Xun Jiang

Satellite remote sounding of mid-tropospheric CO2

Human activity has increased the concentration of the earths atmospheric carbon dioxide, which plays a direct role in contributing to global warming. Mid-tropospheric CO_2 retrieved by the Atmospheric Infrared Sounder shows a substantial spatiotemporal variability that is supported by in situ aircraft measurements. The distribution of middle tropospheric CO_2 is strongly influenced by surface sources and large-scale circulations such as the mid-latitude jet streams and by synoptic weather systems, most notably in the summer hemisphere. In addition, the effects of stratosphere-troposphere exchange are observed during a final stratospheric warming event. The results provide the means to understand the sources and sinks and the lifting of CO_2 from surface layers into the free troposphere and its subsequent transport around the globe. These processes are not adequately represented in three chemistry-transport models that have been used to study carbon budgets.

Interannual variability of mid‐tropospheric CO2 from Atmospheric Infrared Sounder

Atmospheric Infrared Sounder (AIRS) offers a unique opportunity to investigate the variability of mid-tropospheric CO_2 over the entire globe. In this paper, we use AIRS data to examine the interannual variability of CO_2 and find significant correlations between AIRS mid-tropospheric CO_2 and large-scale atmospheric dynamics. During El Nino events, mid-tropospheric CO_2 over the central Pacific Ocean is enhanced whereas it is reduced over the western Pacific Ocean as a result of the change in the Walker circulation. The variation of AIRS CO_2 in the high latitudes of the northern hemisphere is closely related to the strength of the northern hemispheric annular mode. These results contribute to a better understanding of the influence of large-scale dynamics on tracer distributions.

Extratropical signature of the quasi-biennial oscillation

Using the assimilated data from the National Centers for Environmental Prediction (NCEP) reanalysis, we show that the extratropical signature of the tropical quasi-biennial oscillation (QBO) is seen mostly in the North Annular Mode (NAM) of atmospheric variability. To understand the extratropical manifestation of the QBO, we discuss two effects that have been suggested earlier: (1) The extratropical circulation is driven by the QBO modulation of the planetary wave flux, and (2) the extratropical circulation is driven by the QBO-induced meridional circulation. We found that the first effect is seen in wave 1 in the beginning of winter and in wave 2 in the end of winter. The QBO-induced circulation affects midlatitude regions over the entire winter. To investigate the QBO-NAM coupling, we use an equation that relates the stream function of the meridional circulation and the polar cap averaged temperature, which is a proxy for the NAM index. In addition to the annual Ω_a and the QBO frequency Ω_Q the spectrum of its solutions indicates the satellite frequencies at Ω_a ± Ω_Q.

Lorenz energy cycle of the global atmosphere based on reanalysis datasets

The mean state of the global atmospheric energy cycle is re-examined using the two reanalysis datasets — NCEP2 and ERA40 (1979–2001). The general consistency between the two datasets suggests that the present estimates of the energy cycle are probably the most reliable ones. The comparison between the present and a previous study shows noticeable discrepancies in some of the energy components and conversion rates. The current estimate of the transformations from mean potential energy to mean kinetic energy C(P_M, K_M) further suggests that the near-surface processes play an important role in the conversion rate C(P_M, K_M), along with the Ferrel cell and Hadley cells, which probably change the direction of the conversion rate C(P_M, K_M).

Evidence for carbonyl sulfide (OCS) conversion to CO in the lower atmosphere of Venus

The chemical regimes in the atmosphere of Venus vary from photochemistry in the middle atmosphere to thermal equilibrium chemistry in the lower atmosphere and the surface. Many chemical cycles have been proposed, but few details about these cycles are fully verified by comparison between observations and modeling. Recent high-quality data of carbonyl sulfide (OCS) and CO from ground-based and Venus Express observations provide a unique opportunity to test our understanding of chemistry and transport in the lower atmosphere of Venus. The spatial distributions of OCS and CO in the atmosphere reflect a sensitive balance between chemistry and transport. On the basis of our updated photochemical model and winds from Lee et al.s (2007) general circulation model, we study the chemistry and transport in a simplified two-dimensional chemistry-transport model. OCS is produced by heterogeneous reactions on the surface; the middle atmosphere is a net sink for OCS. The combination of data and modeling provides strong evidence for the loss of OCS by conversion to CO. The detailed chemical mechanism is currently unknown, although a number of speculations have been proposed. The sensitivity of the distributions of OCS and CO to model parameters is reported.

Quasi‐biennial oscillation and quasi‐biennial oscillation–annual beat in the tropical total column ozone: A two‐dimensional model simulation

The National Centers for Environmental Prediction–Department of Energy Reanalysis 2 data are used to calculate the monthly mean meridional circulation and eddy diffusivity from 1979 to 2002 for use in the California Institute of Technology–Jet Propulsion Laboratory two-dimensional (2-D) chemistry and transport model (CTM). This allows for an investigation of the impact of dynamics on the interannual variability of the tropical total column ozone for all years for which the Total Ozone Mapping Spectrometer and the Solar Backscatter Ultraviolet merged total ozone data are available. The first two empirical orthogonal functions (EOFs) of the deseasonalized and detrended stratospheric stream function capture 88% of the total variance on interannual timescales. The first EOF, accounting for over 70% of the interannual variance, is related to the quasi-biennial oscillation (QBO) and its interaction with annual cycles, the QBO-annual beat (QBO-AB). The 2-D CTM provides realistic simulations of the seasonal and interannual variability of ozone in the tropics. The equatorial ozone anomaly from the model is close to that derived from the observations. The phase and amplitude of the QBO are well captured by the model. The magnitude of the QBO signal is somewhat larger in the model than it is in the data. The QBO-AB found in the simulated ozone agrees well with that in the observed data.

The pattern of northern hemisphere surface air temperature during prolonged periods of low solar output

We show that the reconstructed sensitivity of the sea level temperature to long term solar forcing in the Northern Hemisphere is in very good agreement with the empirical temperature pattern corresponding to changes of the North Annular Mode (NAM). This implies that long-term variations of solar output affect climate predominantly through the NAM that extends throughout the stratosphere and troposphere.

Seasonal cycle of N2O: Analysis of data

We carried out a systematic study of the seasonal cycle and its latitudinal variation in the nitrous oxide (N_2O) data collected by National Oceanic and Atmospheric Administration–Global Monitoring Division (NOAA-GMD) and the Advanced Global Atmospheric Gases Experiment (AGAGE). In order to confirm the weak seasonal signal in the observations, we applied the multitaper method for the spectrum analysis and studied the stations with significant seasonal cycle. In addition, the measurement errors must be small compared with the seasonal cycle. The N_2O seasonal cycles from seven stations satisfied these criteria and were analyzed in detail. The stations are Alert (82°N, 62°W), Barrow (71°N, 157°W), Mace Head (53°N, 10°W), Cape Kumukahi (19°N, 155°W), Cape Matatula (14°S, 171°W), Cape Grim (41°S, 145°E) and South Pole (90°S, 102°W). The amplitude (peak to peak) of the seasonal cycle of N_2O varies from 0.29 ppb (parts-per-billion by mole fraction in dry air) at the South Pole to 1.15 ppb at Alert. The month at which the seasonal cycle is at a minimum varies monotonically from April (South Pole) to September (Alert). The seasonal cycle in the Northern Hemisphere shows the influence of the stratosphere; the seasonal cycle of N_2O in the Southern Hemisphere suggests greater influence from surface sources. Preliminary estimates are obtained for the magnitude of the seasonally varying sources needed to account for the observations.

Interannual Variability and Trends of Extratropical Ozone. Part I: Northern Hemisphere

The authors apply principal component analysis (PCA) to the extratropical total column ozone from the combined merged ozone data product and the European Centre for Medium-Range Weather Forecasts assimilated ozone from January 1979 to August 2002. The interannual variability (IAV) of extratropical O3 in the Northern Hemisphere (NH) is characterized by four main modes. Attributable to dominant dynamical effects, these four modes account for nearly 60% of the total ozone variance in the NH. The patterns of variability are distinctly different from those derived for total O3 in the tropics. To relate the derived patterns of O3 to atmospheric dynamics, similar decompositions are performed for the 30–100-hPa geopotential thickness. The results reveal intimate connections between the IAV of total ozone and the atmospheric circulation. The first two leading modes are nearly zonally symmetric and represent the connections to the annular modes and the quasi-biennial oscillation. The other two modes exhibit in-quadrature, wavenumber-1 structures that, when combined, describe the displacement of the polar vortices in response to planetary waves. In the NH, the extrema of these combined modes have preferred locations that suggest fixed topographical and land–sea thermal forcing of the involved planetary waves. Similar spatial patterns and trends in extratropical column ozone are simulated by the Goddard Earth Observation System chemistry–climate model (GEOS-CCM). The decreasing O3 trend is captured in the first mode. The largest trend occurs at the North Pole, with values 1 Dobson Unit (DU) yr 1 . There is almost no trend in tropical O3. The trends derived from PCA are confirmed using a completely independent method, empirical mode decomposition, for zonally averaged O3 data. The O3 trend is also captured by mode 1 in the GEOS-CCM, but the decrease is substantially larger than that in the real atmosphere.

Simulation of upper tropospheric CO2 from chemistry and transport models

The California Institute of Technology/Jet Propulsion Laboratory two-dimensional (2-D), three-dimensional (3-D) GEOS-Chem, and 3-D MOZART-2 chemistry and transport models (CTMs), driven respectively by NCEP2, GEOS-4, and NCEP1 reanalysis data, have been used to simulate upper tropospheric CO2 from 2000 to 2004. Model results of CO2 mixing ratios agree well with monthly mean aircraft observations at altitudes between 8 and 13 km (Matsueda et al., 2002) in the tropics. The upper tropospheric CO2 seasonal cycle phases are well captured by the CTMs. Model results have smaller seasonal cycle amplitudes in the Southern Hemisphere compared with those in the Northern Hemisphere, which are consistent with the aircraft data. Some discrepancies are evident between the model and aircraft data in the midlatitudes, where models tend to underestimate the amplitude of CO2 seasonal cycle. Comparison of the simulated vertical profiles of CO2 between the different models reveals that the convection in the 3-D models is likely too weak in boreal winter and spring. Model sensitivity studies suggest that convection mass flux is important for the correct simulation of upper tropospheric CO2.