and electron-withdrawing groups at their o-, m-, p- position was examined. Observed results were compared with those found for unsubstituted azocalix[4]arene. Concentration effects on the visible absorption maxima of the dyes are also reported.

Comparison of Adsorption and Selectivity Characteristics for 4‐Nitrophenol Imprinted Polymers Prepared via Bulk and Suspension Polymerization

Abstract This manuscript describes a method for the selective removal of phenolic compounds from aqueous medium by imprinted polymers, which is the noncovalent approach based on both hydrogen bonding and hydrophobic interaction. These imprinted polymers were prepared by both bulk polymerization (IP1) and suspension polymerization (IP2) of methacryloylantipyrine (MAAP) in the presence of azobisisobutyronitrile (AIBN) as an initiator and cross‐linking EGDMA and was imprinted with 4‐nitrophenol. The effect of polymerization technique (bulk and suspension) on the adsorption and selectivity of phenolics was investigated. The maximum adsorption capacities of these IP1 and IP2 polymers were 25.9 and 27.6 mg/g for 4‐nitrophenol, respectively. It was observed that the 4‐nitrophenol binding capacity decreased with increasing pH. The selectivity experiments showed that the polymer prepared via suspension polymerization has high‐binding ability for 4‐nitrophenol to other phenolics compared to the polymer prepared via bulk polymerization.