Richard L. Reynolds

Aeolian Dust in Colorado Plateau Soils: Nutrient Inputs and Recent Change in Source

Aeolian dust (windblown silt and clay) is an important component in arid-land ecosystems because it may contribute to soil formation and furnish essential nutrients. Few geologic surfaces, however, have been characterized with respect to dust-accumulation history and resultant nutrient enrichment. We have developed a combination of methods to identify the presence of aeolian dust in arid regions and to evaluate the roles of this dust in ecosystem processes. Unconsolidated sandy sediment on isolated surfaces in the Canyonlands region of the Colorado Plateau differs greatly in mineralogical and chemical composition from associated bedrock, mainly aeolian sandstone. Detrital magnetite in the surficial deposits produces moderately high values of magnetic susceptibility, but magnetite is absent in nearby bedrock. A component of the surficial deposits must be aeolian to account for the abundance of magnetite, which formed originally in far-distant igneous rocks. Particle-size analysis suggests that the aeolian dust component is typically as much as 20–30%. Dust inputs have enriched the sediments in many elements, including P, Mg, Na, K, and Mo, as well as Ca, at sites where bedrock lacks calcite cement. Soil-surface biologic crusts are effective dust traps that apparently record a change in dust sources over the past several decades. Some of the recently fallen dust may result from human disturbance of land surfaces that are far from the Canyonlands, such as the Mojave Desert. Some land-use practices in the study area have the potential to deplete soil fertility by means of wind-erosion removal of aeolian silt.

MULTI-DECADAL IMPACTS OF GRAZING ON SOIL PHYSICAL AND BIOGEOCHEMICAL PROPERTIES IN SOUTHEAST UTAH

Many soils in southeastern Utah are protected from surface disturbance by biological soil crusts that stabilize soils and reduce erosion by wind and water. When these crusts are disturbed by land use, soils become susceptible to erosion. In this study, we compare a never-grazed grassland in Canyonlands National Park with two historically grazed sites with similar geologic, geomorphic, and geochemical characteristics that were grazed from the late 1800s until 1974. We show that, despite almost 30 years without livestock grazing, surface soils in the historically grazed sites have 38–43% less silt, as well as 14– 51% less total elemental soil Mg, Na, P, and Mn content relative to soils never exposed to livestock disturbances. Using magnetic measurement of soil magnetite content (a proxy for the stabilization of far-traveled eolian dust) we suggest that the differences in Mg, Na, P, and Mn are related to wind erosion of soil fine particles after the historical disturbance by livestock grazing. Historical grazing may also lead to changes in soil organic matter content including declines of 60–70% in surface soil C and N relative to the never-grazed sites. Collectively, the differences in soil C and N content and the evidence for substantial rock-derived nutrient loss to wind erosion implies that livestock grazing could have long-lasting effects on the soil fertility of native grasslands in this part of southeastern Utah. This study suggests that nutrient loss due to wind erosion of soils should be a consideration for management decisions related to the long-term sustainability of grazing operations in arid environments.

The ecology of dust

Wind erosion and associated dust emissions play a fundamental role in many ecological processes and provide important biogeochemical connectivity at scales ranging from individual plants up to the entire globe. Yet, most ecological studies do not explicitly consider dust-driven processes, perhaps because most relevant research on aeolian (wind-driven) processes has been presented in a geosciences rather than an ecological context. To bridge this disciplinary gap, we provide a general overview of the ecological importance of dust, examine complex interactions between wind erosion and ecosystem dynamics from the scale of plants and surrounding space to regional and global scales, and highlight specific examples of how disturbance affects these interactions and their consequences. It is likely that changes in climate and intensification of land use will lead to increased dust production from many drylands. To address these issues, environmental scientists, land managers, and policy makers need to consider wind erosion and dust emissions more explicitly in resource management decisions.

Environmental magnetic implications of Greigite (Fe3S4) Formation in a 3 m.y. lake sediment record from Butte Valley, northern California

Authigenic greigite (Fe 3 S 4 ) has been identified in several horizons of lake beds in a 102-m core from Butte Valley, northern California, using mineral magnetic methods and x-ray diffraction analysis. The presence of greigite has several implications for the paleoenvironmental record from Butte Valley. First, its occurrence in 2.5-3.0 Ma strata confirms that greigite can persist in the geological record for long periods of time. Second, the detrital mineral magnetic record may be partially obscured by the presence of authigenic greigite and care must be taken in interpreting magnetic variations in the greigite-bearing zones as paleoclimate proxies. Third, differences in the timing of remanence acquisition for authigenic and detrital phases may compromise studies of high-frequency geomagnetic field variations. Fourth, greigite may also be significant as a paleoenvironmental indicator of lake and sediment chemistry. The magnetic detection of greigite may therefore provide important information about paleolimnological conditions.

Eolian sand transport pathways in the southwestern United States: importance of the Colorado River and local sources

Geomorphologists have long recognized that eolian sand transport pathways extend over long distances in desert regions. Along such pathways, sediment transport by wind can surmount topographic obstacles and cross major drainages. Recent studies have suggested that three distinct eolian sand transport pathways exist (or once existed) in the Mojave and Sonoran Desert regions of the southwestern United States. One hypothesized pathway is eolian sand transport from the eastern Mojave Desert of California into western Arizona, near Parker, and would require sand movement across what must have been at least a seasonally dry Colorado River valley. We tested this hypothesis by mineralogical, geochemical and magnetic analyses of eolian sands on both sides of the Colorado River, as well as sediment from the river itself. Results indicate that dunes on opposite sides of the Colorado River are mineralogically distinct: eastern California dunes are feldspar-rich whereas western Arizona dunes are quartz-rich, derived from quartz-rich Colorado River sediments. Because of historic vegetation changes, little new sediment from the Colorado River is presently available to supply the Parker dunes. Based on this study and previous work, the Colorado River is now known to be the source of sand for at least three of the major dune fields of the Sonoran Desert of western Arizona and northern Mexico. On the other hand, locally derived alluvium appears to be a more important source of dune fields in the Mojave Desert of California. Although many geomorphologists have stressed the importance of large fluvial systems in the origin of desert dune fields, few empirical data actually exist to support this theory. The results presented here demonstrate that a major river system in the southwestern United States is a barrier to the migration of some dune fields, but essential to the origin of others. Published by Elsevier Science Ltd.

The analysis of forms of sulfur in ancient sediments and sedimentary rocks: comments and cautions

Assumptions commonly made during analysis of the amount of monosulfides [acid-volatile sulfides (AVS)] and disulfides in modern sediments, may not be valid for ancient sedimentary rocks. It is known that ferric iron can oxidize H2S during AVS analysis unless a reducing agent such as stannous chloride is added to the treatment. In addition, some monosulfides such as greigite and pyrrhotite require heat during the AVS analysis in order to dissolve completely. However, the use of heat and/or stannous chloride in the AVS treatment may partially dissolve disulfides and it is generally recommended that stannous chloride not be used in the AVS treatment for modern sediments. Most of the monosulfides are assumed to be recovered as AVS without the addition of stannous chloride. This study investigates the recovery of monosulfides during sulfur speciation analysis with application to ancient sedimentary rocks. Sulfur in samples containing naturally occurring greigite and mackinawite or pyrite was measured using variations of a common sulfur-speciation scheme. The sulfur-speciation scheme analyzes for monosulfide sulfur, disulfide sulfur, elemental sulfur, inorganic sulfate and organically bound sulfur. The effects of heat, stannous chloride and ferric iron on the amounts of acid-volatile sulfide and disulfide recovered during treatment for AVS were investigated. Isotopic compositions of the recovered sulfur species along with yields from an extended sulfur-speciation scheme were used to quantify the effects. Hot 6 N HCl AVS treatment recovers > 60% of the monosulfides as AVS in samples containing pure greigite and mackinawite. The remaining monosulfide sulfur is recovered in a subsequent elemental sulfur extraction. Hot 6 N HCl plus stannous chloride recovers 100% of the monosulfides as AVS. The addition of ferric iron to pure greigite and mackinawite samples during AVS treatment without stannous chloride decreased the amount of monosulfides recovered as AVS and, if present in great enough concentration, oxidized some of the AVS to a form not recovered in later treatments. The hot stannous chloride AVS treatments dissolve <5% of well-crystallized pyrite in this study. The amount of pyrite dissolved depends on grain size and crystallinity. Greigite in ancient sedimentary rocks was quantitatively recovered as AVS only with hot 6 N HCl plus stannous chloride. Hot 6 N HCl AVS treatment of these rocks did not detect any monosulfides in most samples. A subsequent elemental sulfur extraction did not completely recover the oxidized monosulfides. Therefore, the use of stannous chloride plus heat is recommended in the AVS treatment of ancient sedimentary rocks if monosulfides are present and of interest. All assumptions about the amount of monosulfides and disulfides recovered with the sulfur-speciation scheme used should be verified by extended sulfur-speciation and/or isotopic analysis of the species recovered.

The History of Recent Limnological Changes and Human Impact on Upper Klamath Lake, Oregon

Hypereutrophic Upper Klamath Lake has been studied for almost 50 years to evaluate the nature, cause, and effects of its very productive waters. Mitigation of undesirable effects of massive cyanobacterial blooms requires understanding their modern causes as well as their history. Knowledge of the pre-settlement natural limnology of this system can provide guidelines for lake restoration and management of land and water use strategies to maximize the benefits of this aquatic resource. This investigation uses a paleolimnological approach to document the nature and chronology of limnological and biological changes in Upper Klamath Lake for the past 200 years, covering the time when the lake was first described until today. A 45-cm gravity core, dated by 210Pb and diatom correlations, was analyzed for diatoms, pollen, akinetes (resting spores) of the cyanobacterium Aphanizomenon flos-aquae, reworked tephra shards, and sediment magnetic characteristics. Pollen profiles show little vegetation change during this time. In contrast, diatoms indicative of increased nutrient fluxes (P and Si) increase moderately, coinciding with the settlement of the region by Euro-Americans. Numerous settlement activities, including draining of lake-margin marshes, upstream agriculture and timber harvest, road construction, and boat traffic, may have affected the lake. Magnetic properties and reworked tephra suggest riparian changes throughout the basin and increased lithogenic sediment delivery to the lake, especially after 1920 when the marshes near the mouth of the Williamson River were drained and converted to agricultural and pasture land. Drainage and channelization also decreased the ability of the marshes to function as traps and filters for upstream water and sediments. Akinetes of Aphanizomenon flos-aquae record progressive eutrophication of Upper Klamath Lake beginning in the 20th century and particularly after 1920 when lake-margin marsh reclamation more than doubled. The coincidence of limnological changes and human activities following European settlement suggests a major impact on the Upper Klamath Lake ecosystem, although ascribing specific limnological changes to specific human activities is difficult.

Lake-Level History of Lake Michigan for the Past 12,000 Years: The Record From Deep Lacustrine Sediments

Abstract Collection and analysis of an extensive set of seismic-reflection profiles and cores from southern Lake Michigan have provided new data that document the history of the lake basin for the past 12,000 years. Analyses of the seismic data, together with radiocarbon dating, magnetic, sedimentologic, isotopic, and paleontologic studies of core samples, have allowed us to reconstruct lake-level changes during this recent part of the lakes history. The post-glacial history of lake-level changes in the Lake Michigan basin begins about 11.2 ka with the fall from the high Calumet level, caused by the retreat of the Two Rivers glacier, which had blocked the northern outlet of the lake. This lake-level fall was temporarily reversed by a major influx of water from glacial Lake Agassiz (about 10.6 ka), during which deposition of the distinctive gray Wilmette Bed of the Lake Michigan Formation interrupted deposition of red glaciolacustrine sediment. Lake level then continued to fall, culminating in the opening of the North Bay outlet at about 10.3 ka. During the resulting Chippewa low phase, lake level was about 80 m lower than it is today in the southern basin of Lake Michigan. The rise of the early Holocene lake level, controlled primarily by isostatic rebound of the North Bay outlet, resulted in a prominent, planar, transgressive unconformity that eroded most of the shoreline features below present lake level. Superimposed on this overall rise in lake level, a second influx of water from Lake Agassiz temporarily raised lake levels an unknown amount about 9.1 ka. At about 7 ka, lake level may have fallen below the level of the outlet because of sharply drier climate. Sometime between 6 and 5 ka, the character of the lake changed dramatically, probably due mostly to climatic causes, becoming highly undersaturated with respect to calcium carbonate and returning primary control of lake level to the isostatically rising North Bay outlet. Post-Nipissing (about 5 ka) lake level has fallen about 6 m due to erosion of the Port Huron outlet, a trend around which occurred relatively small (± ∼2 m), short-term fluctuations controlled mainly by climatic changes. These cyclic fluctuations are reflected in the sed-imentological and sediment-magnetic properties of the sediments.

Record of middle Pleistocene climate change from Buck Lake, Cascade Range, southern Oregon—Evidence from sediment magnetism, trace-element geochemistry, and pollen

Comparison of systematic variations in sediment magnetic properties to changes in pollen assemblages in middle Pleistocene lake sediments from Buck Lake indicates that the magnetic properties are sensitive to changes in climate. Buck Lake is located in southern Oregon just east of the crest of the Cascade Range. Lacustrine sediments, from 5.2 to 19.4 m in depth in core, contain tephra layers with ages of ≈300–400 ka at 9.5 m and ≈400–470 ka at 19.9 m. In these sediments magnetic properties reflect the absolute amount and relative abundances of detrital Fe-oxide minerals, titanomagnetite and hematite. The lacustrine section is divided into four zones on the basis of magnetic properties. Two zones (19.4–17.4 m and 14.5–10.3 m) of high magnetic susceptibility contain abundant Fe oxides and correspond closely to pollen zones that are indicative of cold, dry environments. Two low-susceptibility zones (17.4–14.5 m and 10.3–5.3 m) contain lesser amounts of Fe oxides and largely coincide with zones of warm-climate pollen. Transitions from cold to warm climate based on pollen are preceded by sharp changes in magnetic properties. This relation suggests that land-surface processes responded to these climate changes more rapidly than did changes in vegetation as indicated by pollen frequencies. Magnetic properties have been affected by three factors: (1) dissolution of Fe oxides, (2) variation in heavy-mineral content, and (3) variation in abundance of fresh volcanic rock fragments. Trace-element geochemistry, employing Fe and the immobile elements Ti and Zr, is utilized to detect postdepositional dissolution of magnetic minerals that has affected the magnitude of magnetic properties with little effect on the pattern of magnetic-property variation. Comparison of Ti and Zr values, proxies for heavy-mineral content, to magnetic properties demonstrates that part of the variation in the amount of magnetite and nearly all of the variation in the amount of hematite are due to changes in heavy-mineral content. Variation in the quantity of fresh volcanic rock fragments is the other source of change in magnetite content. Magnetic-property variations probably arise primarily from changes in peak runoff. At low to moderate flows magnetic properties reflect only the quantities of heavy minerals derived from soil and highly weathered rock in the catchment. At high flows, however, fresh volcanic rock fragments may be produced by breaking of pebbles and cobbles, and such fragments greatly increase the magnetite content of the resulting sediment. Climatically controlled factors that would affect peak runoff levels include the accumulation and subsequent melting of winter snow pack, the seasonality of precipitation, and the degree of vegetation cover of the land surface.Our results do not distinguish among the possible contributions of these disparate factors.

Magnetic records of climate change

Sediments deposited on the sea floor, on lake bottoms, as well as on land as accumulations of windblown silt (loess) and as ancient soils (paleosols) formed in the loess possess many different properties that record past changes in climate. Geologically recoverable information on paleoclimate includes changes in global temperature as it may affect global ice volume and thus temperature of sea water, net precipitation, storm intensity (wind speed) and frequency, as well as wind direction. Such information further contributes to interpretations about changes in oceanic and atmospheric circulation patterns. As such, the understanding of past climatic changes can provide baselines of natural climatic fluctuations as related to those that may be induced or influenced by human activities.