Lourdes Sánchez Nácher

OPTIMIZACIÓN DEL TRATAMIENTO POR PLASMA ATMOSFÉRICO SOBRE LÁMINAS DE POLIETILENO DE BAJA DENSIDAD

The vast majority of polymers and composites have low surface energy; this is due to the low presence of functional groups on their surface which results in low adhesive properties. In order to modify this intrinsic property chemical and physical processes are commonly used. These processes resent disadvantages, such as the use of products harmful to the environment. An alternative to these processes is the use of plasma technology. The main objective of this study is the improvement of the adhesive properties of the low density polyethylene (LDPE). In order to achieve the target, atmospheric plasma pretreatment has been optimized in order to promote subsequent adhesion processes, as the ones needed in the toy industry or the application of dyes or printing on surfaces.Plasma surface treatment is a clean process from the environmental viewpoint. This process does not emit any residue and it is easy to implement in an industrial process. Moreover the atmospheric plasma treatment is suitable to be applied in a large variety of materials even at high speeds when the treatment lasts less than a few seconds.In the present study it is examined the physical and chemical processes that occur in the LDPE surface as function of speed rate and distance of treatment. An increase both of the polar groups on the surface and the roughness after the treatment may increase its adhesive properties. It has been analyzed the influence of the speed rate and the nozzle distance on the final results. The adhesive properties have been evaluated using the T-peel test. The results show that at low speeds rates and low nozzle/substrate distance there is a greater inclusion of polar molecules at the surface. Consequently the adhesion properties of LDPE are improved.