Leticia A. Alba-Aldave

Tertiary arc-magmatism of the Sierra Madre del Sur, Mexico, and its transition to the volcanic activity of the Trans-Mexican Volcanic Belt

The Tertiary magmatic rocks of the Sierra Madre del Sur (SMS) are broadly distributed south of the Trans-Mexican Volcanic Belt (TMVB) and extend to the southern continental margin of Mexico. They represent magmatic activity that originated at a time characterized by significant changes in the plate interactions in this region as a result of the formation of the Caribbean plate and the southeastward displacement of the Chortis block along the continental margin of southwestern Mexico. The change from SMS magmatism to an E‐W trending TMVB volcanism in Miocene time reflects the tectonic evolution of southwestern Mexico during these episodes of plate tectonic rearrangement. The distribution and petrographic characteristics of the magmatic rocks of the SMS define two belts of NW orientation. The first is represented by the nearly continuous coastal plutonic belt (CPB), which consists of batholiths and stocks of predominantly felsic composition. The second belt is inland of the first and consists of discontinuously distributed volcanic fields with piles of andesitic to rhyolitic flows, as well as epiclastic and pyroclastic materials. These two belts were emplaced along a continental crust segment constituted by a mosaic of basements with recognizable petrologic and isotopic diAerences. These basements originated during diAerent tectono-thermal events developed from the Proterozoic to the Mesozoic. Major and trace element data of the SMS magmatic rocks define a clear sub-alkaline tendency. Variations in the general geochemical behavior and in the Sr and Nd isotopic ratios indicate diAerent degrees of magmatic diAerentiation and/or crustal contamination. These variations, specially in the inland Oligocene volcanic regions of Guerrero and Oaxaca states, seem to have been controlled by the particular tectonic setting at the time of magmatism. In northwestern Oaxaca greater extension related to transtensional tectonics produced less diAerentiated volcanic rocks with an apparently lower degree of crustal contamination than those of northeastern Guerrero. The geochronologic data produced by us up to now, in addition to those previously reported, indicate that the Tertiary magmatic rocks of the SMS range in age from Paleocene to Miocene. The general geochronologic patterns indicate a southeastward decrease in the age of igneous activity, rather than a gradual northeastward migration of the locus of magmatism toward the present-day TMVB. SMS magmatic rocks exposed to the west of the 1008W meridian are dominantly Late Cretaceous to Eocene, while those to the east range from Oligocene to Miocene, also following a southeastward age-decreasing trend. Paleocene and Eocene magmatic rocks of the western region of the SMS seem to keep a general NNW trend similar to that of the Tertiary magmatic rocks of the Sierra Madre Occidental (SMO). In the eastern region of the SMS the Oligocene magmatic rocks show a trend that roughly defines an ESE orientation. The change in the trend of arc magmatism may be the eAect of the landward migration of the trench, for a given longitude, as a result of the displacement of the Chortis block. The

Rhyolitic volcanism in extension zone associated with strike-slip tectonics in the Taxco region, southern Mexico

Abstract The Taxco Volcanic Field (TVF) is part of a broad magmatic province in southern Mexico. It constitutes an isolated zone of deeply dissected volcanic rocks encircled by outcrops of Mesozoic sedimentary and volcano-sedimentary units. A thick unit of rhyolitic lava flows associated with domes and at least two ignimbrite units forms the TVF. This volcanic sequence is distributed within a well defined zone, it overlies and is in part contemporaneous with continental sedimentary beds limited by major faults. Geochronologic data indicate that most rhyolitic volcanism in the area is Oligocene in age and synchronous with episodes of strike-slip faulting. We document two successive phases of strike-slip faulting for the late Eocene–early Oligocene interval, the first with NNW extension and the second with NE extension. In both cases pre-existing structures were reactivated and sedimentary basins were developed in response to displacement along major faults. The stratigraphic sequence gives evidence that the TVF is located in an extensional basin associated to strike-slip faults. The evolution of the basin underwent a change from sedimentary deposition with subsidence to piling up by volcanism. The result of this change was the development of a volcanic pile with elevations higher than the surrounding Mesozoic rocks. According to the fault kinematics, stratigraphy and the volume of volcanic rocks, the rhyolitic volcanism was emplaced in the area of maximum extension, showing that magma flowed into low pressure zones. The small number of faults within the Oligocene volcanic sequence suggests that volcanism inhibited normal faulting and that magma partially filled the space generated in the extended zone produced by the strike-slip faulting.

Computer simulation and experimental self-assembly of irradiated glycine amino acid under magnetic fields: Its possible significance in prebiotic chemistry

Ionizing radiation may have played a relevant role in chemical reactions for prebiotic biomolecule formation on ancient Earth. Environmental conditions such as the presence of water and magnetic fields were possibly relevant in the formation of organic compounds such as amino acids. ATR-FTIR, Raman, EPR and X-ray spectroscopies provide valuable information about molecular organization of different glycine polymorphs under static magnetic fields. γ-glycine polymorph formation increases in irradiated samples interacting with static magnetic fields. The increase in γ-glycine polymorph agrees with the computer simulations. The AM1 semi-empirical simulations show a change in the catalyst behavior and dipole moment values in α and γ-glycine interaction with the static magnetic field. The simulated crystal lattice energy in α-glycine is also affected by the free radicals under the magnetic field, which decreases its stability. Therefore, solid α and γ-glycine containing free radicals under static magnetic fields might have affected the prebiotic scenario on ancient Earth by causing the oligomerization of glycine in prebiotic reactions.

Ca‐poor Pyroxene Raman Characteristics in H Ordinary Chondrites

In this work we present the zoning of the Ca‐poor pyroxenes polymorphs and its Raman characteristics of crystal within chondrules in H3.3, H4, H5 and H6 ordinary chondrite suite. Applying the Principal Component Analysis (PCA) method to the Raman data and plotting the first and second principal components, we were able to differentiate their petrologic types in four separate fields.