L. Colangeli

Organics captured from comet 81P/Wild 2 by the Stardust spacecraft

Organics found in comet 81P/Wild 2 samples show a heterogeneous and unequilibrated distribution in abundance and composition. Some organics are similar, but not identical, to those in interplanetary dust particles and carbonaceous meteorites. A class of aromatic-poor organic material is also present. The organics are rich in oxygen and nitrogen compared with meteoritic organics. Aromatic compounds are present, but the samples tend to be relatively poorer in aromatics than are meteorites and interplanetary dust particles. The presence of deuterium and nitrogen-15 excesses suggest that some organics have an interstellar/protostellar heritage. Although the variable extent of modification of these materials by impact capture is not yet fully constrained, a diverse suite of organic compounds is present and identifiable within the returned samples.

Astrophysical and astrochemical insights into the origin of life

Stellar nucleosynthesis of heavy elements such as carbon allowed the formation of organic molecules in space, which appear to be widespread in our Galaxy. The physical and chemical conditions—including density, temperature, ultraviolet (UV) radiation and energetic particles—determine reaction pathways and the complexity of organic molecules in different space environments. Dense interstellar clouds are the birth sites of stars of all masses and their planetary systems. During the protostellar collapse, interstellar organic molecules in gaseous and solid phases are integrated into protostellar disks from which planets and smaller solar

Dust measurements in the coma of comet 67P/Churyumov-Gerasimenko inbound to the Sun

Critical measurements for understanding accretion and the dust/gas ratio in the solar nebula, where planets were forming 4.5 billion years ago, are being obtained by the GIADA (Grain Impact Analyser and Dust Accumulator) experiment on the European Space Agency’s Rosetta spacecraft orbiting comet 67P/Churyumov-Gerasimenko. Between 3.6 and 3.4 astronomical units inbound, GIADA and OSIRIS (Optical, Spectroscopic, and Infrared Remote Imaging System) detected 35 outflowing grains of mass 10−10 to 10−7 kilograms, and 48 grains of mass 10−5 to 10−2 kilograms, respectively. Combined with gas data from the MIRO (Microwave Instrument for the Rosetta Orbiter) and ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) instruments, we find a dust/gas mass ratio of 4 ± 2 averaged over the sunlit nucleus surface. A cloud of larger grains also encircles the nucleus in bound orbits from the previous perihelion. The largest orbiting clumps are meter-sized, confirming the dust/gas ratio of 3 inferred at perihelion from models of dust comae and trails.

The organic-rich surface of comet 67P/Churyumov-Gerasimenko as seen by VIRTIS/Rosetta

The VIRTIS (Visible, Infrared and Thermal Imaging Spectrometer) instrument on board the Rosetta spacecraft has provided evidence of carbon-bearing compounds on the nucleus of the comet 67P/Churyumov-Gerasimenko. The very low reflectance of the nucleus (normal albedo of 0.060 ± 0.003 at 0.55 micrometers), the spectral slopes in visible and infrared ranges (5 to 25 and 1.5 to 5% kÅ−1), and the broad absorption feature in the 2.9-to-3.6–micrometer range present across the entire illuminated surface are compatible with opaque minerals associated with nonvolatile organic macromolecular materials: a complex mixture of various types of carbon-hydrogen and/or oxygen-hydrogen chemical groups, with little contribution of nitrogen-hydrogen groups. In active areas, the changes in spectral slope and absorption feature width may suggest small amounts of water-ice. However, no ice-rich patches are observed, indicating a generally dehydrated nature for the surface currently illuminated by the Sun.

Temperature Dependence of the Absorption Coefficient of Cosmic Analog Grains in the Wavelength Range 20 Microns to 2 Millimeters

We have measured the absorption coefficient per unit mass of cosmic dust analog grains, crystalline fayalite and forsterite, amorphous fayalite, and two kinds of disordered carbon grains, between 20 μm and 2 mm over the temperature range 295-24 K. The results provide evidence of a significant dependence on temperature. The opacity systematically decreases with decreasing temperature; at 1 mm, it varies by a factor of between 1.9 and 5.8, depending on the material, from room temperature to 24 K. The variations are more marked for the amorphous grains. The wavelength dependence of the absorption coefficient is well fitted by a power law with exponent β that varies with temperature. For the two amorphous carbons, β(24 K) ~1.2 with increases of 24% and 50% with respect to the room-temperature values. A 50% increase is found for amorphous fayalite, characterized by β(24 K) = 2. A less pronounced change of β with temperature, 14% and 10%, is observed for crystalline forsterite, β(24 K) = 2.2, and fayalite, β(24 K) = 2.3, respectively. For amorphous fayalite grains, the millimeter opacity at 24 K is larger by a factor of ~4 than that of the crystalline counterpart. In addition, a temperature dependence of the infrared bands present in the spectrum of the two crystalline silicates is found. The features become more intense, sharpen, and shift to slightly higher frequencies with decreasing temperature. The results are discussed in terms of intrinsic far-infrared-millimeter absorption mechanisms. The linear dependence of the millimeter absorption on temperature suggests that two-phonon difference processes play a dominant role. The absorption coefficients reported in this work can be useful in obtaining a more realistic simulation of a variety of astronomical data concerning dust at low temperatures and give hints to better identify its actual properties. In particular, they are used to discuss the origin of the diffuse far-infrared-millimeter interstellar dust emission spectrum. It is proposed that composite particles formed of silicate and amorphous carbon grains can reproduce the observations. The presence of these particles in the diffuse medium is consistent with the recent interstellar extinction model by Mathis.

Infrared Spectroscopy of Comet 81P/Wild 2 Samples Returned by Stardust

Infrared spectra of material captured from comet 81P/Wild 2 by the Stardust spacecraft reveal indigenous aliphatic hydrocarbons similar to those in interplanetary dust particles thought to be derived from comets, but with longer chain lengths than those observed in the diffuse interstellar medium. Similarly, the Stardust samples contain abundant amorphous silicates in addition to crystalline silicates such as olivine and pyroxene. The presence of crystalline silicates in Wild 2 is consistent with mixing of solar system and interstellar matter. No hydrous silicates or carbonate minerals were detected, which suggests a lack of aqueous processing of Wild 2 dust.

Darwin - A Mission to Detect and Search for Life on Extrasolar Planets

The discovery of extrasolar planets is one of the greatest achievements of modern astronomy. The detection of planets that vary widely in mass demonstrates that extrasolar planets of low mass exist. In this paper, we describe a mission, called Darwin, whose primary goal is the search for, and characterization of, terrestrial extrasolar planets and the search for life. Accomplishing the mission objectives will require collaborative science across disciplines, including astrophysics, planetary sciences, chemistry, and microbiology. Darwin is designed to detect rocky planets similar to Earth and perform spectroscopic analysis at mid-infrared wavelengths (6-20 mum), where an advantageous contrast ratio between star and planet occurs. The baseline mission is projected to last 5 years and consists of approximately 200 individual target stars. Among these, 25-50 planetary systems can be studied spectroscopically, which will include the search for gases such as CO(2), H(2)O, CH(4), and O(3). Many of the key technologies required for the construction of Darwin have already been demonstrated, and the remainder are estimated to be mature in the near future. Darwin is a mission that will ignite intense interest in both the research community and the wider public.

C-H Bond Formation in Carbon Grains by Exposure to Atomic Hydrogen: The Evolution of the Carrier of the Interstellar 3.4 Micron Band

We present the results of a systematic study on the interaction of nano-sized carbon grains with atomic hydrogen. The effects of H processing have been analyzed by infrared spectroscopy. The samples were irradiated with fluences ranging between 9.2 × 1016 and 1.3 × 1020 H atoms cm-2. Hydrogen atoms lead to the activation of the aliphatic C–H stretching and bending modes, whose intensity increases with exposure until saturation of hydrogenation. The plateau value of the absorption coefficient per unit mass of material at 3.4 μm is 1.6 × 103 cm2 g-1. The estimated cross section of C–H bond formation by H atoms for carbon particles is σf = (1.9 ± 0.5) × 10-18 cm2 per H atom, as derived from the behavior of the 3.4 μm band intensity as a function of the H atom fluence. We have found that the C–H bond formation depends on the structure of the carbon material that is exposed to atomic hydrogen. In view of the basic role of the hydrogenation of carbon particles by H atoms in interpreting the presence of the 3.4 μm band in the diffuse interstellar medium, the behavior of carbon materials under H processing becomes a fundamental criterion for constraining their applicability as analogs of the interstellar aliphatic component. The 3.4 μm band and the doublet at 6.86 and 7.26 μm of carbon particles processed by H atoms reproduce the peak positions and the relative intensities of those observed in the spectrum of interstellar dust toward the Galactic center. The estimation of the formation cross section of C–H bonds by H atoms, together with the previously determined destruction cross section by UV photons, allows a complete description of the evolution of the interstellar aliphatic carbon component due to UV and H processing. The conclusion of our analysis is that the interstellar component (i.e., the C–H bonds in the CH2 and CH3 groups) responsible for the 3.4 μm stretching band and the associated bending features at 6.85 and 7.25 μm is formed in the diffuse medium, since the carrier readily loses memory of its birthsite, wherever it is, because of interstellar processing, which determines a new equilibrium value for its degree of hydrogenation.

The Surface Composition and Temperature of Asteroid 21 Lutetia As Observed by Rosetta/VIRTIS

A spacecraft flyby of an asteroid reveals a high-density body that is more like a planetesimal than a rubble pile. The Visible, InfraRed, and Thermal Imaging Spectrometer (VIRTIS) on Rosetta obtained hyperspectral images, spectral reflectance maps, and temperature maps of the asteroid 21 Lutetia. No absorption features, of either silicates or hydrated minerals, have been detected across the observed area in the spectral range from 0.4 to 3.5 micrometers. The surface temperature reaches a maximum value of 245 kelvin and correlates well with topographic features. The thermal inertia is in the range from 20 to 30 joules meter−2 kelvin−1 second−0.5, comparable to a lunarlike powdery regolith. Spectral signatures of surface alteration, resulting from space weathering, seem to be missing. Lutetia is likely a remnant of the primordial planetesimal population, unaltered by differentiation processes and composed of chondritic materials of enstatitic or carbonaceous origin, dominated by iron-poor minerals that have not suffered aqueous alteration.

DENSITY AND CHARGE of PRISTINE FLUFFY PARTICLES FROM COMET 67P/CHURYUMOV-GERASIMENKO

The Grain Impact Analyzer and Dust Accumulator (GIADA) instrument on board ESA’s Rosetta mission is constraining the origin of the dust particles detected within the coma of comet 67 P/Churyumov–Gerasimenko (67P). The collected particles belong to two families: (i) compact particles (ranging in size from 0.03 to 1 mm), witnessing the presence of materials that underwent processing within the solar nebula and (ii) fluffy aggregates (ranging in size from 0.2 to 2.5 mm) of sub-micron grains that may be a record of a primitive component, probably linked to interstellar dust. The dynamics of the fluffy aggregates constrain their equivalent bulk density to <1 kg m-3. These aggregates are charged, fragmented, and decelerated by the spacecraft negative potential and enter GIADA in showers of fragments at speeds <1 m s-1. The density of such optically thick aggregates is consistent with the low bulk density of the nucleus. The mass contribution of the fluffy aggregates to the refractory component of the nucleus is negligible and their coma brightness contribution is less than 15%.