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Robert S. Wilhelm

University of California, Santa Barbara

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Publication

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Tetrahedron Letters | 1982

Chemistry of higher order, mixed organocuprates. reactions of α,β-unsaturated ketones.

Bruce H. Lipshutz; Robert S. Wilhelm; Joseph A. Kozlowski

Abstract Organocuprates of general formula R 2 Cu(CN)Li 2 react rapidly with α,β-unsaturated ketones at low temperatures and in high yields to deliver ligands in a conjugate manner. These reagents apparently do not require the use of additives for stabilizing or solubilizing purposes.

Tetrahedron | 1984

THE CHEMISTRY OF HIGHER ORDER ORGANOCUPRATES

Bruce H. Lipshutz; Robert S. Wilhelm; Joseph A. Kozlowski

Journal of the American Chemical Society | 1981

Chemistry of higher order, mixed organocuprates. 1. Substitution reactions at unactivated secondary centers

Bruce H. Lipshutz; Robert S. Wilhelm; David Mack Floyd

Journal of Organic Chemistry | 1984

Substitution reactions of secondary halides and epoxides with higher order, mixed organocuprates, R2Cu(CN)Li2: synthetic, stereochemical, and mechanistic aspects

Bruce H. Lipshutz; Robert S. Wilhelm; Joseph A. Kozlowski; David Parker

Journal of the American Chemical Society | 1982

Chemistry of higher order mixed organocuprates. 2. Reactions of epoxides

Bruce H. Lipshutz; Joseph A. Kozlowski; Robert S. Wilhelm

Journal of Organic Chemistry | 1984

Conjugate addition reactions of .alpha.,.beta.-unsaturated ketones with higher order, mixed organocuprate reagents, R2Cu(CN)Li2

Bruce H. Lipshutz; Robert S. Wilhelm; Joseph A. Kozlowski

Journal of Organic Chemistry | 1984

Chemical and spectroscopic observations on the properties and composition on higher order, mixed organocuprates, R2Cu(CN)Li2

Bruce H. Lipshutz; Joseph A. Kozlowski; Robert S. Wilhelm

Journal of the American Chemical Society | 1982

Chemistry of higher order, mixed organocuprates. 4. The stereochemical outcome of substitution reactions at unactivated secondary centers using organocopper reagents

Bruce H. Lipshutz; Robert S. Wilhelm

Journal of Organic Chemistry | 1983

Chemistry of higher order, mixed organocuprates. 5. On the choice of the copper(I) salt for the formation of R2CuLi

Bruce H. Lipshutz; Joseph A. Kozlowski; Robert S. Wilhelm

Journal of Organic Chemistry | 1984

Higher order, mixed organocuprates. 12. Chemical and spectroscopic observations on the properties and composition of higher order, mixed organocuprates, R2Cu(CN)Li2

Bruce H. Lipshutz; Joseph A. Kozlowski; Robert S. Wilhelm

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Bruce H. Lipshutz

University of California

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Joseph A. Kozlowski

University of California

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David Mack Floyd

Harvard University

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Manuel M. Baizer

Monsanto

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R. Daniel Little

University of California

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Sean T. Nugent

University of California

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David Parker

Durham University

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