Nicolas Le Thomas

Refractive index sensing with an air-slot photonic crystal nanocavity

We investigate an air-slot photonic crystal cavity for high-precision refractive index sensing. The high quality factor approximately 2.6x10(4) of the cavity, along with a strong overlap between the resonant mode and the hollow core region, allows us to achieve an experimental sensitivity of 510nm per refractive index unit (RUI) and a detection limit below 1x10(-5)RUI. The device has a remarkably low sensing volume of 40aliters, holding less than 1x10(6)molecules.

Off-chip beam steering with a one-dimensional optical phased array on silicon-on-insulator

Optical phased arrays are versatile components enabling rapid and precise beam steering. An integrated approach is followed in which a 1D optical phased array is fabricated on silicon-on-insulator. The optical phased array consists of 16 parallel grating couplers spaced 2 mum apart. Steering in one direction is done thermo-optically by means of a titanium electrode on top of the structure using the phased array principle, while steering in the other direction is accomplished by wavelength tuning. At a wavelength of 1550 nm, continuous thermo-optical steering of 2.3 degrees and wavelength steering of 14.1 degrees is reported.

Evanescent excitation and collection of spontaneous Raman spectra using silicon nitride nanophotonic waveguides.

We experimentally demonstrate the use of high contrast, CMOS-compatible integrated photonic waveguides for Raman spectroscopy. We also derive the dependence of collected Raman power with the waveguide parameters and experimentally verify the derived relations. Isopropyl alcohol (IPA) is evanescently excited and detected using single-mode silicon-nitride strip waveguides. We analyze the measured signal strength of pure IPA corresponding to an 819  cm⁻¹ Raman peak due to in-phase C-C-O stretch vibration for several waveguide lengths and deduce a pump power to Raman signal conversion efficiency on the waveguide to be at least 10⁻¹¹  per cm.

Silicon and silicon nitride photonic circuits for spectroscopic sensing on-a-chip [Invited]

There is a rapidly growing demand to use silicon and silicon nitride (Si3N4) integrated photonics for sensing applications, ranging from refractive index to spectroscopic sensing. By making use of advanced CMOS technology, complex miniaturized circuits can be easily realized on a large scale and at a low cost covering visible to mid-IR wavelengths. In this paper we present our recent work on the development of silicon and Si3N4-based photonic integrated circuits for various spectroscopic sensing applications. We report our findings on waveguide-based absorption, and Raman and surface enhanced Raman spectroscopy. Finally we report on-chip spectrometers and on-chip broadband light sources covering very near-IR to mid-IR wavelengths to realize fully integrated spectroscopic systems on a chip.

Optical tuning of planar photonic crystals infiltrated with organic molecules

The optical tuning of InP-based planar photonic crystals (PhCs) infiltrated with a photoresponsive liquid crystal system is presented. Photoinduced phase transitions of a liquid crystal blend doped with azobenzene molecules are used to tune the optical response of PhC cavities. This process is found to be reversible and stable. Several tuning conditions are analyzed in terms of the blend phase diagram.

Polytypic InP Nanolaser Monolithically Integrated on (001) Silicon

On-chip optical interconnects still miss a high-performance laser monolithically integrated on silicon. Here, we demonstrate a silicon-integrated InP nanolaser that operates at room temperature with a low threshold of 1.69 pJ and a large spontaneous emission factor of 0.04. An epitaxial scheme to grow relatively thick InP nanowires on (001) silicon is developed. The zincblende/wurtzite crystal phase polytypism and the formed type II heterostructures are found to promote lasing over a wide wavelength range.

Experimental observation of slow mode dispersion in photonic crystal coupled-cavity waveguides.

We experimentally investigate the dispersion curve of an integrated silicon-on-insulator coupled-cavity waveguide in a photonic crystal environment using a technique based on far-field imaging. We show that a chain of eight coupled cavities of a moderate Q factor can form a continuous dispersion band characterized by extremely flat dispersion and a group index of 105+/-20 within a 2.6 nm wavelength range. The experimental results are well reproduced by theoretical calculations based on the guided-mode expansion method.

Surface Enhanced Raman Spectroscopy Using a Single Mode Nanophotonic-Plasmonic Platform

We demonstrate the generation of Surface Enhanced Raman Spectroscopy (SERS) signals from integrated bowtie antennas, excited and collected by the fundamental TE mode of a single mode silicon nitride waveguide. Due to the integrated nature of this particular single mode SERS probe one can rigorously quantify the complete enhancement process. The Stokes power, generated by a 4-nitrothiophenol-coated antenna and collected into the fundamental TE mode, exhibits an 8 × 106 enhancement compared to the free space Raman scattering of a 4-nitrothiophenol molecule. Furthermore, we present an analytical model which identifies the relevant design parameters and figure of merit for this new SERS-platform. An excellent correspondence is obtained between the theoretically predicted and experimentally observed absolute Raman power. This work paves the way toward a new class of fully integrated lab-on-a-chip systems where the single mode SERS probe can be combined with other photonic, fluidic, or biological functionalities.

Bright and dark plasmon resonances of nanoplasmonic antennas evanescently coupled with a silicon nitride waveguide

In this work we investigate numerically and experimentally the resonance wavelength tuning of different nanoplasmonic antennas excited through the evanescent field of a single mode silicon nitride waveguide and study their interaction with this excitation field. Experimental interaction efficiencies up to 19% are reported and it is shown that the waveguide geometry can be tuned in order to optimize this interaction. Apart from the excitation of bright plasmon modes, an efficient coupling between the evanescent field and a dark plasmonic resonance is experimentally demonstrated and theoretically explained as a result of the propagation induced phase delay.

Bioinspired bright noniridescent photonic melanin supraballs

A one-pot emulsion process produces noniridescent supraball inks made of core-shell melanin and silica nanoparticles. Structural colors enable the creation of a spectrum of nonfading colors without pigments, potentially replacing toxic metal oxides and conjugated organic pigments. However, significant challenges remain to achieve the contrast needed for a complete gamut of colors and a scalable process for industrial application. We demonstrate a feasible solution for producing structural colors inspired by bird feathers. We have designed core-shell nanoparticles using high–refractive index (RI) (~1.74) melanin cores and low-RI (~1.45) silica shells. The design of these nanoparticles was guided by finite-difference time-domain simulations. These nanoparticles were self-assembled using a one-pot reverse emulsion process, which resulted in bright and noniridescent supraballs. With the combination of only two ingredients, synthetic melanin and silica, we can generate a full spectrum of colors. These supraballs could be directly added to paints, plastics, and coatings and also used as ultraviolet-resistant inks or cosmetics.