V. I. Kovalenko

Geochronology of igneous rocks and formation of the Late Paleozoic south Mongolian active margin of the Siberian continent

The succession of magmatic events associated with development of the Early Carboniferous-Early Permian marginal continental magmatic belt of southern Mongolia is studied. In the belt structure there are defined the successive rock complexes: the older one represented by differentiated basalt-andesite-rhyodacite series and younger bimodal complex of basalt-comendite-trachyrhyolite composition. The granodiorite-plagiogranite and banatite (diorite-monzonite-granodiorite) plutonic massifs are associated with the former, while peralkaline granite massifs are characteristic of the latter. First systematic geochronological study of igneous rock associations is performed to establish time succession and structural position of both complexes. Geochronological results and geological relations between rocks of the bimodal and differentiated complexes showed first that rocks of the differentiated complex originated 350 to 330 Ma ago at the initial stage of development of the marginal continental belt. This is evident from geochronological dates obtained for the Adzh-Bogd and Edrengiyn-Nuruu massifs and for volcanic associations of the complex. The dates are consistent with paleontological data. The bimodal association was formed later, 320 to 290 Ma ago. The time span separating formation of two igneous complexes ranges from several to 20–30 m.y. in different areas of the marginal belt. The bimodal magmatism was interrelated with rifting responsible for development of the Gobi-Tien Shan rift zone in the belt axial part and the Main Mongolian lineament along the belt northern boundary. Loci of bimodal rift magmatism likely migrated with time: the respective magmatic activity first initiated on the west of the rift system and then advanced gradually eastward with development of rift structures. Normal granitoids untypical but occurring nevertheless among the products of rift magmatism in addition to peralkaline massifs are assumed to have been formed, when the basic magmatism associated with rifting stimulated crustal anatexis and generation of crustal granitoid magmas under specific conditions of rifting within the active continental margin.

Isotopic structure and evolution of the continental crust in the East Transbaikalian segment of the Central Asian Foldbelt

New data on the geology and tectonics of the main structural elements of the East Transbaikalian segment of the Central Asian Foldbelt are discussed. Correlation charts of the main stratified and igneous complexes are compiled. The rocks of the Baikal-Patom and Baikal-Muya belts, as well as the Barguzin-Vitim Superterrane, are characterized by new Nd isotopic data, which have allowed us to establish the sources of these rocks, to separate isotopic provinces, and to distinguish two stages of crust-forming processes: the Early Baikalian (1.0–0.8 Ga) and the Late Baikalian (0.70–0.62 Ga). The Early Baikalian crust was formed in relatively narrow and spatially isolated troughs of the Baikal-Muya Belt and probably in the Amalat Terrane, whereas the Late Baikalian continental crust was formed and reworked in the Karalon-Mamakan, Yana, and Katera-Uakit zones of the Baikal-Muya Belt. The Baikal-Patom Belt and most of the Anamakit-Muya Zone in the Baikal-Muya Belt are characterized by remobilization of the Early Precambrian continental crust and by a subordinate role of Late Riphean juvenile sources. Reworking of the mixed Late Riphean and Early Precambrian crustal sources is typical of the Barguzin-Vitim Superterrane. The origination and evolution of the continental crust in the studied region are considered in light of new data; alternative versions of paleogedynamic reconstructions are discussed.

Composition, sources, and mechanism of continental crust growth in the Lake zone of the Central Asian Caledonides: I. Geological and geochronological data

Data on the composition, inner structure, and age of volcanic and siliceous-terrigenous complexes and granitoids occurring in association with them in the Caledonian Lake zone in Central Asia are discussed in the context of major relations and trends in the growth of the Caledonian continental crust in the Central Asian Foldbelt (CAFB). The folded structures of the Lake zone host basalt, basalt-andesite, and andesite complexes of volcanic rocks that were formed in distinct geodynamic environments. The volcanic rocks of the basalt complex are noted for high concentrations of TiO2 and alkalis, occur in association with fine-grained siliceous siltstone and siliceous-carbonate rocks, are thus close to oceanic-island complexes, and were likely formed in relation to a mantle hotspot activity far away from erosion regions supplying terrigenous material. The rocks of the basalt-andesite and andesite complexes have lower TiO2 concentrations and moderate concentrations of alkalis and contain rock-forming amphibole. These rocks are accompanied by rudaceous terrigenous sediments, which suggests their origin in island-arc environments, including arcs with a significantly dissected topography. These complexes are accompanied by siliceous-terrigenous sedimentary sequences whose inner structure is close to those of sediments in accretionary wedges. The folded Caledonides of the Lake zone passed through the following evolutionary phases. The island arcs started to develop at 570 Ma, their evolution was associated with the emplacement of layered gabbroids and tonalitetrondhjemite massifs, and continued until the onset of accretion at 515–480 Ma. The accretion was accompanied by the emplacement of large massifs of the tonalite-granodiorite-plagiogranite series. The postaccretionary evolutionary phase at 470–440 Ma of the Caledonides was marked by intrusive subalkaline and alkaline magmatism. The Caledonides are characterized by within-plate magmatic activity throughout their whole evolutionary history, a fact explained by the accretion of Vendian-Cambrian oceanic structures (island arcs, oceanic islands, and back-arc basins) above a mantle hotspot. Indicators of within-plate magmatic activity are subalkaline high-Ti basalts, alkaline-ultrabasic complexes with carbonatites and massifs of subalkaline and alkaline gabbroids, nepheline syenites, alkaline granites, subalkaline granites, and granosyenites. The mantle hotspot likely continued to affect the character of the lithospheric magmatism even after the Caledonian folded terrane was formed.

Composition, sources, and mechanisms of formation of the continental crust of the Lake zone of the Central Asian Caledonides. II. Geochemical and Nd isotope data

Part II of this paper reports geochemical and Nd isotope characteristics of the volcanogenic and siliceous-terrigenous complexes of the Lake zone of the Central Asian Caledonides and associating granitoids of various ages. Geological, geochronological, geochemical, and isotopic data were synthesized with application to the problems of the sources and main mechanisms of continental crust formation and evolution for the Caledonides of the Central Asian orogenic belt. It was found that the juvenile sialic crust of the Lake zone was formed during the Vendian-Cambrian (approximately 570–490 Ma) in an environment of intraoceanic island arcs and oceanic islands from depleted mantle sources with the entrainment of sedimentary crustal materials into subduction zones and owing to the accretion processes of the amalgamation of paleoceanic and island arc complexes and Precambrian microcontinents, which terminated by ∼490 Ma. The source of primary melts for the low-Ti basalts, andesites, and dacites of the Lake zone ophiolites and island arc complexes was mainly the depleted mantle wedge above a subduction zone. In addition, an enriched plume source contributed to the genesis of the high-Ti basalts and gabbroids of oceanic plateaus. The source of terrigenous rocks associating with the volcanics was composed of materials similar in composition to the country rocks at a minor and varying role of ancient crustal materials introduced into the ocean basin owing to the erosion of Precambrian microcontinents. The sedimentary rocks of the accretionary prism were derived by the erosion of mainly juvenile island arc sources with a minor contribution of rocks of the mature continental crust. The island arc and accretion stages of the development of the Lake zone (∼540–590 Ma) were accompanied by the development of high- and low-alumina sodic granitoids through the melting at various depths of depleted mantle reservoirs (metabasites of a subducted oceanic slab and a mantle wedge) and at the base of the island arc at the subordinate role of ancient crustal rocks. The melts of the postaccretion granitoids of the Central Asian Caledonides were derived mainly from the rocks of the juvenile Caledonian crust at an increasing input of an ancient crustal component owing to the tectonic mixing of the rocks of ophiolitic and island arc complexes and microcontinents. The obtained results indicate that the Vendian-Early Paleozoic stage of the evolution of the Central Asian orogenic belt was characterized by the extensive growth of juvenile continental crust and allow us to distinguish a corresponding stage of juvenile crust formation.

Structure and Evolution of the Continental Crust in the Baikal Fold Region

A summary of original Nd isotopic data on granitoids, silicic volcanics, and metasediments of the Baikal Fold Region is presented. The available Nd isotopic data, in combination with new geological and geochronological evidence, allowed recognition of the Early Baikalian (1000 ± 100 to 720 ± 20 Ma) and Late Baikalian (700 ± 10 to 590 ± 5 Ma) tectonic cycles in the geological evolution. The tectonic stacking, deformation, metamorphism, and granite formation are related to orogenic events that occurred 0.80–0.78 Ga and 0.61–0.59 Ga ago. The crust-forming events dated at 1.0–0.8 Ga and 0.70–0.62 Ga pertain to each cycle. The Early Baikalian crust formation developed largely in the relatively narrow and spatially separated Kichera and Param-Shamansky zones of troughs in the Baikal-Muya Belt. The formation and reworking of the Late Baikalian continental crust played the leading role in the Karalon-Mamakan, Yana, and Kater-Uakit zones and in the Svetlinsky Subzone of the Anamakit-Muya Zone in the Baikal-Muya Belt. In general, three large historical periods are recognized in the evolution of the Baikal Fold Region. The Early Baikalian period was characterized by prevalence of reworking of the older continental crust. The Late Baikalian-Early Caledonian period is distinguished by more extensive formation and transformation of the juvenile crust. The third, Late Paleozoic period was marked by reworking of the continental crust with juxtaposition of all older crustal protoliths. Two models of paleogeodynamic evolution of the Baikalian fold complexes are considered: (1) the autochthonous model that corresponds to the formation of suboceanic crust in rift-related basins of the Red Sea type and its subsequent reworking in the course of collision-related squeezing of paleorifts and intertrough basins and (2) the allochthonous model that implies the formation of fragments of the Baikal-Muya Belt at the shelf of the Rodinia supercontinent, their subsequent participation in the evolution of the Paleoasian ocean, and their eventual juxtaposition during Late Baikalian and Early Caledonian events in the structure of the Caledonian Siberian Superterrane of the Central Asian Foldbelt.

Geology, Geochronology, and Geodynamics of the Khan Bogd Alkali Granite Pluton in Southern Mongolia

The Khan Bogd alkali granite pluton, one of the world’s largest, is situated in the southern Gobi Desert, being localized in the core of the Late Paleozoic Syncline, where island-arc calc-alkaline differentiated volcanics (of variable alkalinity) give way to the rift-related bimodal basalt-comendite-alkali granite association. The tectonic setting of the Khan Bogd pluton is controlled by intersection of the near-latitudinal Gobi-Tien Shan Rift Zone with an oblique transverse fault, which, as the rift zone, controls bimodal magmatism. The pluton consists of the eastern and the western ring bodies and comes into sharp intrusive contact with rocks of the island-arc complex and tectonic contact with rocks of the bimodal complex. The inner ring structure is particularly typical of the western body and accentuated by ring dikes and roof pendants of the country island-arc complex. According to preliminary gravity measurements, the pluton is a flattened intrusive body (laccolith) with its base subsiding in stepwise manner northwestward. Reliable geochronologic data have been obtained for both plutonic and country rocks: the U-Pb zircon age of alkali granite belonging to the main intrusive phase is 290 ± 1 Ma, the 40Ar/39Ar ages of amphibole and polylithionite are 283 ± 4 and 285 ± 7 Ma, and the Rb-Sr isochron yields 287 ± 3 Ma; i.e., all these estimates are close to 290 Ma. Furthermore, the U-Pb zircon age of red normal biotite granite (290 ± 1 Ma) and the Rb-Sr age of the bimodal complex in the southern framework of the pluton are the same. The older igneous rocks of the island-arc complex in the framework and roof pendants of the pluton are dated at 330 Ma. The geodynamic model of the Khan Bogd pluton formation suggests collision of the Hercynian continent with a hot spot in the paleoocean; two variants of this model are proposed. According to the first variant, the mantle plume, after collision with the margin of the North Asian paleocontinent, reworked the subducted lithosphere and formed a structure similar to an asthenospheric window, which served as a source of rift-related magmatism and the Khan Bogd pluton proper. In compliance with the second variant, the emergence of hot mantle plume resulted in flattening of the subducted plate; cessation of the island-arc magmatism; and probably in origin of a local convective system in the asthenosphere of the mantle wedge, which gave rise to the formation of a magma source. The huge body of the Khan Bogd alkali granite pluton and related volcanic rocks, as well as its ring structure, resulted from the caldera mechanism of the emplacement and evolution of magmatic melts.

Late Riphean alkali granites of the Zabhan microcontinent: Evidence for the timing of Rodinia breakup and formation of microcontinents in the Central Asian Fold belt

The estimation of chronological boundaries in the geological history of the Rodinia supercontinent, in particular, the age of its breakup is far from a final solution. The enormous size of the supercontinent rules out synchronization of geological events throughout its territory. In addition, the estimation is complicated by unreliable reconstructions of positions of particular cratons within the supercontinent and a shortage of geochronological data on substantiation of the timing of breakup in separate parts of Rodinia. Most likely, this was a long-term process similar to that of the breakup of Pangea, which lasted for almost 150 Ma from the Early Jurassic to the Early Cenozoic [1]. The long-term character of these events is evidenced by the available geochronological data on the processes of rifting that initiated the breakup in various parts of Rodinia. For example, according to the reconstruction [2], two age levels of rifting are established beyond the Laurasian part of the supercontinent. The older event occurred from 830 to 795 Ma ago. The younger event (780‐ 745 Ma ago) completed the breakup of the continental lithosphere. The Laurasian part of Rodinia was broken into the Siberian and Laurentian continents 720‐ 630 Ma ago [3]. The breakup of Rodinia promoted the origin of the Paleoasian ocean, the evolution of which produced the Central Asian Fold belt (CAFB). The terranes (microcontinents) of the Precambrian crust within the fold belt are regarded as fragments of supercontinent margins [3]. Such an interpretation is supported by structural and historical similarities of the terranes with some continental massifs in Rodinia and by wide occurrence of shelf complexes therein. However, the timing of separation of these terranes from the supercontinent and their initial location remain uncertain. In this communication, new data on the isotopic age and composition of the Late Riphean alkali granites of the Zabhan Terrane established in the CAFB are reported for the first time and the timing of the breakup and approximate position of this microcontinent in Rodinia is outlined. Geological characteristics. The Zabhan microcontinent (Fig. 1) represents terranes with an Early Precambrian basement, which are rare in the CAFB. The oldest metamorphic rocks of the Baidarik Block are subdivided into the Upper Archean Baidarag and the Lower Proterozoic Bumbuger crystalline complexes [4]. The stages of the microcontinent evolution are broadly correlated with those of the North Chinese and Siberian cratons [4]. The collisional processes responsible for the formation of the main tectonic units of these cratons and the microcontinent occurred almost synchronously 1.90‐1.85 Ga ago. In the northeast, the basement rocks are unconformably overlapped by primarily greenschist-facies rocks of the Ul’dzit-Gol Complex (metasandstones, black shales, and marmorized dolomites) of presumably Middle‐lower Upper Riphean age. Based on the K‐Ar actinolite dating, the age of greenschist-facies metamorphism of rocks of this complex is estimated at ~840 Ma [5]. In the western part of the microcontinent, the basement rocks are overlain by gently dipping subaerial volcanics of the Zabhan Group [6]. They are composed of virtually unmetamorphosed violet, black, and redbrown subaerial volcanic glasses, vitreous rhyodacites and trachyrhyolites, as well as ignimbrites with rare small feldspar and quartz phenocrysts. The subordinate basic and intermediate volcanic rocks are usually confined to the base of the group and to its roof in some places [6]. Their share increases toward the western

Average compositions of igneous melts from main geodynamic settings according to the investigation of melt inclusions in minerals and quenched glasses of rocks

We compiled a database containing more than 480000 determinations for 73 elements in melt inclusions in minerals and quenched glasses of volcanic rocks. These data were used to estimate the mean contents of major, volatile, and trace elements in igneous melts from main geodynamic settings. The following settings were distinguished: (I) oceanic spreading zones (mid-ocean ridges); (II) zones of mantle plume activity on oceanic plates (oceanic islands and plateaus); (III) and (IV) settings related to subduction processes, including (III) zones of island-arc magmatism generated on the oceanic crust and (IV) magmatic zones of active continental margins involving the continental crust into magma generation processes; (V) intracontinental rifts and continental hot spots; and (VI) back-arc spreading centers. The histogram of SiO2 contents in the natural igneous melts of all geodynamic settings exhibits a bimodal distribution with two maxima at SiO2 contents of 50–52 wt % and 72–74 wt %. The range 62–64 wt % SiO2 comprises the minimum number of determinations. Primitive mantle-normalized spidergrams were constructed for average contents of elements in the igneous melts of basic, intermediate, and acidic compositions from settings I–V. The diagrams reflect the characteristic features of melt compositions for each geodynamic setting. On the basis of the analysis of data on the composition of melt inclusions and glasses of rocks, average ratios of incompatible trace and volatile components (H2O/Ce, K2O/Cl, Nb/U, Ba/Rb, Ce/Pb, etc.) were estimated for the igneous melts of all of the settings. Variations of these ratios were determined, and it was shown that, in most cases, the ratios of incompatible elements are significantly different between settings. The difference is especially pronounced for the ratios of elements with different degrees of incompatibility (e.g., Nb/Yb) and for some ratios with volatile components (e.g., K2O/H2O).

Crust-forming processes in the Hercynides of the Central Asian Foldbelt

The paper reports data on the evolutionary history of magmatism, its conditions, and sources in the process of the development of the Southern Mongolian Hercynides during the pre-accretion, continental-margin, and rifting stages within the time span from the Silurian to Early Permian. The Hercynian continental crust in the southern Mongolian segment of the Central Asian Foldbelt (CAFB) was determined to have grown in the environment of ensimatic island arcs, backarc basins, spreading centers, and oceanic islands or plateaus, with material coming from the depleted and, perhaps, also enriched mantle sources in the open ocean that surrounded the Siberian paleocontinent on the side of the Caledonian margin. This made it possible to recognize the Early-Middle Paleozoic epoch of juvenile crustal growth in CAFB and the corresponding isotopic crustal province with a total area of more than 200 thousand km2. The principal differences between the composition and structure of the blocks surrounding the Hercynian regions (Caledonides in the Gobi Altai and Grenwillides in the South Gobi microcontinent) testify that the southern margin of the Caledonian Siberian continent and the Grenvillides of the South Gobi microcontinent had different geological histories and were spatially separated. The structural complex of the Paleoasian ocean, including the terranes of the South Gobi microcontinent, were transformed into a continental block in the latest Devonian-earliest Carboniferous, in relation with accretion processes, folding, metamorphism, and tectonic delamination along the boundaries of structurally heterogeneous domains. The subsequent recycling of the crust by magmatic processes was related to the development of an active continental margin (ACM). The development of an ACM in the Hercynides resulted from and was a continuation of the motions of the continental and oceanic lithospheric plates, i.e., processes that brought about the Hercynian accretion. The evolution history of the ACM was subdivided into two stages: early (a continental-margin stage proper) and late (rifting stage). The rocks of the early stage were produced at 350–330 Ma and compose a differentiated basalt-andesite-rhyodacite complex and related massifs of the granodiorite-plagiogranite and banatite (diorite-monzonite-granodiorite) associations. During the rifting stage at 320–290 Ma, a bimodal basalt-comendite-trachyrhyolite association was formed, along with accompanying alkali granite massifs. In the southern Mongolian segment of the Hercynides, the rocks of the rifting stage compose two subparallel rift zones: Gobi-Tien Shan, which extends along the boundaries of the South Gobi microcontinent, and the Main Mongolian lineament, which marks the boundaries between the Hercynides and Caledonides in the CAFB. The rift structures are made up of alkali granitoids and normal-alkalinity granitoids, which are atypical of rift zones. Their genesis is thought to have been related to crustal anatexis, a process that was triggered by rift-related magmas at an unusual combination of rifting and ACM tectonic setting. The basic rocks of the rift associations have geochemical signatures atypical of continental rifting. They show Ta and Nb minima and K and Pb maxima, as is typical of rocks generated at convergent plate boundaries. Nevertheless, the broad variations in the concentrations and ratios of some major and incompatible trace elements and in the Sr, Nd, and O isotopic composition of the rift basaltoids allowed us to distinguish their high-and low-Ti varieties, which were produced with the participation of three mantle sources: depleted mantle similar to the source of basalts in midoceanic ridges, enriched mantle like the source of basalts in oceanic islands, and the mantle material of the metasomatized mantle wedge. The origin of andesites in the rift zones is explained by the contamination of mantle basaltoid melts with sialic (predominantly sedimentary) material of the continental crust or the assimilation of anatectic partial granite melts.

Average compositions of magmas and mantle sources of mid-ocean ridges and intraplate oceanic and continental settings estimated from the data on melt inclusions and quenched glasses of basalts

Based on the generalization of the compositions of melt inclusions and quenched glasses from basaltic rocks, the average compositions of magmas were estimated for mid-ocean ridges (MOR), intraplate continental environments (CR), and ocean islands and plateaus (OI). These compositions were used to constrain the average contents of trace and volatile elements in mantle sources. A procedure was developed for the estimation of the average contents of incompatible elements, including volatiles (H2O, Cl, F, and S), in the mantle. A comparison of the obtained average contents for the depleted mantle (DM) with the available published estimates showed that the contents of most incompatible trace elements (H2O, Cl, F, Be, B, Rb, Sr, Zr, Ba, La, Ce, Nd, Sm, Eu, Hf, Ta, Th, and U) can be reliably estimated from the ratio of K to the desired trace element in the MOR magmas and the average content of K in the DM. For Nb, Ti, P, S, Li, Y, and heavy REE, we used the ratios of their contents to an element with a similar degree of incompatibility in MOR magmas (U for Nb and Dy for the other elements). This approach was used to determine the average contents of incompatible elements in oceanic plume mantle (OPM) and the subcontinental mantle of intraplate settings or continental plume mantle (CPM). It was shown that the average composition of both suboceanic and subcontinental mantle plumes is moderately enriched compared with the DM in the most incompatible elements (K, U, Ba, and La) and volatile components (H2O, Cl, and F). The extent of volatile component enrichment in the plume mantle (500–1500 ppm H2O) is insufficient for a significant depression of the mantle solidus. Therefore, mantle plumes must be hotter than the ambient depleted mantle. The average contents of incompatible trace elements in the OPM are similar to those of the primitive mantle, which could be related either to the retention of primitive mantle material in the regions of plume generation or to DM fertilization at the expense of the deep mantle recycling of crustal materials. In the latter case, the negative anomaly of water in the trace-element distribution patterns of the OPM is explained by the participation of dehydrated crust in its formation. Variations in the compositions of magmas and their sources were considered for various geodynamic settings, and it was shown that the sources are heterogeneous with respect to trace and volatile components. The chemical heterogeneity of the magma sources and gradual transitions between them suggest that the mantle reservoirs interact with each other. Chemical variations in continental and oceanic plume magmas can be attributed to the existence of several interacting sources, including one depleted and at least two enriched reservoirs with different contents of volatiles. These variations are in agreement with the zoned structure of mantle plumes, which consist of a hot and relatively dry core, a colder outer shell with high contents of volatile components, and a zone of interaction between the plume and depleted mantle.