Xingxing Liu

Tuning phase transition temperature of VO2 thin films by annealing atmosphere

A simple new way to tune the optical phase transition temperature of VO2 films was proposed by only controlling the pressure of oxygen during the annealing process. Vanadium films were deposited on glass by a large-scale magnetron sputtering coating system and then annealed in appropriate oxygen atmosphere to form the VO2 films. The infrared transmission change (at 2400 nm) is as high as 58% for the VO2 thin film on the glass substrate, which is very good for tuning infrared radiation and energy saving as smart windows. The phase transition temperature of the films can be easily tuned from an intrinsic temperature to 44.7 °C and 40.2 °C on glass and sapphire by annealing oxygen pressure, respectively. The mechanism is: V3+ ions form in the film when under anaerobic conditions, which can interrupt the V4+ chain and reduce the phase transition temperature. The existence of V3+ ions has been observed by x-ray photoelectron spectroscopy (XPS) experiments as proof.

High performance colored selective absorbers for architecturally integrated solar applications

Architecturally integrated solar thermal technologies such as solar water heaters and solar thermoelectric generators (STEGs) rely on spectrally selective solar absorbers. These solar absorbers need to have simultaneous high solar absorptivity (α) and low thermal emissivity (e), which always makes them look dark blue or black and so blocks architectural integrated solar applications. A colorful appearance should be taken into account for integration into architectural applications. Herein, colored absorbers with a TiNxOy absorbing layer and a TiO2/Si3N4/SiO2 dielectric stack are elaborately designed and can be fabricated with only two targets, Ti and Si, by using reactive magnetron sputtering. Both the theoretical and experimental results show that the color can be tuned a huge amount, while keeping solar absorptivity higher than 95% and thermal emissivity lower than 5%. The highest absorptivity and energy efficiency (α/e) values are 97.6% and 27.2, respectively. These materials can also be fabricated onto thermoelectric generators to demonstrate the conversion of solar energy into electricity. The open circuit voltage dramatically increases from 171 mV to 523 mV (3.1 times) when using the absorbers. Additionally, the colored solar absorbers can be deposited onto most types of substrate, even flexible substrates. They can simultaneously satisfy the aesthetic requirements and excellent energy performance required for architecturally integrated solar thermal and thermoelectric applications, as well as applications in other fields.

Colorful solar selective absorber integrated with different colored units.

Solar selective absorbers are the core part for solar thermal technologies such as solar water heaters, concentrated solar power, solar thermoelectric generators and solar thermophotovoltaics. Colorful solar selective absorber can provide new freedom and flexibility beyond energy performance, which will lead to wider utilization of solar technologies. In this work, we present a monolithic integration of colored solar absorber array with different colors on a single substrate based on a multilayered structure of Cu/TiN(x)O(y)/TiO(2)/Si(3)N(4)/SiO(2). A colored solar absorber array with 16 color units is demonstrated experimentally by using combinatorial deposition technique via changing the thickness of SiO(2) layer. The solar absorptivity and thermal emissivity of all the color units is higher than 92% and lower than 5.5%, respectively. The colored solar selective absorber array can have colorful appearance and designable patterns while keeping high energy performance at the same time. It is a new candidate for a number of solar applications, especially for architecture integration and military camouflage.

Interference-aided spectrum-fitting method for accurate film thickness determination

A new approach was proposed to accurately determine the thickness of film, especially for ultra-thin film, through spectrum fitting with the assistance of interference layer. The determination limit can reach even less than 1 nm. Its accuracy is far better than traditional methods. This determination method is verified by experiments and the determination limit is at least 3.5 nm compared with the results of AFM. Furthermore, double-interference-aided spectra fitting method is proposed to reduce the requirements of determination instruments, which allow one to determine the film thickness with a low precision common spectrometer and largely lower the cost. It is a very high precision determination method for on-site and in-situ applications, especially for ultra-thin films.

Colored solar-thermal absorbing coatings with high absorptance

Its difficult to obtain different color appearance and keep high absorptance simultaneously. We introduce TiO2/Si3N4/SiO2 films into TiNxOy based solar-thermal absorbing coatings to tune the color appearance in a large range, while keeping the absorptance higher than 95%.