Donald W. Watts

Biochars impact on soil moisture storage in an Ultisol and two Aridisols

Abstract Biochar additions to soils can improve soil-water storage capability; however, there is sparse information identifying feedstocks and pyrolysis conditions that maximize this improvement. Nine biochars were pyrolyzed from five feedstocks at two temperatures, and their physical and chemical properties were characterized. Biochars were mixed at 2% wt wt−1 into a Norfolk loamy sand (Fine-loamy, kaolinitic, thermic Typic Kandiudult), a Declo silt loam (Coarse-loamy, mixed, superactive, mesic xeric Haplocalcid), or a Warden silt loam (Coarse-silty, mixed, superactive, mesic xeric Haplocambid). Untreated soils served as controls. Soils were laboratory incubated in pots for 127 days and were leached about every 30 days with deionized water. Soil bulk densities were measured before each leaching event. For 6 days thereafter, pot-holding capacities (PHC) for water were determined gravimetrically and were used as a surrogate for soil-moisture contents. Water tension curves were also measured on the biochar-treated and untreated Norfolk soil. Biochar surface area, surface tension, ash, C, and Si contents, in general, increased when produced under higher pyrolytic temperatures (≥500°C). Both switchgrass biochars caused the most significant water PHC improvements in the Norfolk, Declo, and Warden soils compared with the controls. Norfolk soil-water tension results at 5 and 60 kPa corroborated that biochar from switchgrass caused the most significant moisture storage improvements. Significant correlation occurred between the PHC for water with soil bulk densities. In general, biochar amendments enhanced the moisture storage capacity of Ultisols and Aridisols, but the effect varied with feedstock selection and pyrolysis temperature.

Switchgrass Biochar Affects Two Aridisols

The use of biochar has received growing attention because of its ability to improve the physicochemical properties of highly weathered Ultisols and Oxisols, yet very little research has focused on its effects in Aridisols. We investigated the effect of low or high temperature (250 or 500°C) pyrolyzed switchgrass () biochar on two Aridisols. In a pot study, biochar was added at 2% w/w to a Declo loam (Xeric Haplocalcids) or to a Warden very fine sandy loam (Xeric Haplocambids) and incubated at 15% moisture content (by weight) for 127 d; a control (no biochar) was also included. Soils were leached with 1.2 to 1.3 pore volumes of deionized HO on Days 34, 62, 92, and 127, and cumulative leachate Ca, K, Mg, Na, P, Cu, Fe, Mn, Ni, Zn, NO-N, NO-N, and NH-N concentrations were quantified. On termination of the incubation, soils were destructively sampled for extractable Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Zn, NO-N, and NH-N, total C, inorganic C, organic C, and pH. Compared with 250°C, the 500°C pyrolysis temperature resulted in greater biochar surface area, elevated pH, higher ash content, and minimal total surface charge. For both soils, leachate Ca and Mg decreased with the 250°C switchgrass biochar, likely due to binding by biochars functional group sites. Both biochars caused an increase in leachate K, whereas the 500°C biochar increased leachate P. Both biochars reduced leachate NO-N concentrations compared with the control; however, the 250°C biochar reduced NO-N concentrations to the greatest extent. Easily degradable C, associated with the 250°C biochars structural make-up, likely stimulated microbial growth, which caused NO-N immobilization. Soil-extractable K, P, and NO-N followed a pattern similar to the leachate observations. Total soil C content increases were linked to an increase in organic C from the biochars. Cumulative results suggest that the use of switchgrass biochar prepared at 250°C could improve environmental quality in calcareous soil systems by reducing nutrient leaching potential.

WATER TREATMENT RESIDUALS AMENDED SOILS RELEASE Mn, Na, S, AND C

Drinking water treatment facilities remove impurities from raw water sources using various chemicals. The by-product produced from the purification process is called water treatment residuals (WTR). If WTR contain residual chemicals from the purification process, soluble elements may be released potentially causing chemical imbalances in soil and groundwater systems. The study objectives were to: (i) examine Mn, Na, S, and total organic carbon (TOC) released from soil and deionized water leachate from a Norfolk soil (fine-loamy, kaolinitic, thermic Typic Kandiudult) incubated for 60 days with 0 (untreated) and 60 g kg−1 of three different WTR; and (ii) assess effects of oxidation-reduction potential on Mn stability and solubility. The WTR were obtained from a North and South Carolina drinking water treatment facility that treated raw water using alum [Al2(SO4)3], caustic soda (NaOH), and potassium permanganate (KMnO4). During incubation, treatments were maintained between 5% and 10% moisture, and oxidation-reduction potential was measured using a Pt electrode. After 60 days, treatments were leached with 1.2-pore volumes of deionized water. Soils were then analyzed for Mn, Na, and S, and leachates were analyzed for TOC and similar elements using inductively coupled plasma spectroscopy. At this time, WTR-treated soils were slightly acidic, moderately reduced, and enriched in extractable Mn, Na, and S concentrations. Water leachates from WTR-treated soil were also enriched with Mn, Na, S, and TOC. Divalent Mn was the dominant oxidation state, making Mn more susceptible to leaching. One WTR enriched with Mn caused Norfolk soil Mn concentrations to exceed crop sensitive stress threshold levels. It is recommended that a prescreening procedure should be used to determine if WTR applied to soil will release elements that may cause plant growth problems.

Solid‐phase extraction and GC analyses of select agricultural pesticides and metabolites in stream water

Abstract The occurrence of agricultural pesticides in surface waters around the USA has created a concern over the status of safe drinking water. Solid‐phase extraction (SPE) or liquid‐liquid extraction (LLE) is usually employed to concentrate trace levels of pesticides in water samples to concentrations that are measurable with advanced chromatographic instruments. We describe here a SPE and capillary gas chromatographic (GC) procedure to extract and concentrate trace levels of select agricultural pesticides and metabolites from stream water. Our SPE and GC method provides high sensitivity, with recoveries between 85% to 95%, and high reproducibility for 9 of the pesticides studied. The described method provided marginal recoveries of 19 and 60% for the atrazine metabolites.

Storm flow export of metolachlor from a Coastal Plain watershed.

Abstract During an 18‐month (1994–1995) survey of the surface water in an Atlantic Coastal Plain watershed, metolachlor was most frequently detected during storm flow events. Therefore, a sampling procedure, focused on storm flow, was implemented in June of 1996. During 1996, three tropical cyclones made landfall within 150 km of the watershed. These storms, as well as several summer thunderstorms, produced six distinct storm flow events within the watershed. Metolachlor was detected leaving the watershed during each event. In early September, Hurricane Fran produced the largest storm flow event and accounted for the majority of the metolachlor exports. During the storm event triggered by Hurricane Fran, the highest daily average flow (7.5 m2 s‐1) and highest concentration (5.1 μg L‐1) ever measured at the watershed outlet were recorded. Storm flow exports leaving the watershed represented 0.1 g ha‐1 or about 0.04% of active ingredient applied.

Evaluation of C18 solid-phase extraction cartridges for the isolation of select pesticides and metabolites

Abstract Nine different C18 solid‐phase extraction (SPE) cartridges were evaluated for their efficiency at extracting nine pesticides and two s‐triazine metabolites from spiked deionized water samples. The SPE cartridges were found to contain nitrogen (N) and/or phosphorus (P) contaminants and varied in their extraction efficiency for certain pesticides and metabolites. Four of the nine SPE cartridges gave acceptable (70 to 120%) pesticide and metabolite recovery percentages, while five cartridges had marginal (50 to 70%) to poor (< 50%) recoveries. Statistical analyses showed that the poor to marginal recoveries found for three compounds could not be explained by considering several indigenous chemical and physical traits of the cartridge. It is suggested that proper SPE cartridge selection for pesticide recovery should be evaluated using several different cartridges.