R. M. Macfarlane

A Three-Color, Solid-State, Three-Dimensional Display

A three-color, solid-state, volumetric display based on two-step, two-frequency upconversion in rare earth-doped heavy metal fluoride glass is described. The device uses infrared laser beams that intersect inside a transparent volume of active optical material to address red, green, and blue voxels by sequential two-step resonant absorption. Three-dimensional wire-frame images, surface areas, and solids are drawn by scanning the point of intersection of the lasers around inside of the material. The prototype device is driven with laser diodes, uses conventional focusing optics and mechanical scanners, and is bright enough to be seen in ambient room lighting conditions. QuickTime movie of the three-dimensional display.

Holographic data storage

We present an overview of our research effort on volume holographic digital data storage. Innovations, developments, and new insights gained in the design and operation of working storage platforms, novel optical components and techniques, data coding and signal processing algorithms, systems tradeoffs, materials testing and tradeoffs, and photon-gated storage materials are summarized.

Photon-gated hole burning: a new mechanism using two-step photoionization

We have observed photon-gated spectral hole burning, i.e., hole burning that occurs only in the presence of an additional gating-light source. Gating enhancement factors of 10(4) were observed. In BaClF:Sm(2+) this involves two step photoionization of Sm(2+) and leads to persistent holes in the (4)F(0) --> (5)D(0) (687.9-nm) and (7)F(0) --> (5)D(1) (629.7-nm) absorption lines. The hole widths of 25 MHz at 2 K are much narrower than the inhomogeneous broadening of 16 GHz. The action spectrum of the gating shows a threshold behavior around 2.5 eV. Erasing studies show that Sm(3)+ acts as a trap for the released electrons. A remarkable and novel feature is that the holes can be recovered after temperature cycling to 300 K.

Pixel-matched holographic data storage with megabit pages

Digital data-page holograms consisting of 1024 x 1024 arrays of binary pixels have been stored and subsequently retrieved with an optical exposure consistent with a data rate 1 Gbit /s. Each input pixel was precisely registered with a single detector pixel, and a raw bit-error rate as low as 2.4 x 10(-6) was demonstrated with global-threshold detection. To our knowledge, this is the first demonstration of the often-cited goal of holographic data storage of megabit data pages and a gigabit-per-second data rate.

Two-color holography in reduced near-stoichiometric lithium niobate

We explored a number of factors affecting the properties relevant to holographic optical data storage by using a two-color recording scheme in reduced, near-stoichiometric lithium niobate. Two-color, or photon-gated, recording is achieved by use of 852-nm information-carrying beams and 488-nm gating light. Readout at 852 nm is nondestructive, with a gating ratio of ~10(4). Recording sensitivity, gating ratio, dynamic range, and dark decay were measured for crystals of differing stoichiometry, degree of reduction, wavelength of the gating light, temperature, and optical power density. The two-color sensitivity per incident photon is still somewhat less than that of the one-color process at 488 nm for ~1 W/cm(2) of gating light but is essentially the same in terms of absorbed photons. Two-color recording is an attractive way of achieving nondestructive readout in a read-write material, and it allows selective optical erasure.

Reaching the magnetic anisotropy limit of a 3d metal atom

Maximizing atomic magnetic memory A study of the magnetic response of cobalt atoms adsorbed on oxide surfaces may lead to much denser storage of data. In hard drives, data are stored as magnetic bits; the magnetic field pointing up or down corresponds to storing a zero or a one. The smallest bit possible would be a single atom, but the magnetism of a single atom —its spin—has to be stabilized by interactions with heavy elements or surfaces through an effect called spin-orbit coupling. Rau et al. (see the Perspective by Khajetoorians and Wiebe) built a model system in pursuit of single-atom bits—cobalt atoms adsorbed on magnesium oxide. At temperatures approaching absolute zero, the stabilization of the spins magnetic direction reached the maximum that is theoretically possible. Science, this issue p. 988; see also p. 976 A cobalt atom bound to a single oxygen site on magnesia has the maximum magnetic anisotropy allowed for a transition metal [Also see Perspective by Khajetoorians and Wiebe] Designing systems with large magnetic anisotropy is critical to realize nanoscopic magnets. Thus far, the magnetic anisotropy energy per atom in single-molecule magnets and ferromagnetic films remains typically one to two orders of magnitude below the theoretical limit imposed by the atomic spin-orbit interaction. We realized the maximum magnetic anisotropy for a 3d transition metal atom by coordinating a single Co atom to the O site of an MgO(100) surface. Scanning tunneling spectroscopy reveals a record-high zero-field splitting of 58 millielectron volts as well as slow relaxation of the Co atom’s magnetization. This striking behavior originates from the dominating axial ligand field at the O adsorption site, which leads to out-of-plane uniaxial anisotropy while preserving the gas-phase orbital moment of Co, as observed with x-ray magnetic circular dichroism.

Excitation mechanisms for upconversion lasers

A number of nonlinear upconversion excitation mechanisms have been used to achieve lasing at wavelengths that are shorter than those of the pump light. We found that sequential two-step absorption was the principal process in YAlO 3 :Er 3+ and LaF 3 :Nd 3+ whereas energy transfer upconversion dominated in YLiF : Er 3+ . A nonlinear absorption process associated with cross relaxation resulted in upconversion lasing in YLiF 4 :Nd 3+

Frequency shift and dephasing of the S1 ← S0 transition of free-base porphin in an n-octane crystal as a function of temperature

Abstract We report a study of the temperature dependence of the homogeneous width and frequency of the S1 ← S0 0-0 transition of free-base porphin as a guest in an n-octane matrix. In the liquid helium temperature region, the measurements have been made by means of photochemical hole-burning, at higher temperatures up to 90 K via an analysis of the fluorescence spectrum. The results are interpreted in terms of the “exchange model” for optical dephasing.

Volume holographic data storage at an areal density of 250 gigapixels/in. 2

One thousand volume holographic data pages, each containing 1x10(6)pixels , are stored in a common volume of LiNbO(3) :Fe by use of the 90 degrees geometry. An effective transverse aperture of 1.6 mm x 1.6mm , realized by repetition of this experiment at each of the eight surrounding locations, results in a demonstrated areal density of 394pixels/mum (2) (254 Gpixels/in. (2)) . Short-focal-length Fourier optics provide a tightly confined object beam at the crystal; the reference beam is angle multiplexed. Data pages retrieved with a 1024 x 1024 CCD camera are processed to remap bad spatial light modulator pixels and to compensate for global and local pixel misregistration and are then decoded with a strong 8-bits-from-12-pixels modulation code. The worst-case raw bit-error rate (BER) before error correction was 1.1x10(-3) , sufficient to deliver a user BER of 10(-12) at an overall code rate of 0.61 user bits per detector pixel. This result corresponds to 1.08% of the well-known theoretical volumetric density limit of 1/lambda(3) .

High-resolution laser spectroscopy of rare-earth doped insulators: a personal perspective

I offer some reflections on the past three decades of high-resolution spectroscopy of rare-earth ions in solids which was ushered in by the development of tunable lasers in the mid 1970s. A brief review is given of some of the accomplishments in the area of spectral hole-burning and coherent transient spectroscopy, emphasizing work with which the author has been associated. Spectral hole-burning has been characterized by a richness of mechanisms. These include population storage in nuclear-spin and electron-spin Zeeman sub-levels, hyperfine and superhyperfine levels and metastable optical levels with corresponding hole lifetimes from many hours to microseconds. In addition, persistent hole-burning has been seen in disordered materials and in those showing photo-ionization or photo-chemistry following excitation into zero-phonon lines. This has made hole-burning a generally useful technique for the measurement of magnetic and electric dipole moments, hyperfine interactions, spin relaxation and thermally induced line-broadening. Photon-echoes have proven to be the prime source of coherence-time information and coherence times as long as several milliseconds corresponding to optical resonance widths of less than 100 Hz have been reported. Tables summarizing these results and providing references to original work are included.