Nicola Trivellin

A combined electro-optical method for the determination of the recombination parameters in InGaN-based light-emitting diodes

We present an electro-optical method for the extrapolation of the nonradiative and Auger recombination coefficients in InGaN/GaN Light-emitting diodes (LEDs). The method has the advantage of permitting the extrapolation of the recombination parameters of packaged devices, contrary to conventional techniques based on the analysis of quasibulk structures. For the analyzed devices, the average values of the nonradiative and Auger recombination coefficients have been determined to be equal to 2.3×107 s−1 and 1.0×10−30 cm6 s−1, respectively. These results are consistent with previous reports based on the analysis of quasibulk structures and on theoretical simulations. The method described in this paper constitutes an efficient tool for the analysis of the recombination dynamics in GaN-based LEDs. The results obtained within this work support the hypothesis on the importance of Auger recombination in determining the so-called efficiency droop in LED structures.

Investigation of the deep level involved in InGaN laser degradation by deep level transient spectroscopy

This paper reports an extensive analysis of the properties of the deep level responsible for the degradation of InGaN-based laser diodes. The analysis is based on combined optical measurements and Deep-Level Transient Spectroscopy (DLTS) investigation. Results indicate that stress induces a significant increase in threshold current of the devices, which is strongly correlated to the increase in the concentration of a deep level (DL) detected by DLTS. The DL involved in the degradation process is located 0.35–0.45 eV below the conduction band. 2D simulation indicates that degradation occurs within the quantum-well region.

Leakage current and reverse-bias luminescence in InGaN-based light-emitting diodes

This paper reports an electro-optical analysis of the correlation between reverse-bias leakage current and luminescence in light-emitting diodes based on InGaN. The results of the analysis suggest that (i) the main mechanism responsible for leakage current conduction is tunneling, (ii) leakage current is correlated with the presence of reverse-bias luminescence, (iii) leakage current flows through preferential paths, that can be identified by means of emission microscopy, and (iv) reverse-bias luminescence could be ascribed to the recombination of electron-hole pairs in the quantum well region.

Chip and package-related degradation of high power white LEDs

With this paper we present an analysis of the degradation of state-of-the-art high power LEDs. Three different kinds of commercially available samples, from leading manufacturers, were submitted to stress under various current and temperature levels. Based on an accurate estimation of the thermal resistance of the devices, iso-thermal and iso-current stress tests have been carried out, with the aim of separately evaluating the role of current and temperature in determining the degradation of the LEDs. Results indicate that state-of-the-art LEDs can show a significant degradation of their electrical and optical characteristics, when they are operated close to their current/temperature limits. In particular, data reveal the presence of two different degradation mechanisms: (i) the degradation of the blue semiconductor chip, due to the increase in non-radiative recombination, or to the decrease in the acceptor dopant concentration at the p-side of the diodes; (ii) the chemical degradation of the package, with subsequent worsening of its optical properties. Results suggest that even high-performance LEDs can suffer from limited lifetime: thermal management and driving conditions must be carefully optimized with the aim of achieving high reliability for LEDs to be adopted in high efficiency lighting systems.

Degradation of InGaN-based laser diodes analyzed by means of electrical and optical measurements

In this paper we present a detailed analysis of the degradation of InGaN-based laser diodes carried out by means of electrical and optical techniques. The study is based on the comparison between the degradation kinetics of laser diodes and light-emitting diode (LED)-like samples, i.e., devices with the same epitaxial structure as the lasers, but with no ridge and facets. Results described in the following indicate that degradation of lasers and LED-like samples is due to the same mechanism, possibly involving the generation of point defects within the active region of the devices. Furthermore, since degradation occurs both in lasers and in LED-like samples (i.e., structures with no current confinement), results suggest that degradation of lasers is not correlated with the geometry of the devices, nor to worsening of current confinement under the ridge.

Extensive Analysis of the Degradation of Blu-Ray Laser Diodes

This letter describes an analysis of the degradation of InGaN-based laser diodes. The influence of current, temperature, and optical power level on the degradation kinetics has been analyzed by means of a wide set of stress tests carried out under different operating conditions. We demonstrate the following: 1.) the degradation rate is strongly related to the operating current level; 2.) high-temperature stress does not determine significant degradation of lasers characteristics; and 3.) the intensity of the optical field does not significantly influence the degradation rate. Degradation process is found to be electrothermally activated and is ascribed to the increase of the nonradiative recombination rate in the active layer, with subsequent decrease of the efficiency of the devices.

Thermally Activated Degradation of Remote Phosphors for Application in LED Lighting

This paper reports on an extensive analysis of the degradation of remote phosphors for solid-state lighting applications. The study is based on combined optical and thermal measurements, carried out before and during long-term stress tests, and provides the following results: 1) During normal operation, phosphors can show significant self-heating; 2) as a consequence of self-heating, the conversion efficiency of the phosphors decreases; and 3) exposure to long-term stress tests at moderate/high temperature levels (in the range of 85 °C-145 °C) can lead to remarkable degradation of the phosphors. Degradation mainly consists in a decrease in conversion efficiency and in worsening of the chromatic properties of the light-emitting diode-phosphor system. Finally, an activation energy value of 1.2 eV was extrapolated for the thermally activated degradation of the phosphors.

Analysis of Defect-Related Localized Emission Processes in InGaN/GaN-Based LEDs

This paper reports an extensive analysis of the defect-related localized emission processes occurring in InGaN/GaN-based light-emitting diodes (LEDs) at low reverse- and forward-bias conditions. The analysis is based on combined electrical characterization and spectrally and spatially resolved electroluminescence (EL) measurements. Results of this analysis show that: (i) under reverse bias, LEDs can emit a weak luminescence signal, which is directly proportional to the injected reverse current. Reverse-bias emission is localized in submicrometer-size spots; the intensity of the signal is strongly correlated to the threading dislocation (TD) density, since TDs are preferential paths for leakage current conduction. (ii) Under low forward-bias conditions, the intensity of the EL signal is not uniform over the device area. Spectrally resolved EL analysis of green LEDs identifies the presence of localized spots emitting at 600 nm (i.e., in the yellow spectral region), whose origin is ascribed to localized tunneling occurring between the quantum wells and the barrier layers of the diodes, with subsequent defect-assisted radiative recombination. The role of defects in determining yellow luminescence is confirmed by the high activation energy of the thermal quenching of yellow emission (Ea = 0.64 eV).

Degradation Mechanisms of High-Power LEDs for Lighting Applications: An Overview

This paper reports on the degradation mechanisms that limit the reliability of high-power light-emitting diodes (LEDs) for lighting applications. The study is based on the experimental characterization of state-of-the-art LEDs fabricated by leading manufacturers. We demonstrate that, despite high potential reliability, high-power LEDs may suffer from a number of degradation mechanisms that affect the stability of the blue semiconductor LED chip and of the phosphor layer used for the generation of white light. More specifically, we describe the following relevant mechanisms: 1) the optical degradation of LEDs, due to an increase in the nonradiative recombination rate, which can be correlated to modifications in the forward-bias current-voltage characteristics; 2) the variation in forward voltage, due to the increase in series resistance; 3) the optical degradation of phosphor layers used for blue-to-white light conversion; and 4) the failure of LEDs submitted to “hot plugging,” which is the direct connection of an LED chain to an energized power supply, due to the generation of high current spikes. Results provide an overview on the failure mechanisms that limit the reliability of state-of-the-art LEDs and on the role of current and temperature in determining the failure of the devices.

Analysis of Diffusion-Related Gradual Degradation of InGaN-Based Laser Diodes

This report reveals that diffusion of hydrogen induces gradual degradation in InGaN-based laser diodes (LDs). The increase in nonradiative recombination centers (NRCs) in the LDs has been attributed to diffusion-related phenomena. Factors other than NRCs, such as the threshold carrier density Nth, can increase threshold current Ith. Those factors, however, were not fully investigated. Moreover, the diffusant responsible for the degradation of the LDs has not been univocally identified yet. To separately evaluate the roles of NRCs and Nth in increasing Ith, this report analyzes the stress-induced variation of nonradiative recombination lifetime τnr and lasing wavelength λl. It is revealed that the density of NRCs increases at the first stage of gradual degradation, followed by a rise in Nth. In addition, this report proposes a novel model for the time-variation of 1/τnr to investigate the diffusion-related degradation. By using this model, we extrapolate the value of the diffusion coefficient of diffusants involved in the degradation in InGaN-based LDs. The proposed analysis methods and obtained results are useful for understanding the physics of LD degradation.