Teresa L. Alleman

Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

Fuel Property, Emission Test, and Operability Results from a Fleet of Class 6 Vehicles Operating on Gas-to-Liquid Fuel and Catalyzed Diesel Particle Filters

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Mattheys CCRT diesel particulate filter. No engine modifications were made.

Quality Parameters and Chemical Analysis for Biodiesel Produced in the United States in 2011

Samples of biodiesel (B100) from producers and terminals in 2011were tested for critical properties: free and total glycerin, flash point, cloud point, oxidation stability, cold soak filterability, and metals. Failure rates for cold soak filterability and oxidation stability were below 5%. One sample failed flash point due to excess methanol. One sample failed oxidation stability and metal content. Overall, 95% of the samples from this survey met biodiesel quality specification ASTM D6751. In 2007, a sampling of B100 from production facilities showed that nearly 90% met D6751. In samples meeting D6751, calcium was found above the method detection limit in nearly half the samples. Feedstock analysis revealed half the biodiesel was produced from soy and half was from mixed feedstocks. The saturated fatty acid methyl ester concentration of the B100 was compared to the saturated monoglyceride concentration as a percent of total monoglyceride. The real-world correlation of these properties was very good. The results of liquid chromatograph measurement of monoglycerides were compared to ASTM D6751. Agreement between the two methods was good, particularly for total monoglycerides and unsaturated monoglycerides. Because only very low levels of saturated monoglycerides measured, the two methods had more variability, but the correlation was still acceptable.

Achievement of Low Emissions by Engine Modification to Utilize Gas-to-Liquid Fuel and Advanced Emission Controls on a Class 8 Truck

A 2002 Cummins ISM engine was modified to be optimized for operation on gas-to-liquid (GTL) fuel and advanced emission control devices. The engine modifications included increased exhaust gas recirculation (EGR), decreased compression ratio, and reshaped piston and bowl configuration.

The Impacts of Mid-Level Alcohol Content in Gasoline on SIDI Engine-Out and Tailpipe Emissions

The influences of ethanol and iso-butanol on gasoline engine performance, engine-out and tailpipe emissions were studied using a General Motors (GM) 2.0L turbocharged gasoline spark ignition direct injection (SIDI) engine. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuels were tested. Fourier-Transform Infrared (FTIR) spectroscopy was used to measure non-regulated species including methane, ethylene, acetylene, formaldehyde, acetaldehyde, isobutylene, 1,3-butadiene, n-pentane, and iso-octane. A Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle number (PN) size distribution in the range from 5.6 to 560 nm. The regulated emissions total hydrocarbon (THC), carbon monoxide (CO), and oxides of nitrogen (NOx ) were also measured. Both engine-out and tailpipe emissions results are presented as functions of alcohol content. In general, the alcohols tested reduced total PN emissions, with iso-butanol demonstrating the greatest reduction. Increasing ethanol content and iso-butanol increased formaldehyde emissions, with iso-butanol exhibiting the highest increase. Iso-butanol increased iso-butylene emission; however, it reduced emissions of 1,3-butadiene. Within the context of this study, the alcohols did not significantly change the other regulated emissions.© 2010 ASME

7 – Exhaust Emissions

Publisher Summary This chapter discusses impacts of biodiesel fuel on pollutant emissions from diesel engines and ultrafine particles from a heavy duty diesel engine running on rapeseed oil methyl ester. An important benefit of biodiesel has been its ability to reduce Particulate Matter (PM) emissions. PM includes soot carbon, unburned fuel, lube oil, and sulfuric acid aerosols and it is often fractionated in terms of sulfate, Soluble Organic Fraction (SOF) or Volatile Organic Fraction (VOF), and carbon or soot. Biodiesel can impact soot and SOF originating from the fuel but not SOF originating from the lubricant. Because biodiesel from many sources contains essentially no sulfur, blending biodiesel into diesel fuel can reduce sulfate emissions. Diesel engines are significant contributors of NOx and PM to air pollutant inventories. Although emission standards for NOx and PM have been significantly reduced since 2000, diesel vehicles remain a significant source of these two pollutants. The impact of biodiesel on NOx and PM emissions is the primary concern of the chapter. Biodiesel and biodiesel blends reduce total emissions of various classes of toxic compounds. PM is recognized as one of the major harmful emissions generated by the use of diesel engines; therefore, it is subject to exhaust engine emission regulations worldwide. Besides engineering parameters, such as design of the combustion chamber and the injection system, the mode of operation, or rather the overall load configuration, the fuel and lubricant quality, as well as the wear of the engine affect PM composition. Recently, exhaust emissions of fine and ultrafine particles from diesel engines caused an extensive discussion in Europe.

Property Analysis of Ethanol--Natural Gasoline--BOB Blends to Make Flex Fuel

Ten natural gasolines were analyzed for a wide range of properties, including Reid vapor pressure (RVP), benzene, sulfur, distillation, stability, metals, and aromatic content, to determine their quality. Benzene and sulfur content were sufficiently low in all but one of the samples that they could be blended without further upgrading. Four of these samples were selected to blend with blendstock for oxygenate blending (BOB) and ethanol to produce E51, E70, and E83 blends, targeting 7.8 and 9.0-psi finished fuels. The volume of each component in the blend was estimated using the Reddy model, with the assumption that the BOB and natural gasoline blend linearly and behave as a single component in the model calculations. Results show that the Reddy model adequately predicts the RVP of the finished blend for E51 and E70, but significantly underpredicts the RVP of E83 blends by nearly 2 psi. It is hypothesized that the underprediction is a function of the very low aromatic content of the E83 blends, even compared to the E51 and E70 blends.