Paul J. Lamothe

Aeolian Dust in Colorado Plateau Soils: Nutrient Inputs and Recent Change in Source

Aeolian dust (windblown silt and clay) is an important component in arid-land ecosystems because it may contribute to soil formation and furnish essential nutrients. Few geologic surfaces, however, have been characterized with respect to dust-accumulation history and resultant nutrient enrichment. We have developed a combination of methods to identify the presence of aeolian dust in arid regions and to evaluate the roles of this dust in ecosystem processes. Unconsolidated sandy sediment on isolated surfaces in the Canyonlands region of the Colorado Plateau differs greatly in mineralogical and chemical composition from associated bedrock, mainly aeolian sandstone. Detrital magnetite in the surficial deposits produces moderately high values of magnetic susceptibility, but magnetite is absent in nearby bedrock. A component of the surficial deposits must be aeolian to account for the abundance of magnetite, which formed originally in far-distant igneous rocks. Particle-size analysis suggests that the aeolian dust component is typically as much as 20–30%. Dust inputs have enriched the sediments in many elements, including P, Mg, Na, K, and Mo, as well as Ca, at sites where bedrock lacks calcite cement. Soil-surface biologic crusts are effective dust traps that apparently record a change in dust sources over the past several decades. Some of the recently fallen dust may result from human disturbance of land surfaces that are far from the Canyonlands, such as the Mojave Desert. Some land-use practices in the study area have the potential to deplete soil fertility by means of wind-erosion removal of aeolian silt.

MULTI-DECADAL IMPACTS OF GRAZING ON SOIL PHYSICAL AND BIOGEOCHEMICAL PROPERTIES IN SOUTHEAST UTAH

Many soils in southeastern Utah are protected from surface disturbance by biological soil crusts that stabilize soils and reduce erosion by wind and water. When these crusts are disturbed by land use, soils become susceptible to erosion. In this study, we compare a never-grazed grassland in Canyonlands National Park with two historically grazed sites with similar geologic, geomorphic, and geochemical characteristics that were grazed from the late 1800s until 1974. We show that, despite almost 30 years without livestock grazing, surface soils in the historically grazed sites have 38–43% less silt, as well as 14– 51% less total elemental soil Mg, Na, P, and Mn content relative to soils never exposed to livestock disturbances. Using magnetic measurement of soil magnetite content (a proxy for the stabilization of far-traveled eolian dust) we suggest that the differences in Mg, Na, P, and Mn are related to wind erosion of soil fine particles after the historical disturbance by livestock grazing. Historical grazing may also lead to changes in soil organic matter content including declines of 60–70% in surface soil C and N relative to the never-grazed sites. Collectively, the differences in soil C and N content and the evidence for substantial rock-derived nutrient loss to wind erosion implies that livestock grazing could have long-lasting effects on the soil fertility of native grasslands in this part of southeastern Utah. This study suggests that nutrient loss due to wind erosion of soils should be a consideration for management decisions related to the long-term sustainability of grazing operations in arid environments.

Metal emissions from Kilauea, and a suggested revision of the estimated worldwide metal output by quiescent degassing of volcanoes

Abstract Measurements of a large suite of metals (Pb, Cd, Cu, Zn and several others) and sulfur at Kilauea volcano over an extended period of time has yielded a detailed record of the atmospheric injection of ordinarily-rare metals from this quiescently degassing volcano, representative of an important type. We have combined the Kilauea data with data of recent studies by others (emissions from volcanoes in the Indonesian arc; the large Laki eruption of two centuries ago; Etna; estimates of total volcanic emissions of sulfur) to form the basis for a new working estimate of the rate of worldwide injection of metals to the atmosphere by volcanoes. The new estimate is that volcanoes inject a substantially smaller mass of ordinarily-rare metals into the atmosphere than was stated in a widely cited previous estimate [J.O. Nriagu, A global assessment of natural sources of atmospheric trace metals, Nature 338 (1989) 47–49]. Our estimate, which is an upper limit, is an annual injection mass of about 10,000 tons of the metals considered, versus the earlier estimate of about 23,000 tons. Also, the proportions of the metals are substantially different in our new estimate.

Geochemistry of metal-rich brines from central Mississippi Salt Dome basin, U.S.A.

Abstract Oil-field brines are the most favored ore-forming solutions for the sediment-hosted Mississippi Valley-type ore deposits. Detailed inorganic and organic chemical and isotope analyses of water and gas samples from six oil fields in central Mississippi, one of the very few areas with high metal brines, were conducted to study the inorganic and organic complexes responsible for the high concentrations of these metals. The samples were obtained from production zones consisting of sandstone and limestone that range in depth from 1900 to 4000 m (70–120°C) and in age from Late Cretaceous to Late Jurassic. Results show that the waters are dominantly bittern brines related to the Louann Salt. The brines have extremely high salinities that range from 160,000 to 320,000 mg/l total dissolved solids and are Na Ca Cl-type waters with very high concentrations of Ca (up to 48,000 mg/l) and other alkaline-earth metals, but with low concentrations of aliphatic acid anions. The concentrations of metals in many water samples are very high, reaching values of 70 mg/l for Pb, 245 mg/l for Zn, 465 mg/l for Fe and 210 mg/l for Mn. The samples with high metal contents have extremely low concentrations ( 2 S. Samples obtained from the Smackover Formation (limestone) have low metal contents that are more typical of oil-field waters, but have very high concentrations (up to 85 mg/l) of H 2 S. Computations with the geochemical code SOLMINEQ.87 give the following results: (1) both Pb and Zn are present predominantly as aqueous chloride complexes (mainly as PbCl 4 2− and ZnCl 4 2− , respectively); (2) the concentrations of metals complexed with short-chained aliphatic acid anions and reduced S species are minor; (3) organic acid anions are important in controlling the concentrations of metals because they affect the pH and buffer capacity of the waters at subsurface conditions; and (4) galena and sphalerite solubilities control the concentrations of Pb and Zn in these waters.

Geochemical evidence for diversity of dust sources in the southwestern United States

Several potential dust sources, including generic sources of sparsely vegetated alluvium, playa deposits, and anthropogenic emissions, as well as the area around Owens Lake, California, affect the composition of modern dust in the southwestern United States. A comparison of geochemical analyses of modern and old (a few thousand years) dust with samples of potential local sources suggests that dusts reflect four primary sources: (1) alluvial sediments (represented by Hf, K, Rb, Zr, and rare-earth elements, (2) playas, most of which produce calcareous dust (Sr, associated with Ca), (3) the area of Owens (dry) Lake, a human-induced playa (As, Ba, Li, Pb, Sb, and Sr), and (4) anthropogenic and/or volcanic emissions (As, Cr, Ni, and Sb). A comparison of dust and source samples with previous analyses shows that Owens (dry) Lake and mining wastes from the adjacent Cerro Gordo mining district are the primary sources of As, Ba, Li, and Pb in dusts from Owens Valley. Decreases in dust contents of As, Ba, and Sb with distance from Owens Valley suggest that dust from southern Owens Valley is being transported at least 400 km to the east. Samples of old dust that accumulated before European settlement are distinctly lower in As, Ba, and Sb abundances relative to modern dust, likely due to modern transport of dust from Owens Valley. Thus, southern Owens Valley appears to be an important, geochemically distinct, point source for regional dust in the southwestern United States.

Controls of Bedrock Geochemistry on Soil and Plant Nutrients in Southeastern Utah

The cold deserts of the Colorado Plateau contain numerous geologically and geochemically distinct sedimentary bedrock types. In the area near Canyonlands National Park in Southeastern Utah, geochemical variation in geologic substrates is related to the depositional environment with higher concentrations of Fe, Al, P, K, and Mg in sediments deposited in alluvial or marine environments and lower concentrations in bedrock derived from eolian sand dunes. Availability of soil nutrients to vegetation is also controlled by the formation of secondary minerals, particularly for P and Ca availability, which, in some geologic settings, appears closely related to variation of CaCO3 and Ca-phosphates in soils. However, the results of this study also indicate that P content is related to bedrock and soil Fe and Al content suggesting that the deposition history of the bedrock and the presence of P-bearing Fe and Al minerals, is important to contemporary P cycling in this region. The relation between bedrock type and exchangeable Mg and K is less clear-cut, despite large variation in bedrock concentrations of these elements. We examined soil nutrient concentrations and foliar nutrient concentration of grasses, shrubs, conifers, and forbs in four geochemically distinct field sites. All four of the functional plant groups had similar proportional responses to variation in soil nutrient availability despite large absolute differences in foliar nutrient concentrations and stoichiometry across species. Foliar P concentration (normalized to N) in particular showed relatively small variation across different geochemical settings despite large variation in soil P availability in these study sites. The limited foliar variation in bedrock-derived nutrients suggests that the dominant plant species in this dryland setting have a remarkably strong capacity to maintain foliar chemistry ratios despite large underlying differences in soil nutrient availability.

Critical tissue residue approach linking accumulated metals in aquatic insects to population and community-level effects.

Whole body Zn concentrations in individuals (n = 825) from three aquatic insect taxa (mayflies Rhithrogena spp. and Drunella spp. and the caddisfly Arctopsyche grandis) were used to predict effects on populations and communities (n = 149 samples). Both mayflies accumulated significantly more Zn than the caddisfly. The presence/absence of Drunella spp. most reliably distinguished sites with low and high Zn concentrations; however, population densities of mayflies were more sensitive to increases in accumulated Zn. Critical tissue residues (634 μg/g Zn for Drunella spp. and 267 μg/g Zn for Rhithrogena spp.) caused a 20% reduction in maximum (90th quantile) mayfly densities. These critical tissue residues were associated with exposure to 7.0 and 3.9 μg/L dissolved Zn for Drunella spp. and Rhithrogena spp., respectively. A threshold in a measure of taxonomic completeness (observed/expected) was observed at 5.4 μg/L dissolved Zn. Dissolved Zn concentrations associated with critical tissue residues in mayflies were also associated with adverse effects in the aquatic community as a whole. These effects on populations and communities occurred at Zn concentrations below the U.S. EPA hardness-adjusted continuous chronic criterion.

Determination of rare-earth elements, yttrium and scandium in manganese nodules by inductively-coupled argon-plastma emission spectrometry

Abstract A sequential-scanning, inductively-coupled argon plasma emission spectrometer is used for the determination of the rare-earth elements, plus yttrium and scandium, in manganese nodules. Wavelength selection is optimized to minimize spectral interferences from manganese nodule components. Samples are decomposed with mixed acids in a sealed polycarbonate vessel, and elements are quantified without further treatment. Results for U.S. Geological Survey manganese nodule standards A-1 and P-1 had average relative standard deviations of 6.8% and 8.1%, respectively, and results were in good agreement with those obtained by other methods.

Biogeochemical plant-soil interaction: variable element composition in leaves of four plant species collected along a south-north transect at the southern tip of Norway.

Leaves from four different plant species (birch, willow, juniper, and heather) together with samples of the soil O and C horizons were collected at 44-46 sites along a south-to-north transect extending inland for 200 km from the southern tip of Norway. The transect covers one of the steepest vegetation gradients on Earth, crossing six vegetation zones. Juniper and heather are evergreen, and preferably exclude potentially toxic elements to avoid their accumulation in assimilating tissues, birch and willow shed their leaves in autumn together with the load of potentially toxic elements, and thus can tolerate the uptake of such elements. The plant leaves show the highest concentrations for B, Ca, K, Mg, Mn, P, Rb and S. In the soil O-horizon Ag, Au, As, Bi, Cu, Ge, Hg, In, Pb, Sb, Se, Sn, Te and W are enriched with respect to the C-horizon, whilst Mn and Rb are depleted. Cadmium, Sr and Zn are enriched in willow and Cs, Na and Tl in heather. In terms of concentration gradients from the coast inland, two different patterns are detected: 1) short range with an almost exponential decrease of concentrations from the coast, which appears to be typical for seaspray-related element input, and 2) long range with an almost linear decrease of concentrations with distance from the coast. These patterns differ among the four species, even for one and the same element. Inter-element correlation is different from material to material. Along the transect each of the different plants at the same site individually adapts to the available element combination. High linear correlations in the plants occur between the lanthanides (La, Ce, Y), and interestingly, between P and Ti. The plant/soil system appears highly non-linear and self-regulated.

Determination of ammonium in a buddingtonite sample by ion-chromatography

An ion-chromatographic method for the direct determination of ammonium, potassium, and sodium in geologic materials is described. Samples are decomposed with a mixture of hydrofluoric and hydrochloric acids in a sealed polycarbonate bottle heated in a microwave oven. The ion-chromatograph separates the cations and determines them by conductivity measurement. The ammonium concentrations thus determined have been verified by use of an ammonia-specific electrode. A total of 32 analyses of ammonium salts by both techniques showed an average error of -4%, with a relative standard deviation (RSD) of 6%. The ammonium concentrations found in a buddingtonite sample had an RSD of 2.2% and their mean agreed with that obtained by the Kjeldahl method. By use of the prescribed dilution of the sample, detection limits of 0.1% can be achieved for all three cations.