Jeremy M. Grace

Plasma Treatment of Polymers

Abstract Plasma treatment of polymers encompasses a variety of plasma technologies and polymeric materials for a wide range of applications and dates back to at least the 1960s. In this article we provide a brief review of the United States patent literature on plasma surface modification technologies and a brief review of the scientific literature on investigations of the effects of plasma treatment, the nature of the plasma environment, and the mechanisms that drive the plasma–surface interaction. We then discuss low‐radio‐frequency capacitively coupled nitrogen plasmas and their characteristics, suggesting that they provide significant plasma densities and populations of reactive species for effective plasma treatments on a variety of materials, particularly when placing the sample surface in the cathode sheath region. We further discuss surface chemical characterization of treated polymers, including some results on polyesters treated in capacitively coupled nitrogen plasmas driven at 40 kHz. Finally, we connect plasma characterization with surface chemical analysis by applying a surface sites model to nitrogen uptake of poly(ethylene terephthalate) (PET) and poly(ethylene naphthalate) (PEN) treated in a 40 kHz nitrogen plasma. This example serves to suggest an interesting practical approach to comparisons of plasma treatments. In addition, it suggests an approach to defining the investigations required to conclusively identify the underlying treatment mechanisms.

Analysis of two-dimensional microdischarge distribution in dielectric-barrier discharges

The two-dimensional spatial distribution of microdischarges in atmospheric pressure dielectric-barrier discharges (DBDs) in air was studied. Experimental images of DBDs (Lichtenberg figures) were obtained using photostimulable phosphors. The storage phosphor imaging method takes advantage of the linear response of the phosphor for characterization of microdischarge intensity and position. A microdischarge interaction model in DBDs is proposed and a Monte Carlo simulation of microdischarge interactions in the discharge is presented. Comparison of modelled and experimental images indicates interactions and short-range structuring of microdischarge channels.

41.4: New Capabilities in Vacuum Thermal Evaporation Sources for Small Molecule OLED Manufacturing

A vacuum thermal evaporation source has been developed where blended or single-component organic materials are metered from a cooled reservoir to a heating element. High material utilization, very high deposition rates, and multicomponent deposition with precise composition control are features of this vaporization-on-demand source.

Experimental and numerical investigation of a capacitively coupled low-radio frequency nitrogen plasma

Abstract A capacitively coupled nitrogen discharge driven at a frequency of 40 kHz was analyzed using a particle-in-cell (PIC) code, electrical probe measurements and optical emission spectra (OES). The configuration studied is used to generate plasmas for surface modification of polymer webs and consists of a pair of coplanar electrodes spaced several centimeters from the web plane and housed in a grounded shield. Both the probe measurements and the simulations indicate the presence of a group of high-energy electrons in concentrations of order 0.1% of the bulk electron concentration. Furthermore, bulk electron temperatures from the simulations are less than 1 eV. The energetic electrons and the low temperature of the bulk electrons are both characteristics of discharges operating in the gamma regime, where secondary electron emission from ion bombardment of the cathode sustains the ionization in the discharge. Because ions can respond to the instantaneous potential at the low-driving frequency used, half of the current at the electrode location is ion current. (In contrast, displacement current from the electron motion dominates at significantly higher driving frequencies.) The energetic electrons can provide a valuable source of N + ions through dissociative ionization. The formation of the N + ion was not included in the simulation, but was detected by the OES measurements. The atomic nitrogen ions and neutrals, together with the high-energy electrons, may be responsible for the formation of nitrogen-containing species in the surface region of polymer films treated with nitrogen plasmas using the configuration studied in this work.