Sang-Woo Ji

Pilot-scale passive bioreactors for the treatment of acid mine drainage: efficiency of mushroom compost vs. mixed substrates for metal removal.

Pilot-scale field-testing of passive bioreactors was performed to evaluate the efficiency of a mixture of four substrates (cow manure compost, mushroom compost, sawdust, and rice straw) relative to mushroom compost alone, and of the effect of the Fe/Mn ratio, during the treatment of acid mine drainage (AMD) over a 174-day period. Three 141 L columns, filled with either mushroom compost or the four substrate mixture (in duplicate), were set-up and fed with AMD from a closed mine site, in South Korea, using a 4-day hydraulic retention time. In the former bioreactor, effluent deterioration was observed over 1-2 months, despite the good efficiency predicted by the physicochemical characterization of mushroom compost. Steady state effluent quality was then noted for around 100 days before worsening in AMD source water occurred in response to seasonal variations in precipitation. Such changes in AMD quality resulted in performance deterioration in all reactors followed by a slow recovery toward the end of testing. Both substrates (mushroom compost and mixtures) gave satisfactory performance in neutralizing pH (6.1-7.8). Moreover, the system was able to consistently reduce sulfate from day 49, after the initial leaching out from organic substrates. Metal removal efficiencies were on the order of Al (∼100%) > Fe (68-92%) > Mn (49-61%). Overall, the mixed substrates showed comparable performance to mushroom compost, while yielding better effluent quality upon start-up. The results also indicated mushroom compost could release significant amounts of Mn and sulfate during bioreactor operation.

Comparative effectiveness of mixed organic substrates to mushroom compost for treatment of mine drainage in passive bioreactors

Bioreactors are one possible best sustainable technology to address the mine-impacted water problems. Several prospective substrates (mushroom compost, cow manure, sawdust, wood chips, and cut rice straw) were characterized for their ability to serve as a source of food and energy for sulfate-reducing bacteria. Twenty bench-scale batch bioreactors were then designed and set up to investigate relative effectiveness of various mixtures of substrates to that of mushroom compost, the most commonly used substrate in field bioreactors, for treating mine drainage with acidic (pH 3) and moderate pH (pH 6). Overall, reactive mixtures showed satisfactory performances in generating alkalinity, reducing sulfate and removing metals (Al>Fe>Mn) (up to 100%) at both pH conditions, for all substrates. The mixture of sawdust and cow manure was found as the most effective whereas the mixture containing 40% cut rice straw gave limited efficiency, suggesting organic carbon released from this substrate is not readily available for biodegradation under anaerobic conditions. The mushroom compost-based bioreactors released significant amount of sulfate, which may raise a more concern upon the start-up of field-scale bioreactors. The correlation between the extent of sulfate reduction and dissolved organic carbon/SO(4)(2-) ratio was weak and this indicates that the type of dissolved organic carbon plays a more important role in sulfate reduction than the absolute concentration and that the ratio is not sensitive enough to properly describe the relative effectiveness of substrate mixtures.

Bauxite residue neutralization with simultaneous mineral carbonation using atmospheric CO2

Simultaneous carbon mineralization during neutralization of bauxite residue, a caustic alkaline by-product of alumina refining, was tested using laboratory batch and a field pilot study in contact with atmospheric CO2. Since CO2 sequestration is limited by the Ca concentration in the bauxite residue, extra Ca sources were added in a semi-soluble mineral and salt form (flue gas desulfurization gypsum or CaCl2) to verify whether this Ca addition accelerated and enlarged the CO2 sequestration obtained as a consequence of neutralization. The results of 55 days of batch and longer-term field tests were in good agreement, and the neutralization rate was accelerated through the addition of both Ca sources. Without the addition of the extra Ca source, atmospheric CO2 contributed to neutralization of pore water alkalinity alone, while Ca addition induced further neutralization through mineral carbonation of atmospheric CO2 to CaCO3. This simple addition of environmentally benign Ca to bauxite residue may provide a feasible bauxite residue management practice that is cost-effective and easy to apply in the field.

Field application of selective precipitation for recovering Cu and Zn in drainage discharged from an operating mine

Acid mine drainage (AMD) generated from mining activities has been recognized as a serious problem due to its increased acidity and high concentration of heavy metals. In this research, a feasibility test of the selective precipitation (SP) process was performed using AMD discharged from a currently operating mine in Korea for the purpose of minimizing the environmental impact of AMD. For the SP process, a pilot scale equipment (100L reaction tank) was used in field and among various metals, Cu and Zn were the target metals. Through the research, it was confirmed that AMD from an operating mine has two disadvantages of being applied to the SP: altering water quality and unexpected inclusion of clay debris. Despite unfavorable conditions, Cu and Zn precipitate of 80% purity with 90% precipitation rate was able to be obtained from 1.4L/min (2.0tons/day) AMD. The recovered precipitates were identified as amorphous CuS and ZnS with small amounts of impurities (Si minerals, CuFeS2, and Fe/Al hydroxide). The strategies to reduce these impurities were also discussed. Recovery rate, which is the amount of precipitate collected per unit volume of AMD, was proposed as an indicator to evaluate the working efficiency of the SP process. It was confirmed that the recovery rate was strongly dependent on flow rate and dose of coagulant. The results of this study may be helpful in reducing the potential complications which occurs when SP is applied on field.

Optimizing the addition of flocculants for recycling mineral-processing wastewater

Abstract Mineral processing requires large volumes of water, but water is limited at mining sites. Therefore, techniques to recycle mineral-processing wastewater without negative effects on recovery and flotation grade are critical. Among a number of technologies to recycle water, flocculation using an anionic polymer was tested for recycling mineral-processing wastewater, as a major issue in mineral-processing wastewater recycling is to reduce suspended particles. A batch cylinder test was employed to evaluate the optimum amount of flocculant to add and settlement rate, turbidity, and floc size were measured as indications of dewaterability. Adding increasing amounts of flocculant increased the sedimentation rate due to the increased floc size. However, turbidity did not improve by increasing the concentration of flocculant because the polymer coating on the particle surface prevented efficient bridging of particles. In addition, excess use of flocculant may degrade water quality and produce unnecessary costs. Therefore, it is important to identify the optimum flocculant concentration for treating mineral-processing wastewater based on the properties of the water.

Treatment efficiency of acid mine drainage by the Ho-Nam Coal Mine passive treatment system

The Ho-nam coal mine passive treatment system, which consists of an oxidation pond, successive alkalinity producing system (SAPS) and aerobic wetland, was investigated to estimate the treatment efficiency of the entire system and each treatment step. After the acid mine drainage of Ho-nam coal mine moves through the entire system, metal concentration and acidity decreases and alkalinity increases. Acid mine drainage has been treated successfully by the Ho-nam coal mine passive treatment system. However, iron ions were not removed sufficiently in the oxidation pond even though ferrous ions oxidized to ferric ions. Furthermore, in SAPS, Fe concentration decreased rapidly but sulfate reducing bacteria activity was not shown in the system. These results suggest that the objectives of each step were not achieved as designed, although the system was found to be successful.

Evaluation of design factors for a cascade aerator to enhance the efficiency of an oxidation pond for ferruginous mine drainage

ABSTRACT This research focused on the optimum design of a cascade aerator to enhance the efficiency of an oxidation pond in a passive treatment system for remediating ferruginous mine drainage. For this purpose, various aeration experiments with aerators of different drop heights (0–4 m) and formations (types A and B) were executed on mine drainage. Type A simply drops the mine drainage into the oxidation pond while type B sprays the mine drainage and retains it for 8 min in each step. The efficiency enhancement of the oxidation pond was strongly dependent on the increase in pH and DO of the mine drainage discharged into the pond. The water quality improved with the increase in drop height but especially showed better effect with type B. The reasons for this result were attributed to the increase of contact surface and retention time of the mine drainage. The cascade aerator, therefore, should be designed to be as high as possible with the assistance of spraying form and retention time of the mine drainage to maximize the efficiency of the oxidation pond. These effects could be evaluated by calculating required areas of the oxidation pond for 95% of Fe2+ oxidation.

Assessment of the potential occurrence of acid rock drainage through a geochemical stream sediment survey

During large constructions of roads or structures, unexpected acid rock drainage (ARD) can be caused by local mineralization containing sulfides in the geology. The potential of ARD occurrence of a certain area sometimes must be assessed before initiation of any engineering earth works. However, it is difficult to assess the entire area through collecting rock samples and predicting the potential by laboratory tests, such as the acid–base accounting method. In this study, a new prediction protocol using a geochemical exploration survey technique of stream sediment is proposed. Sediment samples were collected at the case study area where a large development is expected in the future, and the contents of some major and heavy metal elements were compared according to the major geologies of the sampling points. The modified geoaccumulation indices (Igeo) of Fe, Pb and As could indicate a possible zone of pyrophyllite mineralization, which may cause the occurrence of ARD at the study area. Using the enrichment index of the three elements relative to the median values of the area, a high potential zone of ARD could be designated, which was in agreement with the laboratory ARD prediction tests of the rock samples. In the other areas with different mineralization processes, other metallic elements can be selected as indicators of the ARD potential. Likewise, the potential of the occurrence of ARD at an area can be assessed by evaluating the geochemical distributions and drawing the indicator elements for ARD through a stream sediment survey.

Evaluation of net acid generation pH as a single indicator for acid forming potential of rocks using geochemical properties

The main purpose of this research was to evaluate the geochemical properties of rocks for a single indicator of acid-forming potential. The indicators, such as net acid generation (NAG), NAG pH and total S, were applied to 312 rock samples of various geological characteristics. Additional indicators, such as a Modified NAG pH, paste pH and available acid neutralizing capacity (ANC), were applied to 22 selected samples. Among them, NAG pH was considered the most plausible single indicator in evaluating acid-forming potential, as it is simple to measure, widely applicable to various samples and can be used to estimate the NAG value. The acid-forming potential of 287 samples (92% of samples examined in this research) was classified as either non-acid forming (NAF) or potentially acid forming (PAF) by NAG pH, with an NAF criteria of <3.21 and PAF of >4.52. The NAG pH was also a good estimate of the risk of short-term acid release when combined with paste pH information. However, application of NAG pH to coal mine wastes, with high organic carbon contents, produced erroneous results due to the generation of organic acid during the NAG test. In this research, a Modified NAG pH was assessed as an alternative to NAG pH in such situations.

Assessment of the alteration and acid-generating potential of deep boreholes for geological disposal

An integrated study, including mineralogy, geochemistry, lead isotopic composition, acid–base accounting, and factor analysis, was conducted on the rock core samples from two deep boreholes (AH1 and BH3) to assess the alteration and acid-generating potential of two representative lithologies of Korea (granite and geniss) for geological disposal. The alteration condition represents water circulation features in crystalline basement rocks, which is one of the key points to be assessed in repository sites. In addition, this study proposes that the acid-producing potential and acid-consuming minerals in the host rock are important for the long-term safety of a radioactive waste repository, given that sulfide oxidation may occur in artificial fractures created during construction. Fe3+ ions can then react with other sulfide minerals in reducing conditions and release H+ and SO42−, which can deteriorate cement-based grouting materials used for carven walls as well as the host rock. The results of the study show that the composition of Pb isotopes is a good indicator of the alteration of rock core samples compared to the chemical index of alteration and loss on ignition. The acid potential ratio and net acid production potential indicate that most of the core samples in both boreholes have a high alkali-generating potential. Factor analysis shows that the neutralizing capacity in AH1 is highly correlated with the alteration, while the neutralizing capacity in BH3 is correlated with secondary minerals. The alteration appears to be related to secondary minerals and the acid-producing capacity, while the changes in major elements are not related to the Pb isotopes in BH3 due to leaching along fractures.