Hoang T. Nguyen

HIGH-EFFICIENCY FUSED-SILICA TRANSMISSION GRATINGS

We describe the design, fabrication, and performance of high-efficiency transmission gratings fabricated in bulk fused silica for use in high-power ultraviolet laser systems. The gratings exhibit a diffraction efficiency of 94% in order m=-1 and a damage threshold greater than 13>J/cm( 2) for 3-ns pulses at 351 nm. Model calculations and experimental measurements are in good agreement.

Large area high efficiency broad bandwidth 800 nm dielectric gratings for high energy laser pulse compression.

We have demonstrated broad bandwidth large area (229 mm × 114 mm) multilayer dielectric diffraction gratings for the efficient compression of high energy 800 nm laser pulses at high average power.

Plasmonic black metals in resonant nanocavities

We investigate a plasmonic resonant structure tunable from ultra-violet to near infrared wavelengths with maximum absorbance strength over 95% due to a highly efficient coupling with incident light. Additional harmonics are excited at higher frequencies extending the absorbance range to multiple wavelengths. We propose the concept of a plasmonic black metal nanoresonator that exhibits broadband absorbance characteristics by spacing the modes closer through increasing the resonator length and by employing adiabatic plasmonic nano-focusing on the tapered end of the cavity.

Petawatt laser system

We recently demonstrated the production of over a petawatt of peak power in the Nova/Petawatt Laser Facility, generating > 600 J in approximately 440 fs. The Petawatt Laser Project was initiated to develop the capability to test the fast ignitor concept for inertial confinement fusion, and to provide a unique capability in high energy density physics. The laser was designed to produce near kJ pulses with a pulse duration adjustable between 0.5 and 20 ps. At the shortest pulse lengths, this laser is expected to surpass 1021 W/cm2 when focused later this year. Currently, this system is limited to 600 J pulses in a 46.3- cm beam. Expansion of the beam to 58 cm, with the installation of 94-cm gratings, will enable 1 kJ operation. Target experiments with petawatt pulses will be possible either integrated with Nova in the 10 beam target chamber or as a stand alone system in an independent, dedicated chamber. Focusing the beam onto a target will be accomplished using an on axis parabolic mirror. The design of a novel targeting system enabling the production of ultrahigh contrast pulses and an easily variable effective focal length is also described.

Precise diffraction efficiency measurements of large-area greater-than-99%-efficient dielectric gratings at the Littrow angle

We have developed improved cavity-finesse methods for characterizing the diffraction efficiencies of large gratings at the Littrow angle. These methods include measuring cavity length with optical techniques, using a Michelson interferometer to calibrate piezoelectric transducer nonlinearities and angle-tuning procedures to confirm optimal alignment. We used these methods to characterize two 20 cm scale dielectric gratings. The values taken from across their surfaces collectively had means and standard deviations of micro=99.293% and sigma=0.164% and micro=99.084% and sigma=0.079%. The greatest efficiency observed at a single point on a grating was (99.577+/-0.002)%, which is also the most accurate measurement of the diffraction efficiency in the literature of which we are aware. These results prove that a high diffraction efficiency with low variation is achievable across large apertures for gratings.

Fabrication of functional silicon-based nanoporous membranes

Macroscopic porous membranes with pore diameter uniformity approaching the nanometer scale have great potential to significantly increase the speed, selectivity, and efficiency of molecular separations. We present fabrication, characterization, and molecular transport evaluation of nanoporous thin silicon-based sieves created by laser interferometric lithography (LIL). This fabrication approach is ideally suited for the integration of nanostructured pore arrays into larger microfluidic processing systems, using a simple all-silicon lithographic process. Submilli-meter-scale planar arrays of uniform cylindrical and pyramidal nanopores are created in silicon nitride and silicon, respectively, with average pore diameters below 250 nm and significantly smaller standard error than commercial polycarbonate track etched (PCTE) membranes. Molecular transport properties of short cylindrical pores fabricated by LIL are compared to those of thicker commercial PCTE membranes for the first time. A 10-fold increase in pyridine pore flux is achieved with thin membranes relative to commercial sieves, without any modification of the membrane surface.

Amplification of femtosecond pulses to 1 J in Cr:LiSrAlF 6

We have developed a large-aperture, flash-lamp-pumped Cr:LiSrAlF(6) (Cr:LiSAF) amplifier for use in a femtosecond chirped-pulse amplifier system. Optimum design of the 19-mm-diameter amplifier results in a single-pass gain of 5 with good beam quality. This amplifier produces 1.05-J pulses after compression, with a width of 125 fs at a repetition rate of 0.05 Hz.

Nanopillars array for surface enhanced Raman scattering

We present a new class of surface-enhanced Raman scattering (SERS) substrates based on lithographically-defined two-dimensional rectangular array of nanopillars. Two types of nanopillars within this class are discussed: vertical pillars and tapered pillars. For the vertical pillars, the gap between each pair of nanopillars is small enough (< 50 nm) such that highly confined plasmonic cavity resonances are supported between the pillars when light is incident upon them, and the anti-nodes of these resonances act as three-dimensional hotspots for SERS. For the tapered pillars, SERS enhancement arises from the nanofocusing effect due to the sharp tip on top. SERS experiments were carried out on these substrates using various concentrations of 1,2 bis-(4-pyridyl)-ethylene (BPE), benzenethiol (BT) monolayer and toluene vapor. The results show that SERS enhancement factor of over 0.5 x 109 can be achieved, and BPE can be detected down to femto-molar concentration level. The results also show promising potential for the use of these substrates in environmental monitoring of gases and vapors such as volatile organic compounds.

Gratings for High-Energy Petawatt Lasers

To enable high-energy petawatt laser operation we have developed the processing methods and tooling that produced both the worlds largest multilayer dielectric reflection grating and the worlds highest laser damage resistant gratings. We have successfully delivered the first ever 80 cm aperture multilayer dielectric grating to LLNLs Titan Intense Short Pulse Laser Facility. We report on the design, fabrication and characterization of multilayer dielectric diffraction gratings.

Improvement of laser damage resistance and diffraction efficiency of multilayer dielectric diffraction gratings by HF etchback linewidth tailoring

Multilayer dielectric (MLD) diffraction gratings for Petawatt-class laser systems possess unique laser damage characteristics. Details of the shape of the grating lines and the concentration of absorbing impurities on the surface of the grating structures both have strong effects on laser damage threshold. It is known that electric field enhancement in the solid material comprising the grating lines varies directly with the linewidth and inversely with the line height for equivalent diffraction efficiency. Here, we present an overview of laser damage characteristics of MLD gratings, and describe a process for post-processing ion-beam etched grating lines using very dilute buffered hydrofluoric acid solutions. This process acts simultaneously to reduce grating linewidth and remove surface contaminants, thereby improving laser damage thresholds through two pathways.