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Dive into the research topics where Magnus Borgström is active.

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Featured researches published by Magnus Borgström.


Inorganic Chemistry Communications | 2003

Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer

Henriette Wolpher; Magnus Borgström; Leif Hammarström; Jonas Bergquist; Villy Sundström; Stenbjörn Styring; Licheng Sun; Björn Åkermark

This thesis describes the synthesis and properties of ruthenium complexes relevant to artificial photosynthesis. The work includes preparation of RuIIpolypyridine complexes as well as multi component systems where RuII(bpy)3 or RuII(tpy)2 type complexes are used as photosesnsitizers.In the first part, the synthesis and characterisation of bipyridyl(pyridyl)methane type ligands and the corresponding ruthenium(II) bistridentate polypyridyl complexes is described. The bipyridyl-pyridyl methane type ligands were designed to increase the excited state lifetime of ruthenium(II) bisterpyridine-type complexes by altering the ligand field as compared to normal terpyridine ligands.In the second part photoinduced electron transfer and formation of charge separated states in donor-photosensitizer dyads or donor-photosensitizer-acceptor triads is studied. The first covalently linked donor-photosensitizer-acceptor triad with tyrosine as electron donor was prepared, and long lived light induced charge separation was observed. RuIIterpyridine complexes linked to carotenoid or tyrosine were also prepared, for studies of light induced charge separation on a TiO2 surface. Tryptofan was covalently linked to Ru(bpy)3 and proton coupled electron transfer from tryptophan to photogenerated ruthenium(III) was demonstrated. A pH-dependent study of the electron transfer rate gave insight into the mechanism of proton coupled electron transfer in amino acids.Finally, the last part of the thesis presents the preparation and properties of the first complex containing a photosensitizer covalently linked to a Fe-hydrogenase active site model.


New Journal of Chemistry | 2005

Distance-independent photoinduced energy transfer over 1.1 to 2.3 nm in ruthenium trisbipyridine–fullerene assemblies

Frédérique Chaignon; Javier Torroba; Errol Blart; Magnus Borgström; Leif Hammarström; Fabrice Odobel

Ruthenium trisbipyridine C60 dyads linked viapara-phenyleneethynylene units have been prepared. They displayed a rapid energy transfer from Ru to C60 with a rate that was independent of distance, from 1.1 to 2.3 nm. The results are explained by a hopping mechanism involving a bridge-localized excited-state. In fact, for the longest bridge this state was lower in energy than the Ru-based MLCT state, as evidenced by the spectroscopic data.


Chemical Communications | 2004

Intramolecular charge separation in a hydrogen bonded tyrosine–ruthenium(II)–naphthalene diimide triad

Olof Johansson; Henriette Wolpher; Magnus Borgström; Leif Hammarström; Jonas Bergquist; Licheng Sun; Björn Åkermark

Long-lived charge-separated states in the ns to [micro sign]s range were observed upon laser flash excitation of a donor-chromophore-acceptor triad based on tris(bipyridine) ruthenium(ii) as photo-sensitizer, naphthalene diimide as acceptor, and a hydrogen bonded phenol as donor.


Inorganic Chemistry | 2004

Model of the Iron Hydrogenase Active Site Covalently Linked to a Ruthenium Photosensitizer: Synthesis and Photophysical Properties

Sascha Ott; Magnus Borgström; Mikael Kritikos; Reiner Lomoth; Jonas Bergquist; Björn Åkermark; Leif Hammarström; Licheng Sun


Inorganic Chemistry | 2003

Electron donor-acceptor dyads based on ruthenium(II) bipyridine and terpyridine complexes bound to naphthalenediimide

Olof Johansson; Magnus Borgström; Reiner Lomoth; Magnus Palmblad; Jonas Bergquist; Leif Hammarström; Licheng Sun; Björn Åkermark


Inorganic Chemistry | 2003

Electron Donor-Acceptor Dyads and Triads Based on Tris(bipyridine)ruthenium(II) and Benzoquinone : Synthesis, Characterization, and Photoinduced Electron Transfer Reactions

Magnus Borgström; Olof Johansson; Reiner Lomoth; Helena Berglund Baudin; Staffan Wallin; Licheng Sun; Björn Åkermark; Leif Hammarström


Chemistry: A European Journal | 2005

Synthesis and Characterization of Dinuclear Ruthenium Complexes Covalently Linked to RuII Tris‐bipyridine: An Approach to Mimics of the Donor Side of Photosystem II

Yunhua Xu; Gerriet Eilers; Magnus Borgström; Jingxi Pan; Maria Abrahamsson; Ann Magnuson; Reiner Lomoth; Jonas Bergquist; Tomáš Polívka; Licheng Sun; Villy Sundström; Stenbjörn Styring; Leif Hammarström; Björn Åkermark


Dalton Transactions | 2006

Rapid energy transfer in bichromophoric tris-bipyridyl/cyclometallated ruthenium(II) complexes.

Sascha Ott; Magnus Borgström; Leif Hammarström; Olof Johansson


Catalysis Today | 2004

Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes

Henriette Wolpher; Ping Huang; Magnus Borgström; Jonas Bergquist; Stenbjörn Styring; Licheng Sun; Björn Åkermark


Nanoimprint and Nanoprint Technology Conference, Barcelona, Spain, 21-23 October, 2013 | 2013

Nanoimprint Lithography and Gold Electroplating for Nanowire Seed Particle Definition

Reza Jafari Jam; Magnus Heurlin; Anders Kvennefors; Mariusz Graczyk; Vishal Jain; Magnus Borgström; Håkan Pettersson; Lars Samuelson; Ivan Maximov

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