Kevin Konrad

Deeply dredged submarine HIMU glasses from the Tuvalu Islands, Polynesia: Implications for volatile budgets of recycled oceanic crust

Ocean island basalts (OIB) with extremely radiogenic Pb-isotopic signatures are melts of a mantle component called HIMU (high µ, high 238U/204Pb). Until now, deeply dredged submarine HIMU glasses have not been available, which has inhibited complete geochemical (in particular, volatile element) characterization of the HIMU mantle. We report major, trace and volatile element abundances in a suite of deeply dredged glasses from the Tuvalu Islands. Three Tuvalu glasses with the most extreme HIMU signatures have F/Nd ratios (35.6 ± 3.6) that are higher than the ratio (∼21) for global OIB and MORB, consistent with elevated F/Nd ratios in end-member HIMU Mangaia melt inclusions. The Tuvalu glasses with the most extreme HIMU composition have Cl/K (0.11–0.12), Br/Cl (0.0024), and I/Cl (5–6 × 10−5) ratios that preclude significant assimilation of seawater-derived Cl. The new HIMU glasses that are least degassed for H2O have low H2O/Ce ratios (75–84), similar to ratios identified in end-member OIB glasses with EM1 and EM2 signatures, but significantly lower than H2O/Ce ratios (119–245) previously measured in melt inclusions from Mangaia. CO2-H2O equilibrium solubility models suggest that these HIMU glasses (recovered in two different dredges at 2500–3600 m water depth) have eruption pressures of 295–400 bars. We argue that degassing is unlikely to significantly reduce the primary melt H2O. Thus, the lower H2O/Ce in the HIMU Tuvalu glasses is a mantle signature. We explore oceanic crust recycling as the origin of the low H2O/Ce (∼50–80) in the EM1, EM2, and HIMU mantle domains.

Identification of the short-lived Santa Rosa geomagnetic excursion in lavas on Floreana Island (Galapagos) by 40Ar/39Ar geochronology

A set of closely related basaltic lava flows (supersite GA-X) on Floreana Island in the Galapagos Archipelago has a published record of an excursional or transitional direction (virtual geomagnetic pole located at 153.1°E, 54.2°S with α 95 = 5.0°) and a geomagnetic field strength (1.1 × 10 22 Am 2 ) that is only ∼14% of the strength of the modern magnetic field (7.8 × 10 22 Am 2 ). The very large age uncertainty of previous dating of a lava flow (G43) from this set, however, has prevented placing this event in the geomagnetic polarity time scale. Here we report highly reproducible and precise 40 Ar/ 39 Ar ages on the lava flow that indicate that the distinct geomagnetic excursion is 925.7 ± 4.6 ka (2σ; n = 6; mean square of weighted deviates = 1.23). This shows that this dramatic weakening of the geomagnetic field is associated with the Santa Rosa Excursion instead of the Matuyama-Brunhes polarity reversal. Our high-precision 40 Ar/ 39 Ar ages for Floreana provide evidence for the global significance of the Santa Rosa Excursion.

The missing half of the subduction factory: shipboard results from the Izu rear arc, IODP Expedition 350

ABSTRACT IODP Expedition 350 was the first to be drilled in the rear part of the Izu-Bonin, although several sites had been drilled in the arc axis to fore-arc region; the scientific objective was to understand the evolution of the Izu rear arc, by drilling a deep-water volcaniclastic section with a long temporal record (Site U1437). The Izu rear arc is dominated by a series of basaltic to dacitic seamount chains up to ~100-km long roughly perpendicular to the arc front. Dredge samples from these are geochemically distinct from arc front rocks, and drilling was undertaken to understand this arc asymmetry. Site U1437 lies in an ~20-km-wide basin between two rear arc seamount chains, ~90-km west of the arc front, and was drilled to 1804 m below the sea floor (mbsf) with excellent recovery. We expected to drill a volcaniclastic apron, but the section is much more mud-rich than expected (~60%), and the remaining fraction of the section is much finer-grained than predicted from its position within the Izu arc, composed half of ashes/tuffs, and half of lapilli tuffs of fine grain size (clasts <3 cm). Volcanic blocks (>6.4 cm) are only sparsely scattered through the lowermost 25% of the section, and only one igneous unit was encountered, a rhyolite peperite intrusion at ~1390 mbsf. The lowest biostratigaphic datum is at 867 mbsf (~6.5 Ma), the lowest palaeomagnetic datum is at ~1300 mbsf (~9 Ma), and the rhyolite peperite at ~1390 mbsf has yielded a U–Pb zircon concordia intercept age of (13.6 + 1.6/−1.7) Ma. Both arc front and rear arc sources contributed to the fine-grained (distal) tephras of the upper 1320 m, but the coarse-grained (proximal) volcaniclastics in the lowest 25% of the section are geochemically similar to the arc front, suggesting arc asymmetry is not recorded in rocks older than ~13 Ma.

40Ar/39Ar ages and zircon petrochronology for the rear arc of the Izu-Bonin-Marianas intra-oceanic subduction zone

ABSTRACT Long-lived intra-oceanic arcs of Izu-Bonin-Marianas (IBM)-type are built on thick, granodioritic crust formed in the absence of pre-existing continental crust. International Ocean Discovery Program Expedition 350, Site U1437, explored the IBM rear arc to better understand continental crust formation in arcs. Detailed petrochronological (U–Pb geochronology combined with trace elements, oxygen and hafnium isotopes) characterizations of zircon from Site U1437 were carried out, taking care to exclude potential contaminants by (1) comparison of zircon ages with ship-board palaeomagnetic and biostratigraphic ages and 40Ar/39Ar geochronology, (2) analysing zircon from drill muds for comparison, (3) selectively carrying out in situ analysis in petrographic thin sections, and (4) minimizing potential laboratory contamination through using pristine equipment during mineral separation. The youngest zircon ages in Site U1437 are consistent with 40Ar/39Ar and shipboard ages to a depth of ~1390 m below sea floor (mbsf) where Igneous Unit Ig 1 yielded an 40Ar/39Ar age of 12.9 ± 0.3 Ma (all errors 2σ). One single zircon (age 15.4 ± 1.0 Ma) was recovered from the deepest lithostratigraphic unit drilled, Unit VII (1459.80–1806.5 mbsf). Site U1437 zircon trace element compositions are distinct from those of oceanic and continental arc environments and differ from those generated in thick oceanic crust (Iceland-type) where low-δ18O evolved melts are produced via re-melting of hydrothermally altered mafic rocks. Ti-in-zircon model temperatures are lower than for mid-ocean ridge rocks, in agreement with low zircon saturation temperatures, suggestive of low-temperature, hydrous melt sources. Zircon oxygen (δ18O = 3.3–6.0‰) and hafnium (εHf = + 10–+16) isotopic compositions indicate asthenospheric mantle sources. Trace element and isotopic differences between zircon from Site U1437 rear-arc rocks and the Hadean detrital zircon population suggest that preserved Hadean zircon crystals were probably generated in an environment different from modern oceanic convergent margins underlain by depleted mantle.

On the relative motions of long-lived Pacific mantle plumes

Mantle plumes upwelling beneath moving tectonic plates generate age-progressive chains of volcanos (hotspot chains) used to reconstruct plate motion. However, these hotspots appear to move relative to each other, implying that plumes are not laterally fixed. The lack of age constraints on long-lived, coeval hotspot chains hinders attempts to reconstruct plate motion and quantify relative plume motions. Here we provide 40Ar/39Ar ages for a newly identified long-lived mantle plume, which formed the Rurutu hotspot chain. By comparing the inter-hotspot distances between three Pacific hotspots, we show that Hawaii is unique in its strong, rapid southward motion from 60 to 50 Myrs ago, consistent with paleomagnetic observations. Conversely, the Rurutu and Louisville chains show little motion. Current geodynamic plume motion models can reproduce the first-order motions for these plumes, but only when each plume is rooted in the lowermost mantle.Using mantle plumes to reconstruct past plate motion is complicated, because plumes may not be fixed. Here, the authors demonstrate using 40Ar/39Ar ages that the Rurutu plume is relatively stable compared to the rapidly moving Hawaiian plume, yet it has a similar deep mantle origin.

10Be dating of late Pleistocene megafloods and Cordilleran Ice Sheet retreat in the northwestern United States

During the late Pleistocene, multiple floods from drainage of glacial Lake Missoula further eroded a vast anastomosing network of bedrock channels, coulees, and cataracts, forming the Channeled Scabland of eastern Washington State (United States). However, the timing and exact pathways of these Missoula floods remain poorly constrained, thereby limiting our understanding of the evolution of this spectacular landscape. Here we report cosmogenic ^(10)Be ages that directly date flood and glacial features important to understanding the flood history, the evolution of the Channeled Scabland, and relationships to the Cordilleran Ice Sheet (CIS). One of the largest floods occurred at 18.2 ± 1.5 ka, flowing down the northwestern Columbia River valley prior to blockage of this route by advance of the Okanogan lobe of the CIS, which dammed glacial Lake Columbia and diverted later Missoula floods to more eastern routes through the Channeled Scabland. The Okanogan and Purcell Trench lobes of the CIS began to retreat from their maximum extent at ca. 15.5 ka, likely in response to onset of surface warming of the northeastern Pacific Ocean. Upper Grand Coulee fully opened as a flood route after 15.6 ± 1.3 ka, becoming the primary path for later Missoula floods until the last ones from glacial Lake Missoula at 14.7 ± 1.2 ka. The youngest dated flood(s) (14.0 ± 1.4 ka to 14.4 ± 1.3 ka) came down the northwestern Columbia River valley and were likely from glacial Lake Columbia, indicating that the lake persisted for a few centuries after the last Missoula flood.

Millennial-Scale Instability in the Geomagnetic Field Prior to the Matuyama-Brunhes Reversal

Changes in the Earths magnetic field have global significance that reach from the outer core extending out to the uppermost atmosphere. Paleomagnetic records derived from sedimentary and volcanic sequences provide important insights into the geodynamo processes that govern the largest geomagnetic changes (polarity reversals), but dating uncertainties have hindered progress in this understanding. Here we report a paleomagnetic record from multiple lava flows on Tahiti that bracket the Matuyama-Brunhes (M-B) polarity reversal ∼771 thousand years ago. Our high-precision ^(40)Ar/^(39)Ar ages constrain several rapid and short-lived changes in field orientation up to 33,000 years prior to the M-B reversal. These changes are similar to ones identified in other less well-dated lava flows in Maui, Chile and La Palma that occurred during an extended period of reduced field strength recorded in sediments. We use a simple stochastic model to show that these rapid polarity changes are highly attenuated in sediment records with low sedimentation rates. This prolonged 33,000-year period of reduced field strength and increased geomagnetic instability supports models that show frequent centennial-to-millennial scale polarity changes in the presence of a strongly weakened dipole field.