Puput Risdanareni

The Influence of Alkali Activator Concentration to Mechanical Properties of Geopolymer Concrete with Trass as a Filler

This paper describes one of the varying factors influencing the mechanical properties of geopolymer concrete. Fly ash and volcanic material called trass was used as raw materials, while sodium Hydroxide (NaOH) and Sodium silicate (Na2SiO3) was applied as an alkali activator. Mechanical properties were assessed by compressive test, the concentration of NaOH used in this study was eight and ten Molars, and ratio of Na2SiO3 to NaOH by mass was 0.5, 1, 1.5, 2, and 2.5. Test results indicated that the strength of geopolymer concrete and binder were hardly influenced by concentration of NaOH in solution and the activator ratio. Binder with activator ratio of 2.5 has the highest compressive strength both in 8M and 10M NaOH system. However, in concrete, there are a few difference, concretes made with 8M NaOH and activators ratio of 2 have the highest compressive strength. This result might due to the low workability of fresh geopolymer concrete. On the other hand, binder and concrete made with 10M NaOH, showed the highest compressive strength when they were made with the activator ratio of 2,5.

Properties of Y3Fe5O12 (YIG) as Nanocatalyst for Ammonia Formation Produced from Magnetic Induction Method (MIM)

Production of ammonia required high capital energy intensive such as high temperatures (400 to 500 °C) and high pressure (15 to 30 MPa). We investigated a new way to produce green ammonia synthesis using new nanocatalyst and operate in room temperature and ambient pressure. The idea is to synthesize ammonia using Magnetic Induction Method (MIM) and Y3Fe5O12 (YIG) as magnetic nanocatalyst. YIG was prepared by sol gel method and sintered at various temperatures 950 °C, 1050 °C, and 1150 °C. X-Ray Diffraction (XRD) result shows that the major peak at [420] plane. The balance composition of YIG resulted by Energy Dispersive X-Ray (EDX) is in the form of Y3Fe5O12. Initial permeability results show, the highest value maximum permeability at 140 with the range of frequency 1Hz to100MHz obtained by 950 °C sample. The lowest value of relative loss factor obtained by 950 °C sample. YIG nanocatalyst and MIM method were successfully produce ammonia yield at 197 μmol, without MIM the yield was decreased by 14.28%.

Effect of Alkaline Activator Ratio to Mechanical Properties of Geopolymer Concrete with Trass as Filler

This paper describes the effect of alkaline activator ratio (Na2SiO3/NaOH) to mechanical properties of geopolymer concrete. The mechanical properties of geopolymer concrete were assessed by setting time, split tensile strength and porosity. Fly ash was used as a cement substitute, and trass used as filler. While, Natrium hydroxide (NaOH) and Sodium Silicate (Na2SiO3) was applied as alkaline activator. In this study, NaOH concentration eight and ten molar with an alkaline activator ratio Na2SiO3/ NaOH by mass: 0.5, 1, 1.5, 2 and 2.5 were used. The test result showed that setting time, porosity and split tensile strength of geopolymer concrete were hardly influenced by NaOH concentration and the alkaline activator ratio. The alkaline activator ratio of Na2SiO3/NaOH has an optimum value at 2 and 2.5. Test result showed that the fastest setting time was 25 minute, the highest amount of closed porosity was 9.035 % and the highest split tensile strength was 2.86 MPa.

The effect of sintering temperature on the properties of metakaolin artificial lightweight aggregate

This paper describes the effect of sintering temperature on the properties of metakaolin artificial lightweight aggregate (ALWA). Three types of sintering temperature applied in this research are 900°C, 1000°C and 1100°C, whereas ALWA without sintering treatment is used as data control. Properties of metakaolin ALWA investigated in this research are specific gravity, water absorption, physical appearance, porosity and aggregate impact value. Standard test used in this research is ASTM, AFNOR and British Standart. Based on the research results, it can be concluded that sintering temperature is greatly affect on the properties of metakaolin ALWA. Increased sintering temperatures can lead to decreased values of specific gravity, increased pore amount, increased aggregate impact value, increased water absorption values and change aggregate color to be more bright. Referring to the test results, sintering temperature not exceeding 900°C is recommended, as it provides good physical and mechanical properties to ...

Morphology and phase identification of micron to nanosized manganese oxide (MnO) with variations in sintering time

Manganese oxide (MnO) occurs in many rock types and may take the form of minerals. MnO has its drawbacks, namely highly reactive oxidizing species classified as dangerous and explosive at temperatures above 55 °C. Despite this,MnO has excellent magnetic, electrochemical, and conductivity properties, which should be reduced to nano-size to maximize their use and improve the properties of MnO. Phase and morphology characterization of powder this research aims to reduce the grain size of the MnO from micro to nano using the sol-gel method with various sintering times. Sol-gel is a simple synthesis method that has been proven capable of synthesizing a wide variety of micro-sized oxide materials into nano. Sintering time is a technique performed in the synthesis process to dry the material to a temperature above the normal temperature. The temperature used for sintering starting from 600 °C to 1000 °C. Characterizations were done using XRD, SEM, EDX, and FTIR machines. The sintering processes in this study used a temperature of 600 °C with different sintering periods of 30, 60 and 90 minutes. The XRD characterization with a 30-minute sintering time resulted in the smallest MnO in the form crystalline powder of 47.3 nm. The highest intensity (degree of crystallinity) found in MnO sintered for 90 minutes. The results of the morphological characterization of SEM showed a morphological change in MnO from micro-sized triangular to nano-sized spherical shape. The EDX characterization results indicated that the 30-minute sintering caused the lowest change in Mn and the highest change in O. The results of FTIR characterization showed a shift in C-H and Mn-O followed by an increase in the group of N-H, C=O and Mn-O.Manganese oxide (MnO) occurs in many rock types and may take the form of minerals. MnO has its drawbacks, namely highly reactive oxidizing species classified as dangerous and explosive at temperatures above 55 °C. Despite this,MnO has excellent magnetic, electrochemical, and conductivity properties, which should be reduced to nano-size to maximize their use and improve the properties of MnO. Phase and morphology characterization of powder this research aims to reduce the grain size of the MnO from micro to nano using the sol-gel method with various sintering times. Sol-gel is a simple synthesis method that has been proven capable of synthesizing a wide variety of micro-sized oxide materials into nano. Sintering time is a technique performed in the synthesis process to dry the material to a temperature above the normal temperature. The temperature used for sintering starting from 600 °C to 1000 °C. Characterizations were done using XRD, SEM, EDX, and FTIR machines. The sintering processes in this study use...

Phase identification and morphology study of hematite (Fe2O3) with sintering time varitions

Iron oxide has been the interest of many studies due to its applications in various scientific and industrial fields including in environment, corrosion, soil science, and exhaust emissions. Iron oxide (Fe2O3) has potential applications in catalytic reactions in electronic devices such as semiconductors, paint formulations, and lithium rechargeable batteries. Fe2O3 can be synthesized through the process of stirring, decomposition of organic iron, sol-gel, combustion, and evaporating solvents. Most of the methods used involve several steps and take a long time. The aim of this research was to investigate the phase and morphology characterization of iron oxide (Fe2O3) powder with solvent ethylene glycol after being sintered for 1 hour, 2 hours and 3 hours. The characterization tools utilized were XRD, SEM-EDX, and FTIR. The results of XRD analysis showed that the Fe2O3 sintered for 1 hour had the smallest crystallite size with a diameter of 21.05 nm. In the XRD test, the beam of X-ray was shot directly at t...

Mechanical properties of geopolymer paste with fly ash variation

This paper presented mechanical properties of geopolymer paste with fly ash variation. Mechanical properties were assessed by compressive and setting time test. Fly ashes were obtained from three different places namely Paiton, PT Petro Kimia Gresik (PKG) and Fly Ash were sold in the local market of Malang. NaOH (Sodium Hydroxide) with concentration of 10 Molar and Na2SiO3 (Sodium Silicate) were used as alkali activators with ratio activator of 2. Percentage of fly ash and alkali used is 75% and 25%. Compressive strength test was conducted on binder with the age of 7,14,21,28 days, while setting time test was performed on fresh geopolymer paste. The results showed that fly ash obtained from the local market has the highest compressive strength with the value of 48.45MPa at 28 days. However, faster setting time will deliver higher compressive strength of geopolymer.