Sule Erten-Ela

A Panchromatic Boradiazaindacene (BODIPY) Sensitizer for Dye-Sensitized Solar Cells

A novel distyryl-substituted boradiazaindacene (BODIPY) dye displays interesting properties as a sensitizer in DSSC systems, opening the way to further exploration of structure-efficiency correlation within this class of dyes.

Solid-State Dye-Sensitized Solar Cells Using Red and Near-IR Absorbing Bodipy Sensitizers

Boron-dipyrrin dyes, through rational design, yield promising new materials. With strong electron-donor functionalities and anchoring groups for attachment to nanocrystalline TiO(2), these dyes proved useful as sensitizers in dye-sensitized solar cells. Their applicability in a solid-state electrolyte regime offers additional opportunities for practical applications.

Synthesis and dye sensitized solar cell applications of Bodipy derivatives with bis-dimethylfluorenyl amine donor groups

Three Bodipy dyes with strong absorptivities in the visible and near infrared regions were designed, synthesized and their potential as photosensitizers for liquid electrolyte-based dye sensitized solar cells have been evaluated. For the first time Bodipy derivatives with bis-dimethylfluorenyl amine donor groups which were known for their bulky structures as donor groups have been used together. We altered our mostly used triphenylamine group with these and investigated the dye-sensitized solar cell efficiencies of this new class of Bodipy dyes.

Facile synthesis and photovoltaic applications of a new alkylated bismethano fullerene as electron acceptor for high open circuit voltage solar cells

It is crucial to control the lowest unoccupied molecular orbital (LUMO) of electron accepting materials for producing efficient charge transfer in bulk heterojunction (BHJ) solar cells. Due to their high LUMO level, soluble bis-adducts of C60 are of high interest for improving the Voc in BHJ solar cells. In this work, we have developed a novel bis-4-propylpentyl[6,6]methanofullerene bis-adduct, NCBA, using a alkyl solubilizing group. The optoelectronic, electrochemical and photovoltaic properties of this bis-product are investigated. NCBA is successfully applied as the electron acceptor with poly(3-hexylthiophene) (P3HT) in a BHJ solar cell showing a high Voc of 0.73 V.

Perovskite solar cells fabricated using dicarboxylic fullerene derivatives

Perovskite solar cells were first fabricated in dye sensitized solar cells. But also, perovskite hybrid solar cells were demonstrated to be among the most promising candidates within the emerging photovoltaic materials with their high power conversion efficiencies and low-cost fabrication. In this work, we design and synthesize a novel benzoic acid fullerene bis adduct material (BAFB) for use in perovskite hybrid organic–inorganic solar cells. The obtained maximum efficiency is reported to be 9.63% using a novel benzoic acid fullerene bis adduct (BAFB) for perovskite heterojunction solar cells.

Dye Sensitized Solar Cells for Conversion of Solar Energy into Electricity

In this article, nanorod ZnO structured dye sensitized solar cells have been fabricated. Also, a compact ZnO layer was prepared to prevent back electron reactions. Device architectures were fabricated in a FTO/compact ZnO layer/nanorod ZnO layer/dye/redox mediator/Pt/FTO configuration. Nanorod ZnO electrodes were synthesized using microwave irradiation with a diameter of 14–18 nm and a length of 558 nm. The ZnO nanorod, compact ZnO products were analyzed and characterized using x-ray diffraction and scanning electron microscopy. ZnO nanorod structured dye sensitized solar cells using triphenylene diamine dyes with and without a ZnO compact layer showed efficiencies in the range of 0.64–0.96%. Sensitization of a ZnO nanorod structured dye sensitized solar cell device using TPD_2 dye with the lowest band gap shows the cell performance with an efficiency (η) of 0.84%, a short-circuit photocurrent density (Isc) of 3.49 mA/cm2, an open-circuit voltage (Voc) of 600 mV, and a fill factor of 0.40.

Highly conductive polymer materials based multi-walled carbon nanotubes as counter electrodes for dye-sensitized solar cells

ABSTRACT Poly(3,4-ethylenedioxxythiophene) (PEDOT), polyaniline (PANI) and polythiophene (PTh) based multi-walled carbon nanotube (MWCNT) composites were successfully prepared using RF-rotating plasma grafting method. Morphological characterizations of composites were determined using scanning electron microscopy (SEM), which showed that conducting polymers (CPs) of PEDOT, PANI and PTh were coated on the surface of CNTs. The surface properties of the Carbon Nanotube (CNT) composites were also determined by using Infrared Spectra (FT-IR), X-ray Photon Spectra (XPS), and Scanning Electron Microscopy-Energy Dispersive X-ray Spectra (SEM-EDX) analysis. X-ray photon spectra results confirmed the formation of the composites. Composites of MWCNT were used in dye-sensitized solar cells (DSSCs) as counter electrodes and exhibited short-circuit photocurrent densities of 11.19, 10.70 and 8.54 mA/cm2 for PANI/MWCNT, PTh/MWCNT and PEDOT/CNT, respectively. GRAPHICAL ABSTRACT

Pyrrolidino [60] and [70]fullerene homo- and heterodimers as electron acceptors for OPV

New [60] and [70]fullerene homo- and heterodimers absorbing in the visible region have been synthesized and fully characterized. In order to increase the solubility and processability of the new fullerene dimers, different alkyl chains have been used which has allowed the determination of the influence of the solubilizing alkyl groups on the photovoltaic performance. Atomic force microscopy experiments carried out on blends of these dimers and P3HT evidenced the formation of large aggregates, which significantly influence the photovoltaic efficiency.

Synthesis of zinc chlorophyll materials for dye-sensitized solar cell applications

To design sensitizers for dye sensitized solar cells (DSSCs), a series of zinc chlorins with different substituents were synthesized. Novel zinc methyl 3-devinyl-3-hydroxymethyl-20-phenylacetylenylpyropheophorbide-a (ZnChl-1), zinc methyl 20-bromo-3-devinyl-3-hydroxymethylpyropheophorbide-a (ZnChl-2), zinc methyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-3), zinc propyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-4) were synthesized and their photovoltaic performances were evaluated in dye-sensitized solar cells. Photoelectrodes with a 7 μm thick nanoporous layer and a 5 μm thick light-scattering layer were used to fabricate dye sensitized solar cells. The best efficiency was obtained with ZnChl-2 sensitizer. ZnChl-2 gave a Jsc of 3.5 mA/cm(2), Voc of 412 mV, FF of 0.56 and an overall conversion efficiency of 0.81 at full sun (1000 W m(-2)).

Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)

Triphenylene diamine sensitizer comprising donor, electron conducting, and anchoring group is synthesized for a potential application in dye-sensitized solar cells. Absorption spectrum, electrochemical and photovoltaic properties of triphenylene diamine have been investigated. Two different electrodes are used for dye-sensitized solar cells. The performances of ZnO nanorod electrodes are compared to ZnO : CdO nanocomposite electrode. Also, the theoretical calculations for HOMO and LUMO orbitals are used to estimate the photovoltaic properties of organic sensitizer in the design stage. ZnO : CdO nanocomposite electrode-based dye-sensitized solar cell sensitized with organic sensitizer exhibits higher efficiencies than ZnO nanorod electrode. For a typical device, a solar energy conversion efficiency () of 0.80 based on ZnO : CdO nanocomposite is achieved under simulated AM 1.5 solar irradiation (100 mW cm−2) with a short circuit photocurrent density () of 3.10 mA/cm2, an open-circuit voltage () of 480 mV, and a fill factor (FF) of 0.57. These results suggest that the ZnO : CdO nanocomposite system is a good selection and a promising candidate for electrode system in dye-sensitized solar cells.