M. Formisano

Ammoniated phyllosilicates with a likely outer Solar System origin on (1) Ceres

Studies of the dwarf planet (1) Ceres using ground-based and orbiting telescopes have concluded that its closest meteoritic analogues are the volatile-rich CI and CM carbonaceous chondrites. Water in clay minerals, ammoniated phyllosilicates, or a mixture of Mg(OH)2 (brucite), Mg2CO3 and iron-rich serpentine have all been proposed to exist on the surface. In particular, brucite has been suggested from analysis of the mid-infrared spectrum of Ceres. But the lack of spectral data across telluric absorption bands in the wavelength region 2.5 to 2.9 micrometres—where the OH stretching vibration and the H2O bending overtone are found—has precluded definitive identifications. In addition, water vapour around Ceres has recently been reported, possibly originating from localized sources. Here we report spectra of Ceres from 0.4 to 5 micrometres acquired at distances from ~82,000 to 4,300 kilometres from the surface. Our measurements indicate widespread ammoniated phyllosilicates across the surface, but no detectable water ice. Ammonia, accreted either as organic matter or as ice, may have reacted with phyllosilicates on Ceres during differentiation. This suggests that material from the outer Solar System was incorporated into Ceres, either during its formation at great heliocentric distance or by incorporation of material transported into the main asteroid belt.

Bright carbonate deposits as evidence of aqueous alteration on (1) Ceres

The typically dark surface of the dwarf planet Ceres is punctuated by areas of much higher albedo, most prominently in the Occator crater. These small bright areas have been tentatively interpreted as containing a large amount of hydrated magnesium sulfate, in contrast to the average surface, which is a mixture of low-albedo materials and magnesium phyllosilicates, ammoniated phyllosilicates and carbonates. Here we report high spatial and spectral resolution near-infrared observations of the bright areas in the Occator crater on Ceres. Spectra of these bright areas are consistent with a large amount of sodium carbonate, constituting the most concentrated known extraterrestrial occurrence of carbonate on kilometre-wide scales in the Solar System. The carbonates are mixed with a dark component and small amounts of phyllosilicates, as well as ammonium carbonate or ammonium chloride. Some of these compounds have also been detected in the plume of Saturn’s sixth-largest moon Enceladus. The compounds are endogenous and we propose that they are the solid residue of crystallization of brines and entrained altered solids that reached the surface from below. The heat source may have been transient (triggered by impact heating). Alternatively, internal temperatures may be above the eutectic temperature of subsurface brines, in which case fluids may exist at depth on Ceres today.

The diurnal cycle of water ice on comet 67P/Churyumov–Gerasimenko

Observations of cometary nuclei have revealed a very limited amount of surface water ice, which is insufficient to explain the observed water outgassing. This was clearly demonstrated on comet 9P/Tempel 1, where the dust jets (driven by volatiles) were only partially correlated with the exposed ice regions. The observations of 67P/Churyumov–Gerasimenko have revealed that activity has a diurnal variation in intensity arising from changing insolation conditions. It was previously concluded that water vapour was generated in ice-rich subsurface layers with a transport mechanism linked to solar illumination, but that has not hitherto been observed. Periodic condensations of water vapour very close to, or on, the surface were suggested to explain short-lived outbursts seen near sunrise on comet 9P/Tempel 1. Here we report observations of water ice on the surface of comet 67P/Churyumov–Gerasimenko, appearing and disappearing in a cyclic pattern that follows local illumination conditions, providing a source of localized activity. This water cycle appears to be an important process in the evolution of the comet, leading to cyclical modification of the relative abundance of water ice on its surface.

Exposed water ice on the nucleus of comet 67P/Churyumov–Gerasimenko

Although water vapour is the main species observed in the coma of comet 67P/Churyumov–Gerasimenko and water is the major constituent of cometary nuclei, limited evidence for exposed water-ice regions on the surface of the nucleus has been found so far. The absence of large regions of exposed water ice seems a common finding on the surfaces of many of the comets observed so far. The nucleus of 67P/Churyumov–Gerasimenko appears to be fairly uniformly coated with dark, dehydrated, refractory and organic-rich material. Here we report the identification at infrared wavelengths of water ice on two debris falls in the Imhotep region of the nucleus. The ice has been exposed on the walls of elevated structures and at the base of the walls. A quantitative derivation of the abundance of ice in these regions indicates the presence of millimetre-sized pure water-ice grains, considerably larger than in all previous observations. Although micrometre-sized water-ice grains are the usual result of vapour recondensation in ice-free layers, the occurrence of millimetre-sized grains of pure ice as observed in the Imhotep debris falls is best explained by grain growth by vapour diffusion in ice-rich layers, or by sintering. As a consequence of these processes, the nucleus can develop an extended and complex coating in which the outer dehydrated crust is superimposed on layers enriched in water ice. The stratigraphy observed on 67P/Churyumov–Gerasimenko is therefore the result of evolutionary processes affecting the uppermost metres of the nucleus and does not necessarily require a global layering to have occurred at the time of the comet’s formation.

Nature, formation, and distribution of carbonates on Ceres

Hydrated carbonates indicate that the surface of Ceres is recent and dehydration is ongoing, implying a still-evolving body. Different carbonates have been detected on Ceres, and their abundance and spatial distribution have been mapped using a visible and infrared mapping spectrometer (VIR), the Dawn imaging spectrometer. Carbonates are abundant and ubiquitous across the surface, but variations in the strength and position of infrared spectral absorptions indicate variations in the composition and amount of these minerals. Mg-Ca carbonates are detected all over the surface, but localized areas show Na carbonates, such as natrite (Na2CO3) and hydrated Na carbonates (for example, Na2CO3·H2O). Their geological settings and accessory NH4-bearing phases suggest the upwelling, excavation, and exposure of salts formed from Na-CO3-NH4-Cl brine solutions at multiple locations across the planet. The presence of the hydrated carbonates indicates that their formation/exposure on Ceres’ surface is geologically recent and dehydration to the anhydrous form (Na2CO3) is ongoing, implying a still-evolving body.

Seasonal exposure of carbon dioxide ice on the nucleus of comet 67P/Churyumov-Gerasimenko

Rosetta observes sublimating surface ices Comets are “dirty snowballs” made of ice and dust, but they are dark because the ice sublimates away, leaving some of the dust behind on the surface. The Rosetta spacecraft has provided a close-up view of the comet 67P/Churyumov-Gerasimenko as it passes through its closest point to the Sun (see the Perspective by Dello Russo). Filacchione et al. detected the spectral signature of solid CO2 (dry ice) in small patches on the surface of the nucleus as they emerged from local winter. By modeling how the CO2 sublimates, they constrain the composition of comets and how ices generate the gaseous coma and tail. Fornasier et al. studied images of the comet and discovered bright patches on the surface where ice was exposed, which disappeared as the ice sublimated. They also saw frost emerging from receding shadows. The surface of the comet was noticeably less red just after local dawn, indicating that icy material is removed by sunlight during the local day. Science, this issue p. 1563, p. 1566; see also p. 1536 Solid carbon dioxide on the surface of a comet nucleus has been found by the Rosetta spacecraft. Carbon dioxide (CO2) is one of the most abundant species in cometary nuclei, but because of its high volatility, CO2 ice is generally only found beneath the surface. We report the infrared spectroscopic identification of a CO2 ice–rich surface area located in the Anhur region of comet 67P/Churyumov-Gerasimenko. Spectral modeling shows that about 0.1% of the 80- by 60-meter area is CO2 ice. This exposed ice was observed a short time after the comet exited local winter; following the increased illumination, the CO2 ice completely disappeared over about 3 weeks. We estimate the mass of the sublimated CO2 ice and the depth of the eroded surface layer. We interpret the presence of CO2 ice as the result of the extreme seasonal changes induced by the rotation and orbit of the comet.

Variations in the amount of water ice on Ceres’ surface suggest a seasonal water cycle

Local detection of increasing amount of water ice on Ceres’ surface indicates an active body and a possible seasonal cycle. The dwarf planet Ceres is known to host a considerable amount of water in its interior, and areas of water ice were detected by the Dawn spacecraft on its surface. Moreover, sporadic water and hydroxyl emissions have been observed from space telescopes. We report the detection of water ice in a mid-latitude crater and its unexpected variation with time. The Dawn spectrometer data show a change of water ice signatures over a period of 6 months, which is well modeled as ~2-km2 increase of water ice. The observed increase, coupled with Ceres’ orbital parameters, points to an ongoing process that seems correlated with solar flux. The reported variation on Ceres’ surface indicates that this body is chemically and physically active at the present time.

Design, development, and testing of an environmental P-T cell for infrared spectroscopy measurements

Water absorption bands due to superficially adsorbed molecules often dominate the near-infrared spectra of particulate minerals and rocks, when measured in the laboratory in the reflectance mode. In order to remove this, the spectral effect is thus necessary to acquire spectra of samples in vacuum and at higher temperatures. With the aim to accomplish this task, we developed an environmental cell to perform infrared spectroscopic measurements at controlled pressure-temperature conditions. Currently the cell allows one to measure reflectance spectra in the temperature range from room values up to 300 °C (573 K), in the pressure range of 103-10-6 mbar. The acquisition of spectra continuously in two distinct phases, namely, during a preliminary pumping stage (at room T) and subsequently during a heating stage (in vacuum), permits to highlight and characterize separately the effect of pressure and temperature on infrared spectra.