M. T. Capria

Spectroscopic Characterization of Mineralogy and Its Diversity Across Vesta

A New Dawn Since 17 July 2011, NASAs spacecraft Dawn has been orbiting the asteroid Vesta—the second most massive and the third largest asteroid in the solar system (see the cover). Russell et al. (p. 684) use Dawns observations to confirm that Vesta is a small differentiated planetary body with an inner core, and represents a surviving proto-planet from the earliest epoch of solar system formation; Vesta is also confirmed as the source of the howardite-eucrite-diogenite (HED) meteorites. Jaumann et al. (p. 687) report on the asteroids overall geometry and topography, based on global surface mapping. Vestas surface is dominated by numerous impact craters and large troughs around the equatorial region. Marchi et al. (p. 690) report on Vestas complex cratering history and constrain the age of some of its major regions based on crater counts. Schenk et al. (p. 694) describe two giant impact basins located at the asteroids south pole. Both basins are young and excavated enough amounts of material to form the Vestoids—a group of asteroids with a composition similar to that of Vesta—and HED meteorites. De Sanctis et al. (p. 697) present the mineralogical characterization of Vesta, based on data obtained by Dawns visual and infrared spectrometer, revealing that this asteroid underwent a complex magmatic evolution that led to a differentiated crust and mantle. The global color variations detailed by Reddy et al. (p. 700) are unlike those of any other asteroid observed so far and are also indicative of a preserved, differentiated proto-planet. Spacecraft data provide a detailed characterization of the second most massive asteroid in the solar system. The mineralogy of Vesta, based on data obtained by the Dawn spacecraft’s visible and infrared spectrometer, is consistent with howardite-eucrite-diogenite meteorites. There are considerable regional and local variations across the asteroid: Spectrally distinct regions include the south-polar Rheasilvia basin, which displays a higher diogenitic component, and equatorial regions, which show a higher eucritic component. The lithologic distribution indicates a deeper diogenitic crust, exposed after excavation by the impact that formed Rheasilvia, and an upper eucritic crust. Evidence for mineralogical stratigraphic layering is observed on crater walls and in ejecta. This is broadly consistent with magma-ocean models, but spectral variability highlights local variations, which suggests that the crust can be a complex assemblage of eucritic basalts and pyroxene cumulates. Overall, Vesta mineralogy indicates a complex magmatic evolution that led to a differentiated crust and mantle.

The organic-rich surface of comet 67P/Churyumov-Gerasimenko as seen by VIRTIS/Rosetta

The VIRTIS (Visible, Infrared and Thermal Imaging Spectrometer) instrument on board the Rosetta spacecraft has provided evidence of carbon-bearing compounds on the nucleus of the comet 67P/Churyumov-Gerasimenko. The very low reflectance of the nucleus (normal albedo of 0.060 ± 0.003 at 0.55 micrometers), the spectral slopes in visible and infrared ranges (5 to 25 and 1.5 to 5% kÅ−1), and the broad absorption feature in the 2.9-to-3.6–micrometer range present across the entire illuminated surface are compatible with opaque minerals associated with nonvolatile organic macromolecular materials: a complex mixture of various types of carbon-hydrogen and/or oxygen-hydrogen chemical groups, with little contribution of nitrogen-hydrogen groups. In active areas, the changes in spectral slope and absorption feature width may suggest small amounts of water-ice. However, no ice-rich patches are observed, indicating a generally dehydrated nature for the surface currently illuminated by the Sun.

Ammoniated phyllosilicates with a likely outer Solar System origin on (1) Ceres

Studies of the dwarf planet (1) Ceres using ground-based and orbiting telescopes have concluded that its closest meteoritic analogues are the volatile-rich CI and CM carbonaceous chondrites. Water in clay minerals, ammoniated phyllosilicates, or a mixture of Mg(OH)2 (brucite), Mg2CO3 and iron-rich serpentine have all been proposed to exist on the surface. In particular, brucite has been suggested from analysis of the mid-infrared spectrum of Ceres. But the lack of spectral data across telluric absorption bands in the wavelength region 2.5 to 2.9 micrometres—where the OH stretching vibration and the H2O bending overtone are found—has precluded definitive identifications. In addition, water vapour around Ceres has recently been reported, possibly originating from localized sources. Here we report spectra of Ceres from 0.4 to 5 micrometres acquired at distances from ~82,000 to 4,300 kilometres from the surface. Our measurements indicate widespread ammoniated phyllosilicates across the surface, but no detectable water ice. Ammonia, accreted either as organic matter or as ice, may have reacted with phyllosilicates on Ceres during differentiation. This suggests that material from the outer Solar System was incorporated into Ceres, either during its formation at great heliocentric distance or by incorporation of material transported into the main asteroid belt.

Dark material on Vesta from the infall of carbonaceous volatile-rich material

Localized dark and bright materials, often with extremely different albedos, were recently found on Vesta’s surface. The range of albedos is among the largest observed on Solar System rocky bodies. These dark materials, often associated with craters, appear in ejecta and crater walls, and their pyroxene absorption strengths are correlated with material brightness. It was tentatively suggested that the dark material on Vesta could be either exogenic, from carbon-rich, low-velocity impactors, or endogenic, from freshly exposed mafic material or impact melt, created or exposed by impacts. Here we report Vesta spectra and images and use them to derive and interpret the properties of the ‘pure’ dark and bright materials. We argue that the dark material is mainly from infall of hydrated carbonaceous material (like that found in a major class of meteorites and some comet surfaces), whereas the bright material is the uncontaminated indigenous Vesta basaltic soil. Dark material from low-albedo impactors is diffused over time through the Vestan regolith by impact mixing, creating broader, diffuse darker regions and finally Vesta’s background surface material. This is consistent with howardite–eucrite–diogenite meteorites coming from Vesta.

Bright carbonate deposits as evidence of aqueous alteration on (1) Ceres

The typically dark surface of the dwarf planet Ceres is punctuated by areas of much higher albedo, most prominently in the Occator crater. These small bright areas have been tentatively interpreted as containing a large amount of hydrated magnesium sulfate, in contrast to the average surface, which is a mixture of low-albedo materials and magnesium phyllosilicates, ammoniated phyllosilicates and carbonates. Here we report high spatial and spectral resolution near-infrared observations of the bright areas in the Occator crater on Ceres. Spectra of these bright areas are consistent with a large amount of sodium carbonate, constituting the most concentrated known extraterrestrial occurrence of carbonate on kilometre-wide scales in the Solar System. The carbonates are mixed with a dark component and small amounts of phyllosilicates, as well as ammonium carbonate or ammonium chloride. Some of these compounds have also been detected in the plume of Saturn’s sixth-largest moon Enceladus. The compounds are endogenous and we propose that they are the solid residue of crystallization of brines and entrained altered solids that reached the surface from below. The heat source may have been transient (triggered by impact heating). Alternatively, internal temperatures may be above the eutectic temperature of subsurface brines, in which case fluids may exist at depth on Ceres today.

Distribution of phyllosilicates on the surface of Ceres

INTRODUCTION The surface of the dwarf planet Ceres is known to host phyllosilicate minerals, but their distribution and origin have not previously been determined. Phyllosilicates are hydrated silicates, and their presence on the surface of Ceres is intriguing given that their structure evolves through an aqueous alteration process. In addition, some phyllosilicates are known to bear NH4, which places a constraint on the pH and redox conditions during the evolution of Ceres. We studied the distribution of phyllosilicates across the planet’s surface to better understand the evolutionary pathway of Ceres. RATIONALE Using the data acquired by the mapping spectrometer (VIR) onboard the Dawn spacecraft, we mapped the spatial distribution of different minerals on Ceres on the basis of their diagnostic absorption features in visible and infrared spectra. We studied the phyllosilicates through their OH-stretch fundamental absorption at about 2.7 µm and through the NH4 absorption at about 3.1 µm. From our composition maps, we infer the origin of the materials identified. RESULTS We found that Mg- and NH4-bearing phyllosilicates are ubiquitous across the surface of Ceres and that their chemical composition is fairly uniform. The widespread presence of these two types of minerals is a strong indication of a global and extensive aqueous alteration—i.e., the presence of water at some point in Ceres’ geological history. Although the detected phyllosilicates are compositionally homogeneous, we found variations in the intensity of their absorption features in the 3-µm region of the reflectance spectrum. Such variations are likely due to spatial variability in relative mineral abundance (see the figure). CONCLUSION The large-scale regional variations evident in the figure suggest lateral heterogeneity in surficial phyllosilicate abundance on scales of several hundreds of kilometers. Terrains associated with the Kerwan crater (higher concentration of phyllosilicates) appear smooth, whereas the Yalode crater (lower concentration of phyllosilicates) is characterized by both smooth and rugged terrains. These distinct morphologies and phyllosilicate concentrations observed in two craters that are similar in size may reflect different compositions and/or rheological properties. On top of this large-scale lateral heterogeneity, small-scale variations associated with individual craters could result from different proportions of mixed materials in a stratified upper crustal layer that has been exposed by impacts. Variations associated with fresh craters, such as the 34-km-diameter Haulani, indicate the presence of crustal variations over a vertical scale of a few kilometers, whereas much larger craters, such as the 126-km-diameter Dantu, suggest that such stratification may extend for at least several tens of kilometers. Abundance maps. Qualitative maps of the abundances of (top) phyllosilicates and (bottom) NH4, based on the depth of their absorption features. The two maps have a similar global pattern, although they differ in some localized regions such as Urvara. The scale bar is valid at the equator. The dwarf planet Ceres is known to host phyllosilicate minerals at its surface, but their distribution and origin have not previously been determined. We used the spectrometer onboard the Dawn spacecraft to map their spatial distribution on the basis of diagnostic absorption features in the visible and near-infrared spectral range (0.25 to 5.0 micrometers). We found that magnesium- and ammonium-bearing minerals are ubiquitous across the surface. Variations in the strength of the absorption features are spatially correlated and indicate considerable variability in the relative abundance of the phyllosilicates, although their composition is fairly uniform. These data, along with the distinctive spectral properties of Ceres relative to other asteroids and carbonaceous meteorites, indicate that the phyllosilicates were formed endogenously by a globally widespread and extensive alteration process.

The Surface Composition and Temperature of Asteroid 21 Lutetia As Observed by Rosetta/VIRTIS

A spacecraft flyby of an asteroid reveals a high-density body that is more like a planetesimal than a rubble pile. The Visible, InfraRed, and Thermal Imaging Spectrometer (VIRTIS) on Rosetta obtained hyperspectral images, spectral reflectance maps, and temperature maps of the asteroid 21 Lutetia. No absorption features, of either silicates or hydrated minerals, have been detected across the observed area in the spectral range from 0.4 to 3.5 micrometers. The surface temperature reaches a maximum value of 245 kelvin and correlates well with topographic features. The thermal inertia is in the range from 20 to 30 joules meter−2 kelvin−1 second−0.5, comparable to a lunarlike powdery regolith. Spectral signatures of surface alteration, resulting from space weathering, seem to be missing. Lutetia is likely a remnant of the primordial planetesimal population, unaltered by differentiation processes and composed of chondritic materials of enstatitic or carbonaceous origin, dominated by iron-poor minerals that have not suffered aqueous alteration.

Pitted Terrain on Vesta and Implications for the Presence of Volatiles

Vesta to the Core Vesta is one of the largest bodies in the main asteroid belt. Unlike most other asteroids, which are fragments of once larger bodies, Vesta is thought to have survived as a protoplanet since its formation at the beginning of the solar system (see the Perspective by Binzel, published online 20 September). Based on data obtained with the Gamma Ray and Neutron Detector aboard the Dawn spacecraft, Prettyman et al. (p. 242, published online 20 September) show that Vestas reputed volatile-poor regolith contains substantial amounts of hydrogen delivered by carbonaceous chondrite impactors. Observations of pitted terrain on Vesta obtained by Dawns Framing Camera and analyzed by Denevi et al. (p. 246, published online 20 September), provide evidence for degassing of volatiles and hence the presence of hydrated materials. Finally, paleomagnetic studies by Fu et al. (p. 238) on a meteorite originating from Vesta suggest that magnetic fields existed on the surface of the asteroid 3.7 billion years ago, supporting the past existence of a magnetic core dynamo. Analysis of data from the Dawn spacecraft implies that asteroid Vesta is rich in volatiles. We investigated the origin of unusual pitted terrain on asteroid Vesta, revealed in images from the Dawn spacecraft. Pitted terrain is characterized by irregular rimless depressions found in and around several impact craters, with a distinct morphology not observed on other airless bodies. Similar terrain is associated with numerous martian craters, where pits are thought to form through degassing of volatile-bearing material heated by the impact. Pitted terrain on Vesta may have formed in a similar manner, which indicates that portions of the surface contain a relatively large volatile component. Exogenic materials, such as water-rich carbonaceous chondrites, may be the source of volatiles, suggesting that impactor materials are preserved locally in relatively high abundance on Vesta and that impactor composition has played an important role in shaping the asteroid’s geology.

The diurnal cycle of water ice on comet 67P/Churyumov–Gerasimenko

Observations of cometary nuclei have revealed a very limited amount of surface water ice, which is insufficient to explain the observed water outgassing. This was clearly demonstrated on comet 9P/Tempel 1, where the dust jets (driven by volatiles) were only partially correlated with the exposed ice regions. The observations of 67P/Churyumov–Gerasimenko have revealed that activity has a diurnal variation in intensity arising from changing insolation conditions. It was previously concluded that water vapour was generated in ice-rich subsurface layers with a transport mechanism linked to solar illumination, but that has not hitherto been observed. Periodic condensations of water vapour very close to, or on, the surface were suggested to explain short-lived outbursts seen near sunrise on comet 9P/Tempel 1. Here we report observations of water ice on the surface of comet 67P/Churyumov–Gerasimenko, appearing and disappearing in a cyclic pattern that follows local illumination conditions, providing a source of localized activity. This water cycle appears to be an important process in the evolution of the comet, leading to cyclical modification of the relative abundance of water ice on its surface.

Olivine in an unexpected location on Vesta’s surface

Olivine is a major component of the mantle of differentiated bodies, including Earth. Howardite, eucrite and diogenite (HED) meteorites represent regolith, basaltic-crust, lower-crust and possibly ultramafic-mantle samples of asteroid Vesta, which is the lone surviving, large, differentiated, basaltic rocky protoplanet in the Solar System. Only a few of these meteorites, the orthopyroxene-rich diogenites, contain olivine, typically with a concentration of less than 25 per cent by volume. Olivine was tentatively identified on Vesta, on the basis of spectral and colour data, but other observations did not confirm its presence. Here we report that olivine is indeed present locally on Vesta’s surface but that, unexpectedly, it has not been found within the deep, south-pole basins, which are thought to be excavated mantle rocks. Instead, it occurs as near-surface materials in the northern hemisphere. Unlike the meteorites, the olivine-rich (more than 50 per cent by volume) material is not associated with diogenite but seems to be mixed with howardite, the most common surface material. Olivine is exposed in crater walls and in ejecta scattered diffusely over a broad area. The size of the olivine exposures and the absence of associated diogenite favour a mantle source, but the exposures are located far from the deep impact basins. The amount and distribution of observed olivine-rich material suggest a complex evolutionary history for Vesta.