Rassmidara Hoonsawat

Blue photoluminescent carbon nanodots from limeade.

Carbon-based photoluminescent nanodot has currently been one of the promising materials for various applications. The remaining challenges are the carbon sources and the simple synthetic processes that enhance the quantum yield, photostability and biocompatibility of the nanodots. In this work, the synthesis of blue photoluminescent carbon nanodots from limeade via a single-step hydrothermal carbonization process is presented. Lime carbon nanodot (L-CnD), whose the quantum yield exceeding 50% for the 490nm emission in gram-scale amounts, has the structure of graphene core functionalized with the oxygen functional groups. The micron-sized flake of the as-prepared L-CnD powder exhibits multicolor emission depending on an excitation wavelength. The L-CnDs are demonstrated for rapidly ferric-ion (Fe(3+)) detection in water compared to Fe(2+), Cu(2+), Co(2+), Zn(2+), Mn(2+) and Ni(2+) ions. The photoluminescence quenching of L-CnD solution under UV light is used to distinguish the Fe(3+) ions from others by naked eyes as low concentration as 100μM. Additionally, L-CnDs provide exceptional photostability and biocompatibility for imaging yeast cell morphology. Changes in morphology of living yeast cells, i.e. cell shape variation, and budding, can be observed in a minute-period until more than an hour without the photoluminescent intensity loss.

Biomagnetic of Apatite-Coated Cobalt Ferrite: A Core–Shell Particle for Protein Adsorption and pH-Controlled Release

Magnetic nanoparticle composite with a cobalt ferrite (CoFe2O4, (CF)) core and an apatite (Ap) coating was synthesized using a biomineralization process in which a modified simulated body fluid (1.5SBF) solution is the source of the calcium phosphate for the apatite formation. The core–shell structure formed after the citric acid–stabilized cobalt ferrite (CFCA) particles were incubated in the 1.5 SBF solution for 1 week. The mean particle size of CFCA-Ap is about 750 nm. A saturation magnetization of 15.56 emug-1 and a coercivity of 1808.5 Oe were observed for the CFCA-Ap obtained. Bovine serum albumin (BSA) was used as the model protein to study the adsorption and release of the proteins by the CFCA-Ap particles. The protein adsorption by the CFCA-Ap particles followed a more typical Freundlich than Langmuir adsorption isotherm. The BSA release as a function of time became less rapid as the CFCA-Ap particles were immersed in higher pH solution, thus indicating that the BSA release is dependent on the local pH.

Directional quantum transport in graphyne p-n junction

Graphyne, a newly proposed allotrope of carbon, has a structure which is topologically equivalent to that of a strongly distorted graphene [B. G. Kim and H. J. Choi, Phys. Rev. B 86, 115435 (2012)]. The energy gap between the valence and conduction bands is due to the symmetry breaking caused by there being three topologically inequivalent hoping elements. The valleyless fermionic transport properties of γ-graphyne are different from those of graphene since the two valleys are merged together in this carbon allotrope. The transmission and conductance of the electrons in γ-graphyne are found to be directionally dependent. Klein tunneling is predicted if the tunneling is in the y-direction. If the tunneling is in the x-direction, perfect back reflection (anti Klein tunneling) is predicted if the tunneling is at normal incidence. The consequences of these directional transport properties on the performances of p-n junctions fabricated with this carbon allotrope are studied. This work reveals the advantages o...

Josephson Effect in Graphene: Comparison of Real and Pseudo Vector Potential Barriers

The Josephson currents through real vector potential (RVP) and pseudo vector potential (PVP) barriers in graphene are investigated. In graphene, the pseudo vector potential may be caused by a local strain. The comparison of supercurrents induced by the two type-barriers is focused. As a result, we find that not only will the RVP induce a transition Josephson current from the 0 → π state but also causes the difference in the phases of the order parameters of the two superconducting graphene layers to shift from → . The critical current is PVP-independent around the neutrality point while it strongly depends on the RVP. The vector potential dependence of critical current is found to be perfectly linear for both PVP and RVP barriers.

Andreev reflection at a NS interface for non-normal angle of incidence

Abstract The Andreev reflection of electrons at a NS (normal-superconductor) interface is studied for the case where the angle of incidence is not normal. It is seen that the deviation of the Andreev reflection coefficient (for E > Δ) from ideal Andreev reflection. increases as the angle of incidence and that the deviation becomes greater as the mismatch at the interface is increased.

Effect of effective-mass differences on high-injection currents in normal-metal-superconductor point contacts

Abstract The connection rules appropriate to interfaces between metals having different effective masses are used to obtain the transmission coefficient for the high-injection current flow in the superconducting point contact model proposed recently by Hahn. It is found that the transmission coefficient obtained here is very similar to that obtained by Hahn except that the dependence of the coefficient on the properties of the two metals and of the oxide layer is clearly shown.