Meng Zhou
Yale University
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Featured researches published by Meng Zhou.
Journal of the American Chemical Society | 2010
Meng Zhou; Nathan D. Schley; Robert H. Crabtree
A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation gave (18)O incorporation into the product cis-decalol.
Chemical Society Reviews | 2011
Meng Zhou; Robert H. Crabtree
While C-H oxidation by ruthenium oxo compounds has been broadly applied in organic synthesis, examples of C-H oxidation by metal oxo complexes from the rest of the platinum group are still rare. We survey the preparation and reactivity of these late-transition metal oxo and peroxo complexes in this tutorial review.
Journal of the American Chemical Society | 2017
Yang Gao; Changjian Guan; Meng Zhou; Akshai Kumar; Thomas J. Emge; Ashley M. Wright; Karen I. Goldberg; Karsten Krogh-Jespersen; Alan S. Goldman
NaBArF4 (sodium tetrakis[(3,5-trifluoromethyl)phenyl]borate) was found to catalyze reactions of (Phebox)IrIII(acetate) (Phebox = 2,6-bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl) complexes, including (i) β-H elimination of (Phebox)Ir(OAc)(n-alkyl) to give (Phebox)Ir(OAc)(H) and the microscopic reverse, alkene insertion into the Ir-H bond of (Phebox)Ir(OAc)(H), and (ii) hydrogenolysis of the Ir-alkyl bond of (Phebox)Ir(OAc)(n-alkyl) and the microscopic reverse, C-H activation by (Phebox)Ir(OAc)(H), as indicated by H/D exchange experiments. For example, β-H elimination of (Phebox)Ir(OAc)(n-octyl) (2-Oc) proceeded on a time scale of minutes at -15 °C in the presence of (0.4 mM) NaBArF4 as compared with a very slow reaction at 125 °C in the absence of NaBArF4. In addition to NaBArF4, other Lewis acids are also effective. Density functional theory calculations capture the effect of the Na+ cation and indicate that it operates primarily by promoting κ2-κ1 dechelation of the acetate anion, which opens the coordination site needed to allow the observed reaction to proceed. In accord with the effect on these individual stoichiometric reactions, NaBArF4 was also found to cocatalyze, with (Phebox)Ir(OAc)(H), the acceptorless dehydrogenation of n-dodecane.
Molecules | 2015
Meng Zhou; Alan S. Goldman
Pincer (Phebox)Ir(mesityl)(OAc) (2) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)) complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene) using (Phebox)Ir(OAc)2OH2 (1), was treated with thionyl chloride to rapidly form 1-(chloromethyl)-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash column chromatography to form (Phebox)IrCl2OH2 in 87% yield.
ACS Catalysis | 2012
Meng Zhou; David Balcells; Alexander R. Parent; Robert H. Crabtree; Odile Eisenstein
Organometallics | 2013
Meng Zhou; Ulrich Hintermair; Brian G. Hashiguchi; Alexander R. Parent; Sara M. Hashmi; Menachem Elimelech; Roy A. Periana; Gary W. Brudvig; Robert H. Crabtree
Organometallics | 2015
Meng Zhou; Samantha I. Johnson; Yang Gao; Thomas J. Emge; Robert J. Nielsen; William A. Goddard; Alan S. Goldman
Archive | 2015
Samantha I. Johnson; Robert J. Nielsen; Meng Zhou; Alan S. Goldman; William A. Goddard
Archive | 2014
Meng Zhou; Samantha I. Johnson; Robert Nielson; William A. Goddard; Alan S. Goldman
Archive | 2014
Meng Zhou; Alan S. Goldman; Robert Nielson; Samantha I. Johnson; William A. Goddard