Djalma Eugênio Schmitt

Mobility of copper and zinc fractions in fungicide-amended vineyard sandy soils

The purpose of this study was to evaluate the mobility of copper (Cu) and zinc (Zn) in the profile and distribution of sandy soil fractions from vineyards. Soil samples were collected from two vineyards of different ages (14 and 30 years) and a natural field area in the south of Brazil. The chemical characteristics, Cu levels and Zn levels, were analyzed in the soils by extraction with ethylenediamine tetraacetic acid (EDTA) using the 3050B method of USEPA and by chemical fractionation. Cu and Zn were accumulated in the vineyard soils, especially in the uppermost soil layers and in the soil from the oldest vineyard. Approximately, 75% of the total Cu was extracted by EDTA, but only 30% of the total Zn was extracted by EDTA. Most of the Cu, especially in the oldest vineyard, was distributed in the mineral-associated fraction, which is characterized by low geochemical mobility, but another important part of the Cu was distributed in the soil organic matter. Most of the Zn in the soil was distributed in the residual and mineral-associated fractions, which are characterized by low mobility and have potential for causing toxicity to plants.

Phosphorus accumulation and pollution potential in a hapludult fertilized with pig manure

Successive applications of pig litter to the soil surface can increase the phosphorus (P) content and alter its adsorption, promoting P transfer to surface or subsurface waters. The purpose of this study was to evaluate P accumulation and the pollution potential of a soil after application of pig litter. In March 2010, eight years after the installation of an experiment in Braco do Norte, Santa Catarina, SC, Brazil, on a Typic Hapludult, soil was sampled (layers 0-2.5, 2.5-5, 5-10, 10-15, 15-20 and 20-30 cm) after the following fertilization treatments: no pig litter fertilization, pig slurry application and pig manure application. In this period, 694 and 1,890 kg P2O5 ha-1 were applied in the treatments with pig slurry and pig manure, respectively. The P content was determined, based on Mehlich-1, anion exchange resin (AER), 0.01 mol L-1 CaCl2 and total P in the samples. The adsorption isotherm parameters were also determined by the Langmuir and Koski-Vahala & Hartikainem models in the layers 0-2.5 and 20-30 cm. The application of 1,890 kg P2O5 ha-1 in the form of pig manure led to P accumulation, as evidenced by Mehlich-1, down to a depth of 15 cm, by AER and 0.01 mol L-1 CaCl2 down to 20 cm and by total P to 30 cm. After application of 1,890 kg P2O5 ha-1 in the form of pig manure, the values of maximum P adsorption capacity were lowest in the deepest layer (20-30 cm), indicating the occupation of part of the adsorption sites of the particles. The application of swine manure to the soil over eight years increased the P quantity in the soil solution of the surface layer, indicating environmental contamination risk for surface and subsurface waters.

Phosphorus Concentrations in Sequentially Fractionated Soil Samples as Affected by Digestion Methods.

Sequential fractionation has helped improving our understanding of the lability and bioavailability of P in soil. Nevertheless, there have been no reports on how manipulation of the different fractions prior to analyses affects the total P (TP) concentrations measured. This study investigated the effects of sample digestion, filtration, and acidification on the TP concentrations determined by ICP-OES in 20 soil samples. Total P in extracts were either determined without digestion by ICP-OES, or ICP-OES following block digestion, or autoclave digestion. The effects of sample filtration, and acidification on undigested alkaline extracts prior to ICP-OES were also evaluated. Results showed that, TP concentrations were greatest in the block-digested extracts, though the variability introduced by the block-digestion was the highest. Acidification of NaHCO3 extracts resulted in lower TP concentrations, while acidification of NaOH randomly increased or decreased TP concentrations. The precision observed with ICP-OES of undigested extracts suggests this should be the preferred method for TP determination in sequentially extracted samples. Thus, observations reported in this work would be helpful in appropriate sample handling for P determination, thereby improving the precision of P determination. The results are also useful for literature data comparison and discussion when there are differences in sample treatments.

Physical properties and organic carbon content of a Typic Hapludult soil fertilised with pig slurry and pig litter in a no-tillage system

Applications of swine residues to the soil surface in a no-tillage system (NTS) may increase the organic carbon level and improve the physical properties of the soil. This study aimed to evaluate the effect of the continuous application of pig slurry (PS) and pig litter (PL) on the total organic carbon (TOC) content and physical properties of soil under NTS in Southern Brazil. In March 2010, after 8 years of cultivation of black oats (Avena strigosa)–maize (Zea mays), soil samples were collected in the 0–5, 5–10, 10–15, and 15–20 cm layers. The treatments consisted of a control plot (without manure application), plots with PS applications equivalent to one and two times the recommended rate of nitrogen (N) for maize and black oats (PS1X and PS2X, respectively), and plots with PL equivalent to one and two times the recommended rate of N for maize and black oats (PL1X and PL2X, respectively). The TOC, soil bulk density (BD), penetration resistance (PR), total porosity (TP), macro- and microporosity, distribution of pore diameters, and indices of aggregation and aggregate stability were evaluated. Differences were found between treatments for TOC, BD, macro- and microporosity, pore diameter, aggregation, and PR. Treatment with PL favoured the production of aggregates (diameter >4 mm) and increased the rates of aggregation and aggregate stability in the 10–15 and 15–20 cm layers and macroporosity in the 0–5 and 15–20 cm layers. Application of PL2X reduced PR by 34% and 20%, respectively, in the 5–10 and 10–15 cm layers. Eight years of adding PS to successive cultivations of black oats–maize soil managed under NTS produced no changes in the physical features or the TOC of the soil, whereas the application of PL produced improvements in physical attributes of the soil and increased soil TOC.

Changes in soil acidity and organic carbon in a sandy typic hapludalf after medium-term pig-slurry and deep-litter application

Successive applications of liquid swine waste to the soil can increase the contents of total organic carbon and nutrients and change acidity-related soil chemical properties. However, little information is available on the effects of swine waste application in solid form, as of swine deep-litter. The objective of this study was to evaluate alterations of organic carbon and acidity-related properties of a soil after eight years of pig slurry and deep-litter application. In the eighth year of a field experiment established in Braco do Norte, Santa Catarina (SC) on a sandy Typic Hapludalf samples were taken (layers 0-2.5; 2.5-5; 5-10; 10-15; 15-20 and 20-30 cm) from unfertilized plots and plots with pig slurry or deep-litter applications, providing the simple or double rate of N requirement of Zea mays and Avena strigosa in rotation. Soil total organic carbon, water pH, exchangeable Al, Ca and Mg, and cation exchange capacity (CECeffective and CECpH7.0), H+Al, base saturation, and aluminum saturation were measured. The application of pig slurry and deep-litter for eight years increased total organic carbon and CEC in all soil layers. The pig slurry and deep-litter applications reduced active acidity and aluminum saturation and increased base saturation down to a depth of 30 cm. Eight years of pig slurry application did not affect soil acidity.

Phosphorus fractions in the vineyard soil of the Serra Gaúcha of Rio Grande do Sul, Brazil

The study aimed to evaluate the accumulation of P fractions in a vineyard soil profile with successive applications of phosphate fertilizers. In January 2010 an area was selected of native forest and a vineyard at age 33 with a history of phosphate fertilizer application, in Bento Goncalves, Rio Grande do Sul state. Soil samples were collected from 0-5, 5-10 and 10-20 cm layers, prepared and submitted to chemical fractionation of P. The excessive application of phosphate fertilizers during 33 years in the vineyard soil increased the levels of organic and inorganic P until the 20 cm layer in all P fractions. The highest levels of P in the vineyard soil were found mainly in the labile fractions extracted with anion exchange resin and NaHCO3, which indicates high nutrient availability to plants, but also indicates the potential of transfer of solution from soil to surface run-off or percolated through the soil profile, which represents greater potential for contamination of surface and subsurface waters.

Phosphorus fractions in sandy soils of vineyards in southern Brazil

As aplicacoes de fosforo (P) em vinhedos podem causar o acumulo desse nutriente no solo e maximizar seu potencial poluente. Este trabalho objetivou quantificar as fracoes de acumulacao de P em solos arenosos cultivados com videiras na regiao Sul do Brasil. Para isso, amostras de solo foram coletadas nas camadas de 0-5, 6-10 e 11-20 cm em uma area de campo nativo e em dois vinhedos: um com 14 anos de cultivo (vinhedo 1) e outro com 30 anos (vinhedo 2), localizados no municipio de Santana do Livramento, Rio Grande do Sul (RS), Brasil. As amostras foram secas, moidas e submetidas ao fracionamento quimico de P. Os resultados evidenciaram que os teores de P inorgânico aumentaram ate 20 cm de profundidade, principalmente no vinhedo 2, em especial nas fracoes labeis extraidas por resina de troca anionica e por NaHCO3, na fracao moderadamente labil, extraida por NaOH 0,1 e 0,5 mol L-1, e na fracao nao labil, extraida por HCl 1 mol L-1, representando potencial de eutroficacao das aguas. As aplicacoes de fertilizantes fosfatados na adubacao de correcao e de manutencao nos vinhedos com maior tempo de cultivo aumentaram os teores de P na fracao orgânica extraida por NaHCO3 na camada de 0-5 cm, e na fracao moderadamente labil extraida por NaOH 0,1 mol L-1, ate 20 cm de profundidade.

Accumulation of phosphorus fractions and contamination potential in vineyard soils in the southern region of the state of Santa Catarina, Brazil

In vineyards, if phosphate is applied both before planting and at intervals during growth without consideration of technical criteria, the soil P fractions may be increased and their proportions altered. This study was carried out to evaluate the accumulation of P fractions and the parameters of the adsorption isotherm in a sandy Typic Hapludalf soil in vineyards with a history of successive and excessive phosphate fertilization. In December 2010, two vineyards were selected, one 4 and the other 15 years old, in Urussanga, State of Santa Catarina (Brazil). Three trenches were dug in each area and soil was collected from the 0-5, 5-10 and 10-20 cm depth ranges. The soil samples were dried in a forced-air oven, sieved and subjected to chemical analyses, P chemical fractionation and P adsorption isotherms. Excessive phosphate fertilization, before and during cultivation, particularly in the older vineyard and, consequently, with a longer history of phosphate fertilization, increased the inorganic P concentrations to the depth of 20 cm, especially in labile fractions extracted by anion exchange resin and NaHCO3 in the non-labile fraction, as well as in the non-labile fraction extracted by 1.0 mol L-1 HCl. The application of phosphate fertilizers and the long cultivation period increased the P levels in the organic labile fraction extracted by 0.5 mol L-1 NaHCO3, and especially in the moderately labile fraction extracted by 0.1 and 0.5 mol L-1 NaOH. Phosphate fertilization of older vineyards, i.e., cultivated for 15 years, increased the amounts of P desorbed in water, indicating a risk of contamination of surface waters and groundwater. The phosphate fertilization before planting, without considering the results of soil analysis, and during cultivation, disregarding the results of soil analysis, leaf analysis and expected yield, led to a reduction in the maximum P adsorption capacity in the 0-5 cm layer of vineyard 2, indicating saturation of part of the reactive particle adsorption sites.

Phosphorus fractions in apple orchards in southern Brazil

ABSTRACT: Phosphorus (P) applications at dosages higher than the necessary may cause P buildup in the soil labile fractions and, consequently, pollution of water sources. This study aimed to assess accumulation of P fractions as well as the parameters of adsorption isotherms in soil profiles having a history of application of phosphate fertilizers and cultivated with apple trees. Soil samples were collected from an area with no history of cultivation and 2 apple orchards cultivated for 8 (P8) and 18 (P18) years, in the city of Urubici, Santa Catarina, southern Brazil. Soil samples were air dried, sieved in a 2-mm mesh, and subjected to chemical analyses (P adsorption) besides P chemical SOIL AND PLANT NUTRITION - Article Phosphorus fractions in apple orchards in southern Brazil Djalma Eugenio Schmitt 1 , Gustavo Brunetto 2 *, Elaine dos Santos 3 , Winicius de Lima Wagner 3 , Paula Beatriz Sete 4 , Monique Souza , Vitor Gabriel Ambrosini 5 , Matheus Ademir dos Santos 3 , Tales Tiecher 2

Teor crítico de enxofre no solo para o estabelecimento de clones de erva-mate no Sul do Brasil

The cultivation of yerba mate ( Ilex paraguariensis St. Hil.) has great economic importance in the Southern of Brazil. However, the fertilization requirements in the establishment of yerba mate plantations is still unknown. The objective of this work was to evaluate the needs of sulfate fertilization on the initial growth of two clones of yerba mate in a Humic Cambisol. An experiment was carried out in Itaiopolis - SC and four doses of S (0.0; 1.2; 2.4 and 3.6 kg ha -1 of S-SO 4 2- ) and two clones (F1 and F2) were tested. The green mass and the export of nutrients were evaluated: leafs, fine twigs, thick twigs and commercial yerba mate (leaf + fine twigs), and total mass. Soil available S-SO 4 was evaluated in the 0-20 cm soil layer 24 months after planting. The production of thick twigs increased with application of S, for clone F2. However, the yield of fine twig and total mass were influenced by the dose of S, independent of the clone. Thus, there was a positive response from the application of sulfur to clone F2, indicating that it is demanding on the nutrient, increasing the yield of green mass and the levels of S-SO 4 in the soil.