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Dive into the research topics where William A. Kiel is active.

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Featured researches published by William A. Kiel.


Journal of the American Chemical Society | 1983

Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction

William A. Kiel; Gong Yu Lin; Gerardo S. Bodner; J. A. Gladysz

The regioselectivity and stereochemistry of these reactions are examined. Structures are evaluated with NMR. 4 figures, 4 tables.


Journal of the American Chemical Society | 1982

Synthesis and properties of [(.eta.-C5H5)Re(NO)(PPh3)(:CHC6H5)]+PF6-: a benzylidene complex that is formed by a stereospecific .alpha.-hydride abstraction, exists as two geometric isomers, and undergoes stereospecific nucleophilic attack

William A. Kiel; Gong Yu Lin; Anthony G. Constable; Fred B. McCormick; Charles E. Strouse; Odile Eisenstein; J. A. Gladysz


Journal of the American Chemical Society | 1983

Mechanism of coupling of methylidene to ethylene at a homogeneous (triphenylphosphine)nitrosyl(.eta.-cyclopentadienyl)rhenium(+) [(.eta.-C5H5)Re(NO)(PPh3)]+ center. Remarkable enantiomer self-recognition

James H. Merrifield; Gong Yu Lin; William A. Kiel; J. A. Gladysz


Organometallics | 1984

Reactions of benzylrhenium complexes (.eta.5-C5H5)Re(NO)(L)(CH2Ar) with Ph3C+PF6. Analysis of the Re-C.alpha. rotamers involved in .alpha.-hydride abstraction

William A. Kiel; William E. Buhro; J. A. Gladysz


Organometallics | 1982

A new organometallic photoreaction: interconversion of metal-alkylidene geometric isomers

Fred B. McCormick; William A. Kiel; J. A. Gladysz


ChemInform | 2002

Synthesis and electrophile-induced disproportionation of the neutral formyl triphenylphosphinenitrosyl-.eta.-cyclopentadienylrhenium formyl ((.eta.-C5H5)Re(NO)(PPh3)(CHO))

Wilson Tam; Gong Yu Lin; Wai Kwok Wong; William A. Kiel; Victor K. Wong; J. A. Gladysz


ChemInform | 2002

Unprecedented regiospecificity and stereospecificity in reactions of Ph3C+PF6- with rhenium alkyls of the formula (.eta.-C5H5)Re(NO)(PPh3)(CH2R)

William A. Kiel; Gong-Yu Lin; J. A. Gladysz


Archive | 1983

Regiospecific and stereospecific reactions of PhâC/sup +/PFââ» with rhenium alkyls (eta-CâHâ)Re(NO)(PPhâ)(R). cap alpha. - vs. beta. -hydride abstraction

William A. Kiel; G. Y. Lin; G. S. Bodner; J. A. Gladysz


Archive | 1982

Synthesis and electrophile-induced disproportionation of the neutral formyl e-CâHâ)Re(NO)(PPhâ)(CHO)

William Tam; Gong Yu Lin; W. S. Wong; William A. Kiel; Victor K. T. Wong; J. A. Gladysz


Journal of the American Chemical Society | 1982

Synthesis and electrophile-induced disproportionation of the neutral formyl e-C/sub 5/H/sub 5/)Re(NO)(PPh/sub 3/)(CHO)

Wilson Tam; Gong-Yu Lin; Wai Kwok Wong; William A. Kiel; Victor K. Wong; J. A. Gladysz

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Wilson Tam

University of California

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William E. Buhro

Washington University in St. Louis

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