Mark A. Fanton
Pennsylvania State University
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Featured researches published by Mark A. Fanton.
Nano Letters | 2009
Joshua A. Robinson; Maxwell Wetherington; Joseph L. Tedesco; P. M. Campbell; Xiaojun Weng; Joseph Stitt; Mark A. Fanton; Eric Frantz; David W. Snyder; Brenda L. VanMil; Glenn G. Jernigan; Rachael L. Myers-Ward; Charles R. Eddy; D. Kurt Gaskill
We report a direct correlation between carrier mobility and Raman topography of epitaxial graphene (EG) grown on silicon carbide (SiC). We show the Hall mobility of material on SiC(0001) is highly dependent on thickness and monolayer strain uniformity. Additionally, we achieve high mobility epitaxial graphene (18100 cm(2)/(V s) at room temperature) on SiC(0001) and show that carrier mobility depends strongly on the graphene layer stacking.
ACS Nano | 2010
Joshua A. Robinson; Xiaojun Weng; Kathleen A. Trumbull; Randall Cavalero; Maxwell Wetherington; Eric Frantz; Michael LaBella; Zachary Hughes; Mark A. Fanton; David W. Snyder
A promising route for the synthesis of large-area graphene, suitable for standard device fabrication techniques, is the sublimation of silicon from silicon carbide at elevated temperatures (>1200 degrees C). Previous reports suggest that graphene nucleates along the (110n) plane, known as terrace step edges, on the silicon carbide surface. However, to date, a fundamental understanding of the nucleation of graphene on silicon carbide is lacking. We provide the first direct evidence that nucleation of epitaxial graphene on silicon carbide occurs along the (110n) plane and show that the nucleated graphene quality improves as the synthesis temperature is increased. Additionally, we find that graphene on the (110n) plane can be significantly thicker than its (0001) counterpart and appears not to have a thickness limit. Finally, we find that graphene along the (110n) plane can contain a high density of structural defects, often the result of the underlying substrate, which will undoubtedly degrade the electronic properties of the material. Addressing the presence of non-uniform graphene that may contain structural defects at terrace step edges will be key to the development of a large-scale graphene technology derived from silicon carbide.
ACS Nano | 2011
Mark A. Fanton; Joshua A. Robinson; Conor Puls; Ying Liu; Matthew J. Hollander; B.E. Weiland; Michael LaBella; Kathleen A. Trumbull; Richard Kasarda; Casey Howsare; Joseph Stitt; David W. Snyder
We present a novel method for the direct metal-free growth of graphene on sapphire that yields high quality films comparable to that of graphene grown on SiC by sublimation. Graphene is synthesized on sapphire via the simple decomposition of methane at 1425-1600 °C. Film quality was found to be a strong function of growth temperature. The thickness, structure, interface characteristics, and electrical transport properties were characterized in order to understand the utility of this material for electronic devices. Graphene synthesized on sapphire is found to be strain relieved, with no evidence of an interfacial buffer layer. There is a strong correlation between the graphene structural quality and carrier mobility. Room temperature Hall effect mobility values were as high as 3000 cm(2)/(V s), while measurements at 2 K reached values of 10,500 cm(2)/(V s). These films also display evidence of the quantum Hall effect. Field effect transistors fabricated from this material had a typical current density of 200 mA/mm and transconductance of 40 mS/mm indicating that material performance may be comparable to graphene on SiC.
Nano Letters | 2009
Joshua A. Robinson; Conor Puls; Neal Staley; Joseph Stitt; Mark A. Fanton; Konstantin V. Emtsev; Thomas Seyller; Ying Liu
We report results of Raman spectroscopy studies of large-area epitaxial graphene grown on SiC. Our work reveals unexpectedly large variation in Raman shift resulting from graphene strain inhomogeneity, which is shown to be correlated with physical topography by coupling Raman spectroscopy with atomic force microscopy. We show that graphene strain can vary over a distance shorter than 300 nm and may be uniform only over roughly 1 microm. We show that nearly strain-free graphene is possible even in epitaxial graphene.
ACS Nano | 2010
Joshua A. Robinson; Michael LaBella; Kathleen A. Trumbull; Xiaojun Weng; Randall Cavelero; Tad Daniels; Zachary Hughes; Mathew Hollander; Mark A. Fanton; David W. Snyder
We present the integration of epitaxial graphene with thin film dielectric materials for the purpose of graphene transistor development. The impact on epitaxial graphene structural and electronic properties following deposition of Al(2)O(3), HfO(2), TiO(2), and Ta(2)O(5) varies based on the choice of dielectric and deposition parameters. Each dielectric film requires the use of a nucleation layer to ensure uniform, continuous coverage on the graphene surface. Graphene quality degrades most severely following deposition of Ta(2)O(5), while the deposition if TiO(2) appears to improve the graphene carrier mobility. Finally, we discuss the potential of dielectric stack engineering for improved transistor performance.
IEEE Electron Device Letters | 2010
J. S. Moon; D. Curtis; S. Bui; T Marshall; D. Wheeler; I Valles; S. Kim; E Wang; Xiaojun Weng; Mark A. Fanton
In this letter, we report the first experimental demonstration of wafer-scale ambipolar field-effect transistor (FET) on Si (111) substrates by synthesizing a graphene layer on top of 3C-SiC(111)/Si(111) substrates. With lateral scaling of the source-drain distance to 1 μm in a top-gated layout, the ON-state current of 225 μA/μm and peak transconductance of > 40 μS/μm were obtained at Vds = 2 V, which is the highest performance of graphene-on-Si FETs. The peak field-effect mobilities of 285 cm2 /Vs for holes and 175 cm2 /Vs for electrons were demonstrated, which is higher than that of ultra-thin-body SOI (n, p) MOSFETs.
arXiv: Materials Science | 2009
D. K. Gaskill; Glenn G. Jernigan; P. M. Campbell; Joseph L. Tedesco; James C. Culbertson; Brenda L. VanMil; R. L. Myers-Ward; Charles R. Eddy; Jeong Moon; D. Curtis; M Hu; D. Wong; C McGuire; Joshua A. Robinson; Mark A. Fanton; T. Stitt; David W. Snyder; X. Wang; Eric Frantz
An in vacuo thermal desorption process has been accomplished to form epitaxial graphene (EG) on 4H- and 6H-SiC substrates using a commercial chemical vapor deposition reactor. Correlation of growth conditions and the morphology and electrical properties of EG are described. Raman spectra of EG on Si-face samples were dominated by monolayer thickness. This approach was used to grow EG on 50 mm SiC wafers that were subsequently fabricated into field effect transistors with fmax of 14 GHz.
Journal of Applied Physics | 2005
Hun Jae Chung; A. Y. Polyakov; Sung Wook Huh; Saurav Nigam; M. Skowronski; Mark A. Fanton; B.E. Weiland; David W. Snyder
High-purity 6H-SiC single crystals were grown by the halide chemical-vapor deposition process. Growth was performed in a vertical hot-wall reactor with a separate injection of a silicon precursor (silicon tetrachloride) and a carbon precursor (propane). Typical growth rates were between 100 and 300μm∕h. The crystals contain very low concentrations of residual impurities. The main contaminants, namely, nitrogen and boron, are in the 1014atomscm−3 range. Crystals grown under Si-rich conditions were n type with low room temperature electron concentrations in the 1014–1015atomscm3 range and with room-temperature electron mobilities approaching 400cm2∕Vs. The resistivity of the material increased up to 1010Ωcm with increasing C∕Si ratio. Deep levels spectra show that the electron traps density decreases with increasing C∕Si ratio.
Journal of Applied Physics | 2009
Ian C. Manning; Xiaojun Weng; Jeremy D. Acord; Mark A. Fanton; David W. Snyder; Joan M. Redwing
The effects of Si doping on the evolution of stress in AlxGa1−xN:Si thin films (x≈0.4–0.6) grown on 6H-SiC by metal organic chemical vapor deposition were investigated using in situ wafer curvature measurements. The results were correlated with changes in film microstructure as observed by transmission electron microscopy. The incorporation of Si into the films resulted in a compressive-to-tensile transition in the biaxial stress at the surface, and the magnitude of the tensile stress was found to increase in proportion to the Si concentration. The stress gradient was attributed to Si-induced dislocation inclination resulting from an effective climb mechanism. Si doping also resulted in a decrease in the threading dislocation density in the AlxGa1−xN layers, which was attributed to increased dislocation interaction and annihilation. The model describing tensile stress generated by dislocation effective climb was modified to account for the dislocation reduction and was found to yield an improved fit to th...
Applied Physics Letters | 2010
Xiaojun Weng; Joshua A. Robinson; Kathleen A. Trumbull; Randall Cavalero; Mark A. Fanton; David W. Snyder
Using directly interpretable atomic-resolution cross-sectional scanning transmission electron microscopy, we have investigated the structure of few-layer epitaxial graphene (EG) on 6H-SiC(0001). We show that the buried interface layer possesses a lower average areal density of carbon atoms than graphene, indicating that it is not a graphenelike sheet with the 63×63R30° structure. The EG interlayer spacings are found to be considerably larger than that of the bulk graphite and the surface of the SiC(0001) substrate, often treated as relaxed, is found to be strained. Discontinuity of the graphene layers above the SiC surface steps is observed, in contradiction with the commonly believed continuous coverage.