Jakub Trubač

A plate-kinematic model for the assembly of the Bohemian Massif constrained by structural relationships around granitoid plutons

Abstract This paper summarizes the current knowledge on the nature, kinematics and timing of movement along major tectonic boundaries in the Bohemian Massif and demonstrates how the Variscan plutonism and deformation evolved in space and time. Four main episodes are recognized: (1) Late Devonian–early Carboniferous subduction and continental underthrusting of the Saxothuringian Unit beneath the Teplá–Barrandian Unit resulted in the orogen-perpendicular shortening and growth of an inboard magmatic arc during c. 354–346 Ma; (2) the subduction-driven shortening was replaced by collapse of the Teplá–Barrandian upper crust, exhumation of the high-grade (Moldanubian) core of the orogen at c. 346–337 Ma and by dextral strike-slip along orogen-perpendicular NW–SE shear zones; (3) following closure of a Rhenohercynian Ocean basin, the Brunia microplate was underthrust beneath the eastern flank of the Saxothuringian/Teplá–Barrandian/Moldanubian ‘assemblage’; this process commenced at c. 346 Ma in the NE and ceased at c. 335 Ma in the SW; and (4) late readjustments within the amalgamated Bohemian Massif included crustal exhumation and mainly S-type granite plutonism along the edge of the Brunia indentor at c. 330–327 Ma, and peripheral tectonothermal activity driven by strike-slip faulting and possibly mantle delamination around the consolidated Bohemian Massifs interior until late Carboniferous–earliest Permian times.

Isotopic Tracing of Thallium Contamination in Soils Affected by Emissions from Coal-Fired Power Plants

Here, for the first time, we report the thallium (Tl) isotope record in moderately contaminated soils with contrasting land management (forest and meadow soils), which have been affected by emissions from coal-fired power plants. Our findings clearly demonstrate that Tl of anthropogenic (high-temperature) origin with light isotope composition was deposited onto the studied soils, where heavier Tl (ε(205)Tl ∼ -1) naturally occurs. The results show a positive linear relationship (R(2) = 0.71) between 1/Tl and the isotope record, as determined for all the soils and bedrocks, also indicative of binary Tl mixing between two dominant reservoirs. We also identified significant Tl isotope variations within the products from coal combustion and thermo-desorption experiments with local Tl-rich coal pyrite. Bottom ash exhibited the heaviest Tl isotope composition (ε(205)Tl ∼ 0), followed by fly ash (ε(205)Tl between -2.5 and -2.8) and volatile Tl fractions (ε(205)Tl between -6.2 and -10.3), suggesting partial Tl isotope fractionations. Despite the evident role of soil processes in the isotope redistributions, we demonstrate that Tl contamination can be traced in soils and propose that the isotope data represent a possible tool to aid our understanding of postdepositional Tl dynamics in surface environments for the future.

Thallium isotopes in metallurgical wastes/contaminated soils: a novel tool to trace metal source and behavior

Thallium (Tl) concentration and isotope data have been recorded for contaminated soils and a set of industrial wastes that were produced within different stages of Zn ore mining and metallurgical processing of Zn-rich materials. Despite large differences in Tl levels of the waste materials (1-500mgkg-1), generally small changes in ε205Tl values have been observed. However, isotopically lighter Tl was recorded in fly ash (ε205Tl∼-4.1) than in slag (ε205Tl∼-3.3), implying partial isotope fractionation during material processing. Thallium isotope compositions in the studied soils reflected the Tl contamination (ε205Tl∼-3.8), despite the fact that the major pollution period ended more than 30 years ago. Therefore, we assume that former industrial Tl inputs into soils, if significant, can potentially be traced using the isotope tracing method. We also suggest that the isotope redistributions occurred in some soil (subsurface) horizons, with Tl being isotopically heavier than the pollution source, due to specific sorption and/or precipitation processes, which complicates the discrimination of primary Tl. Thallium isotope analysis proved to be a promising tool to aid our understanding of Tl behavior within the smelting process, as well as its post-depositional dynamics in the environmental systems (soils).

Copper isotopic record in soils and tree rings near a copper smelter, Copperbelt, Zambia

The copper (Cu) content and isotopic composition were studied in soils and in pine tree rings at locations close to and far from the Cu smelter, located at Kitwe, Zambia. The soil in the remote area contained 25-75mgkg-1 Cu, whereas the soil close to the smelter contained 207-44,000mgkg-1 Cu. The δ65Cu at the remote area and close to the smelter varied in the range -0.40 to -0.11‰, and -0.44 to 0.01‰ respectively. The δ65Cu of the surface soil at both profiles (-0.44 to -0.40‰) is similar to the isotopic composition of the concentrates processed in the smelter (-0.75 to -0.45‰), i.e. both locations are affected by Cu ore dust. The increase in the δ65Cu in the direction towards the centre of the profile is caused by the oxidative dissolution of Cu(I) from ore minerals, during which heavier Cu is released. In deeper parts of the profile, there is a slight decrease in δ65Cu because of easier mobilisation of the lighter isotope. The tree rings at the two locations differ in the total contents and isotopic composition. At the less contaminated site, the Cu contents equal 0.4 to 1.1mgkg-1 while, at the polluted site, the Cu contents vary in the range 3 to 47mgkg-1. Whereas, at the less contaminated location, the tree rings are substantially enriched in lighter Cu (δ65Cu=-0.76 to -2.2‰), at locations close to the smelter the tree rings have an isotopic composition (-0.31 to -0.88‰) similar to that of the contaminated soil or processed ore. The isotopic compositions of the tree rings close to the smelter are affected particularly by interception of dust containing Cu ore. The δ13C in tree rings demonstrate the interconnection of acidification and Cu mobility.

Magnetic fabric of the Říčany granite, Bohemian Massif

Los braquiopodos retzidinos son una fraccion menor de las faunas devonicas de la CordilleraCantabrica (Norte de Espana). Aparte de un par de formas raras, impublicadas, del Praguiense delDominio Palentino y del Emsiense inferior del Astur-Leones, proximas al genero Rhynchospirina, ellinaje alcanzo su maximo de diversidad en la parte superior del Emsiense, con dos especies del generoRetzia, R. adrieni y R. cf. prominula, Cooperispira subferita y, quizas, una forma impublicada dePlectospira. El grupo no es conocido en el resto del Devonico y reaparece en el Pensilvaniense con algunasformas del genero Hustedia. En este trabajo se propone un nuevo taxon de la Familia Retziidae,Argovejia n.gen., de la parte final del Emsiense superior de Asturias y Leon, constituido por su especietipo,A. talenti n.sp. y, quizas, por las formas del Emsiense superior del Macizo Armoricano (Francia)Retzia haidingeri var. armoricana y Retzia haidingeri var. dichotoma.The Ronda Depression is filled by Neogene sediments on the boundary between Subbeticreliefs, with NE-SW structural trends, and the frontal Subbetic Chaotic Complexes. The folding stylein the Subbetic Units of Western Betics is strongly controlled by the rheology of the rocks: thick andmassive beds of Jurassic limestones over Triassic marls and gypsum with plastic behaviour. Main deformationstructures in the sedimentary infill of the Ronda depression are simultaneous box folds withNNE-SSW and WNW-ESE trends that only affect its southwestern part. This distribution of folds isa consequence of the inherited fold trend that affected the basement during Early Burdigalian age.

Speciation analysis of elements accumulated in Cystoderma carcharias from clean and smelter-polluted sites

Collections of Cystoderma carcharias sporocarps were sampled from clean and smelter-polluted sites and analyzed for Ag, As, Cd, Cu, Pb, Se, and Zn contents. Concentrations of all elements were significantly higher in samples from the smelter-polluted area. Except for As and Pb, all elements were effectively accumulated in the sporocarps at both clean and polluted sites. With the highest concentration of 604 mg Cd kg-1, C. carcharias can be considered as Cd hyperaccumulator. As revealed by HPLC-ICPQQQMS analysis, the As species in sporocarps from clean and polluted areas involved besides the major arsenobetaine a variety of known and unknown arsenicals; the occurrence of dimethylarsinoylacetate and trimethylarsoniopropionate is reported for the first time for gilled fungi (Agaricales). Size-exclusion chromatography of C. carcharias extracts supported by sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) and RP-HPLC data indicated that detoxification of intracellular Cd and Cu may largely rely on metallothioneins (MT) or MT-like peptides, not phytochelatins.